key concepts in chemistry Flashcards
topic 1 part 1 - atomic structure, the periodic table
Describe how the Dalton model of an atom has changed over
time because of the discovery of subatomic particles
Dalton said that atoms were solid spheres and made up of elements, but Thomson’s experiment showed that the charge and mass of an atom must contain even smaller negatively charged particles - electrons
now called a plum pudding model
Describe the structure of an atom
an atom is made up of neutron, electrons, protons.
neutrons and protons are in the nucleus, with electrons surrounding them in shells
Recall the relative charge of a proton
+1
Recall the relative charge of a neutron
0
Recall the relative charge of an electron
-1
recall the relative mass of a proton
1
recall the relative mass of a neutron
1
recall the relative mass of an electron
0.0005/ negligible
Explain why atoms contain equal numbers of protons and electrons
charge on electrons is the same size and charge of protons, but the opposite so the charges cancel out
Describe the nucleus of an atom as very small compared to the overall size of the atom
most of the mass of the atom is concentrated in the nucleus so compared to the overall size of the atom, the nucleus is tiny
where is most of the mass in an atom
most of the mass in an atom is concentrated in its nucleus
what does mass number mean
total number of protons and neutrons in the atom
Describe atoms of a given element as having the same number
of protons in the nucleus and that this number is unique to that
element
atoms in an element have the same number of protons in the nucleus
isotopes are forms of the same element which have the same number of protons but a different number of neutrons
what is an isotope
isotopes are different forms of the same element which have the same number of protons but a different number of neutrons
(in their nuclei)
how to calculate number of protons, neutrons and electrons given the atomic number and mass number
mass number = number of protons and electrons
atomic number = number of protons
atoms has the same number of protons as electrons
to work out neutrons do atomic number - mass number
mass number =
total number of protons and neutrons (bigger number)
atomic number =
number of protons only
Explain how the existence of isotopes results in relative atomic
masses of some elements not being whole numbers
- if an element has more than one isotope
its Ar is the average of the mass numbers of all the different isotopes so it might not be a whole number
Ar =
(relative atomic mass)
the Ar of an element is the average mass of one atom of the element compared to 1/12 of the mass of one atom of carbon-12
how to calculate relative atomic mass of an element from the masses and abundances of its isotopes
(ex boron 10 and boron 11are isotopes of Boron, the relative abundances of boron 10 and 11 are 4 and 16, work out the Ar of boron)
- multiply each relative isotopic mass by its relative abundance and then add up the results
((104) + (1116) = 216)
- divide this by the sum of the isotopic abundances
(216 / (16+4) = 10.8
- to check if your right, your number should be in between the isotopes number
Describe how Dmitri Mendeleev arranged the elements, known
at that time, in a periodic table by using properties of these
elements and their compounds
- he based the elements based on their properties and the properties of their compounds
- he put elements with similar chemical properties in columns
- sometimes he switched the order of elements so he could keep the same properties in the same columns
Describe how Dmitri Mendeleev used his table to predict the
existence and properties of some elements not then discovered
- he left gaps to keep elements with similar chemical properties together
- columns with gaps were used to predict properties of undiscovered elements
Explain that Dmitri Mendeleev thought he had arranged
elements in order of increasing relative atomic mass but this
was not always true because of the relative abundance of
isotopes of some pairs of elements in the periodic table
Mendeleev thought he had organised the elements in order of increasing atomic mass
but this wasn’t always true because at the time he was unaware of the isotopes and their relative abundances