Key Area 3 Flashcards

1
Q

What causes a complex ion to be paramagnetic?

A

The transition metal has a half filled d-subshell

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2
Q

When writing the electronic configuration for ions, where are the electrons removed from first?

A

The 4s orbital

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3
Q

What is a dative covalent bond?

A

A shared pair of electrons from the same atom

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4
Q

How can transition metals act as catalysts?

A

They have:
-Incomplete d orbitals
-Variable oxidation states
-Unpaired d electrons

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5
Q

How do ligands bond to metal atoms to form complexes?

A

Ligands can form dative covalent bonds (with the transition metal ion)

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6
Q

What is a bidentate ligand?

A

A ligand with two parts that can donate electron pairs to the (central) metal ion

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7
Q

What causes d orbital splitting in octahedral complexes?

A

Lone pairs/Non-bonding electron pairs in the ligand

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