KA7- Kintetics Flashcards
What does the rate of reaction normally depend on?
Concentration of the reactants
Wjat does zero order with respect to A mean?
That by increasing the concentration of A it has no effect in the rate of reaction
What does first order with respect to A mean?
If doubling the conc. of A it doubles the rate of reaction
What is the rate constant?
k
not to be confused with K (capital) which is equilibrium constant
How do you use notation to show that a reactant is to the 2nd order?
[A]^2
What is the overall order of a reaction?
It is the sum of the sum of the powers to which the conc. of the reactants are raised in the rate equation
How can the order of the rate of reaction be determined?
Only through experiemental data
Does a reaction usually happen in one step?
No it is called the reaction mechanism
What is the rate of the reaction dependent on?
The rate determining step- the slowest step
For orders 1 to 4 what should the units be for the rate?
1st – s^-1
2nd – lmol^-1s^-1
3rd – l^2mol^-2s^-1
4th –l^3mol^-3s^-1