Issy 3rd Form Chemistry Flashcards

1
Q

Atoms are?

A

Everything in the universe is made of tiny particles. We call these particles ‘atoms’.

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2
Q

Elements are

A

Substances which contain only one type of atom
eg gold, tin and carbon
All of the atoms in an element have the same mass and the same properties
Elements can be solid liquid or gas

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3
Q

Compounds are

A

substances where DIFFERENT atoms are joined together by chemical bonds
eg CO2 or NaCl

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4
Q

A mixture is

A

a substance where the DIFFERENT atoms are NOT joined together with chemical bonds
eg air which is a mixture of different gases like N2, O2 and CO2

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5
Q

How are the particles organised in solids liquids and gases?

A

Solid

Particles are arranged in a regular pattern of lines and rows.
The particles cannot move away from the position they are locked in, they just vibrate on the spot.
The particles are very close together and they always touch.

Liquid
The particles in a liquid can move freely over each other.
The particles are arranged randomly.
Not all of the particles touch, but each particle will be touching at least one other particle.
There are small gaps between particles.

Gas-
The particles move randomly in all directions and travel very fast, zipping around.
The particles do not touch and are very spread out.
Sometimes gas particles bounce off each other (and off the walls of any container) if they happen to collide.

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6
Q

Changes of state- what is boiling?

A

Boiling is a change from liquid to gas.
Boiling happens when liquid particles are heated, making them move faster and faster.
Eventually, the liquid particles will be moving very quickly and in random directions, without being connected to any other particles – they have changed into the gas particle arrangement.
When you boil the kettle the steam that comes out the top is water vapour (water as a gas), because the liquid water has been heated up enough to boil.
Water boils at 100oC.

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7
Q

Changes of state- what is evaporation?

A

Evaporation is also a change from liquid to gas.

A liquid boils when every particle has gained enough energy to break free.
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8
Q

what is the difference between evaporation and boiling?

A

The difference between evaporation and boiling is that evaporation can happen at any temperature.
When you get out the shower, the water on the doors eventually ‘disappears’ because it evaporates.
It doesn’t boil, but it does turn into a gas.
This is because different particles in a liquid have different amounts of energy.
Some particles will gain enough energy to break free and will become a gas.

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9
Q

Changes of state- what is freezing?

A

Freezing is when a liquid turns into a solid.
E.g. when water freezes to ice, which happens at 0oC.
To freeze a liquid, you have to cool it down, which makes the particles travel slower and slower until they are just vibrating in a fixed position and are all very close together.
The particles will then look like the particle arrangement in a solid and the substance has frozen.

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10
Q

Changes of state- what is condensation?

A

Condensation is a change of state from a gas to liquid.
Condensation happens when you cool down a gas and reduce the energy of the particles.
The particles slow down and clump together, taking the arrangement of a liquid.

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11
Q

Changes of state- what is melting?

A

Melting is a change from solid to liquid.
Melting happens when the solid particles get some extra energy, which makes them vibrate faster and faster until they have enough energy to break away from their fixed position.
Then the particles can move freely over each other, and have turned into liquid particles
Heating something will give solid particles enough energy for them to adopt a liquid particle arrangement.

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12
Q

What is density?

A

Density means how much mass something has in a certain volume.

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13
Q

Put the three states of matter in order from most dense to least dense

A

Solid
Liquid
Gas

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14
Q

How do gases cause pressure?

A

Gas particles move quickly in all directions.
They do not travel far before they bump into each other or the walls of their container.
Each time a particle hits the wall of a container, it causes pressure.
The more often gas particles hit the walls of their container, the higher the pressure.
The harder gas particles hit the walls of their container, the higher the pressure.
If the pressure gets too high, the container will burst.
E.g. squashing a balloon raises the pressure and bursts it.

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15
Q

Can liquids cause pressure?

A

Yes Liquids can cause pressure sometimes. For example, when a water pipe bursts.

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16
Q

Can solids cause pressure?

A

Solids cannot cause pressure because their particles cannot move off their fixed positions.

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17
Q

What is pressure?

A

Pressure means how much force is applied to something divided by the area it is applied over.

P=F/A

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18
Q

what are Chemical symbols for elements?

A

Every element has a symbol, which is shown on the periodic table.
Some symbols are just one letter, some are two. The first letter is always a capital. If there is a second letter, it is always lower case.
E.g.
Hydrogen is ‘H’.
Helium is ‘He’.
Magnesium is ‘Mg’.
Sulfur ‘S’.
Lithium is ‘Li’.

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19
Q

Bonded elements - what are they and can you name them?

A

Some elements have 2 atoms which are bonded together.
eg the chemical symbol for hydrogen is H but hydrogen gas is a bonded element with another hydrogen atom so is H2 (the 2 should be smaller and sit at the bottom of the line but I can’t do it on this card!)

as well as hydrogen other atoms which travel in pairs are
nitrogen oxygen fluorine chlorine bromine and iodine

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20
Q

What are chemical symbol for compounds?

A

The formulae for compounds are written by putting the element symbols together in a line with no gaps between them.
Because all compounds are made of elements, this is always the case.

Carbon dioxide compound is made of carbon and oxygen atoms. The formula is CO2.
The little numbers tell you how many of each atom is in a compound.
The number is shown just after the element.
If there is no number given on the right of an element, then there is just one atom of it.

Water is made of hydrogen and oxygen atoms. The formula is H2O.

Any metals usually go first, and any oxygens usually go last.
The formula of magnesium oxide is:
    MgO.

MgCl2 is the formula for magnesium chloride, which contains magnesium and chlorine atoms.

The ‘l’ is a lower case 'L', and not a capital ‘I’. So the compound has magnesium and chlorine, not magnesium, carbon and iodine.
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21
Q

The chemical formula for sulfuric acid is H2SO4

What elements make up sulfuric acid and how many of each are there in one molecule of it?

A

2 x hydrogen
1 x sulfur
4 x oxygen

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22
Q

What is a redox reaction?

A

A redox reaction has both oxidation and reduction

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23
Q

What is oxidisation?

A

A loss of electrons

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24
Q

What is reduction?

A

A gain of electrons

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25
Q

What is a displacement reaction?
Give an example of solids which displace
Give an example of displacement in solution

A

.A more reactive metal displaces a less reactive metal from a compound.
Aluminium displaces iron from iron oxide giving aluminium oxide + iron.
Copper displaces silver in silver nitrate solution to give , copper nitrate + silver.

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26
Q

Is there conservation of mass during a chemical reaction?

A

In a chemical reaction, the atoms rearrange and join together in different ways.
As the same number of each type of atom is there at the end as there was at the start, then the mass doesn’t change.
If we think about the total number of each atom, we can see it stays the same.
So the mass will also stay the same – it is conserved.
This is true for any chemical reaction because atoms cannot be created or destroyed.

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27
Q

How do the group 1 metals react with water?

A

They all react violently fizzing around the top of the water, producing hydrogen and the metal hydroxide. The further down the group the more reactive they are
eg 2Li + 2H20 ——-> 2LiOH + H2

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28
Q

Explain the reactivity of the group 1 metals in terms of electronic configuration

A

The group 1 metals all have 1 electron in their outer shell, this makes them more reactive than group 2 as they have 2. They are trying to lose the electron in their outer shell to gain a stable electronic structure.
There is an attraction between the nucleus and the electron in the outer shell.
The further away the electron is from the nucleus the less the attraction so the easier it is to lose the electron.
The bigger the atomic mass the more shells there are and so the group 1 metals get more reactive the further down the group you go.

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29
Q

What are the vertical columns of the periodic table called, can you name some of them?

A

The vertical columns of the periodic table are called groups.
Elements in each group can be named:
Group 1: the alkali metals.
Group 7: the halogens.
Group 0: the noble gases.

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30
Q

Where in the periodic table are the transition metals?

A

The large block in the middle is called the transition metals.

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31
Q

Name some facts about the groups of the periodic table

A

Elements in each group have similar properties and patterns to each other. For instance:

Group 1, the alkali metals, are very reactive. They get more reactive as they go down the group.
Group 7, the halogens, are also reactive. They get less reactive as they go down the group.
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32
Q

What are the rows of the periodic table called? Do the elements in each row have any patterns? Name 2 patterns.

A

The horizontal rows of the periodic table are called periods.
Patterns can also be seen as you go along the periods.
The size of the atom decreases as you go from left to right along the period.
The elements get less metallic as you go from left to right.

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33
Q

Explain the reactivity of the group 7 halogens in terms of electronic configuration.

A

The group 7 halogens all have 7 electron in their outer shell, they are trying to gain an electron in their outer shell to gain a stable electronic structure.
There is an attraction between the nucleus and the electrons in the outer shell.
The further away the electron is from the nucleus the less the attraction so the harder it is to gain the electron. The closer the shells are to the nucleus the more the electron will be attracted.

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34
Q

What is the electronic structure of the noble gases

A

They all have completed outer shells and so are stable and non reactive

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35
Q

What is the structure of the halogens as elements?

A

They are diatoms, molecules containing two atoms
Cl2, Br2, I2

36
Q

Explain oxidation and reduction in terms of electronic structure

A

OIL oxidation is loss of electrons
RIG reduction is gain of electrons

37
Q

What are the colour changes during halogen displacement reactions

A
  1. If a brown colour is seen iodine has been produced
  2. if a yellow colour is seen bromine has been produced
38
Q

Explain how displacement of halogens occurs when they react with aqueous halide solutions?

A

A more reactive halogen can replace a less reactive one in an aqueous solution.
Chlorine cannot be displaced as it is the most reactive
Bromine can be replaced by chlorine.
iodine can be replaced by both bromine and chlorine

eg Br2 + 2KI —-> 2KBr + I2

39
Q

What is an aqueous solution?

A

A solution in which the solvent is water.

40
Q

Name 2 facts about the alkali metals

A

Alkali metals are all in group 1
Alkali metals are stored in oil to prevent them from reacting with the oxygen in the air.
When the alkali metals react with water they produce an alkaline solution.

The metals in Group 1 include (from top of the group to the bottom of the group):
    Lithium (Li).
    Sodium (Na).
    Potassium (K).
    Rubidium (Rb).
    Caesium (Cs).
    Francium (Fr).
41
Q

Give 6 properties of the alkali metals

A

1) Soft – they are easily cut with a knife. The further down the group, the easier they are to cut.
2) Low density – they are able to float on top of water. However the density increases as you go down the group.
3) The melting point of the alkali metals decreases as you go down the group
4) The boiling point of the alkali metals decreases as you go down the group.

5) The metals react with water producing the metal hydroxide and hydrogen.
6) As you go down the group, the metals get more reactive.

42
Q

List 4 facts about the halogens.

A

1) The halogens are found in Group 7.
2) They are a very dangerous set of elements.
3) If you breathe in the toxic gases they could cause death.
4) They can also cause burns on the skin that need to be treated at hospital.

The non-metals in group 7 include (from top of the group to the bottom of the group).
Fluorine (F).
Chlorine (Cl).
Bromine (Br).
Iodine (I).
Astatine (At).

43
Q

Name 3 properties of halogens

A

1) The colour of the halogens gets darker as you go down the group, as the atomic number increases.
2) The elements become less reactive as you go down the group, and have less energy.
3)At room temperature, the three states of matter occur within the group:

  • Fluorine and chlorine are gases.
  • Bromine is a liquid.
  • Iodine and astatine are solids.
    The density trend of the halogens is that they increase as you go down the group.
44
Q

What is diffusion

A

Process by which particles of gas or liquid spread out from an area of high concentration to a lower concentration. It therefore can be described as the net movement of particles.

45
Q

Give some examples of diffusion

A

Squash diffusing into water

46
Q

What is sublimation?

A

When a gas changes straight to a solid or a solid changes straight to a gas

47
Q

What is meant by the term solution?

A

A mixture of a solute and a solvent that doesn’t separate out.

48
Q

What is a solute?

A

the substance being dissolved

49
Q

What is a solvent?

A

the liquid the solute is dissolving into.

50
Q

Identify the units of solubility

A

g of solute per 100g of solvent

51
Q

What is meant by the term saturated solution?

A

A solution in which the maximum amount of solvent has been dissolved. Any more solute added will sit as crystals on the bottom of the container.

52
Q

Describe an experiment to determine the solubility of a substance at room temperature.

A

Eg sugar dissolving in water

  1. Measure 25cm3 of water into a beaker
  2. Add sugar 5 g at a time recording how much you have added
  3. Stir with a glass rod each time (try to maintain consistency)
  4. Keep adding solute until no more dissolves
  5. Record the total amount of solute added
53
Q

Name 3 factors affecting rate of dissolving?

A
  1. Temperature
  2. Surface area of solute
  3. Amount of stirring
54
Q

Explain the ammonia and hydrochloric acid diffusion experiment

A

1 Cotton wool soaked in ammonia is put at one end of a long glass tube
2.Cotton wool soaked in hydrochloric acid is put at the other end of a long glass tube
3. Bungs are placed in both ends of the tube.
4. A white ring of powder is observed.
5. The white powder is ammonium chloride formed by the reaction between particles of ammonia and hydrochloric acid.
6. This shows that particles of each substance have diffused along the tube.
7. The ring is closer to the end of the tube where the hydrochloric acid was placed because the particles of HCL have a greater molecular weight than NH3 so move more slowly.

55
Q

What is a displacement reaction?
Give an example of solids which displace
Give an example of displacement in solution

A

A more reactive metal displaces a less reactive metal from a compound.
Aluminium displaces iron from iron oxide giving aluminium oxide and iron
Copper displaces silver in silver nitrate solution to give , copper nitrate and silver.

56
Q

what is the order of the reactivity series?

A

potassium
sodium
lithium
calcium
magnesium
aluminium
zinc
iron
tin
lead
copper
silver
gold

57
Q

What is fractional distillation?

A

The method used to separate mixture liquids with different boiling points

58
Q

Describe how fractional distillation is used to separate different hydrocarbons from crude oil.

A
  1. The oil is heated and vapourised before it passes into the fractioning tower.
  2. The fractioning tower is hotter at the bottom than it is at the top.
  3. The hydrocarbons cool as they rise up the tower and condense at different heights due to their different boiling points. The lower boiling points condense higher up.
  4. The hydrocarbons with large molecules are collected at the bottom of the tower as liquids.
  5. Those with smaller molecules condense and are collected nearer the top.
  6. The very top of the tower collects liquid petroleum gas (LPG)
59
Q

What is chromatography?

A

Chromatography is used to separate mixtures which allows you to identify substances.
There are 4 different types
-paper
- gas
- thin layer
- column

60
Q

Describe the method for using paper chromatography for analysing substances.

A
  1. Draw a line in pencil just above the bottom of the filter paper, pencil is used as it does not dissolve in the solvent
  2. Place a small amount of each of the substances in spots on the pencil line
  3. The paper is hung in a beaker of solvent making sure that the pencil line is above the top of the solvent (prevents the substances dissolving in solvent)
  4. Allow the solvent to soak into and move up the paper.
  5. Take the paper out of the solvent when it gets near to the top of the paper and mark the solvent front- level where the solvent reached
  6. The paper is left to dry.
61
Q

Explain how paper chromotography can be used to analyse pure substances and mixtures.

A

If the substance is pure it will produce one spot, if it is impure two or more spots will be produced.

62
Q

Explain how Rf values in paper chromatography are calculated

A

The Rf value is the ratio of the distances traveled by the substance and the solvent. This is why marking the final position of the solvent before it dries is so important.
Each substance has a different Rf value in different solvents
1. On the chromatography paper measure the distance from the pencil line to the final position of the solvent.
2. Then measure the distance from the pencil line to the centre of a spot.

     distance traveled by the substance Rf =   -------------------------------------------------------
     distance traveled by the solvent Rf value is always < 1
63
Q

Identify the 8 different hydrocarbons produced during the fractional distillation of crude oil and give their uses. Work in order to top to bottom.

A
  1. refinery gases/ LPG - heating fuel for homes and business not on mains supply and fuel for some cars
  2. Petrol - for vehicles
  3. Naptha - used for making chemicals
  4. Kerosene - Aeroplane fuel/ jet engines
  5. Diesel - vehicles including buses and lorries
  6. Lubricating oil - used in engines
  7. Heavy fuel oil - used for some central heating systems and ships
  8. Bitumen - used for roads and on roofs.
64
Q

what are the equations for the complete combustion of hydrocarbons made simple

A

Complete combustion of a hydrocarbon happens when there is a good supply of air, so the maximum amount of energy is given out.
Hydrocarbon + oxygen → carbon dioxide + water.

65
Q

Describe the process of cracking

A

cracking is the process of splitting up long-chain hydrocarbons into short-chain hydrocarbons by heating.

1) long-chain hydrocarbon have a higher boiling point and are viscous.
2) short-chain hydrocarbon have lower boiling point and are thinner and paler.
3) short-chain hydrocarbons are higher in demand. ( petrol/ paraffin)
4) to meet this demand they split up the long-chain hydrocarbons into more useful molecules.
5) this is done by cracking which is a form of thermal decomposition.

66
Q

What is an alkane?

A

A saturated hydrocarbon made up of only single bonds. (saturated with hydrogen atoms)

67
Q

Why are shorter alkanes more in demand as fuels?

A

The shorter alkanes flow more easily, are more flammable and burn with a cleaner flame .

68
Q

How do the properties of an alkane change with increasing chain length?

A
  1. The longer the chain the more viscous the alkane (flow)
  2. Shorter alkanes (short chain) have a lower boiling point
  3. Shorter alkanes are more flammable (easier to ignite)
69
Q

Give an example of a chemical equation for cracking

A

C10H22 ——> C8H18 + C2H4
longer alkane becomes shorter alkane (used as fuel) plus alkene used to make useful substances such as polymers

70
Q

Explain the economic need for cracking

A

Cracking converts longchain alkanes which do not have many uses and are therefore not of high value into shorter chain alkanes and polymers which are more useful and therefore more in demand, commanding a higher market value.

71
Q

Explain the term incomplete combustion

A

Incomplete combustion occurs when a fuel is burnt in a limited supply of oxygen. When burning hydrocarbons this can result in carbon (soot) and/or carbon monoxide being produced instead of carbon dioxide.

72
Q

what can be produced due to incomplete combustion?

A

Acid rain. caused by sulfur dioxide and nitrogen oxides.

73
Q

How is sulphur dioxide SO2 formed

Give equations for the complete and incomplete burning of carbon disulphide

A

Carbon disulphide CS2 is found in small amounts in oil and burns when the oil burns

CS2 + 3O2 —> CO2 + 2SO2 complete combustion

2CS2 + 5O2 —> 2CO + 4SO2 incomplete combustion less oxygen

CS2 + 2O2 —> C + 2SO2 incomplete combustion even less oxygen

74
Q

How are the pollutants nitrogen oxides formed (NO and NO2)

A

Nitrogen in the air reacts with oxygen in the air when fuels are burnt at very high temperatures
N2 + O2 —–> 2NO
N2 +2O2 —–> 2NO2

75
Q

What is the difference between relative atomic mass and relative formula mass ?

A

Relative atomic mass (Ar) is of an element and can be found on the periodic table - the top number .
Relative formula mass (Mr) is of a compound and you add together the sum of all of the (Ar) of each element
eg C has a relative atomic mass of 12
CO2 has a relative formula mas of 12+16+16 = 44

76
Q

How do you find the % mass of an element in a compound?

A

1.Use a periodic table to find the Ar of the element and the Mr of the compound.
2. Ar/Mr x 100 will give the percentage

77
Q

What is a mole in chemistry?

A

The unit for the amount of a substance.

78
Q

What is the molar volume for RTP?

A

24000 cm 3 (cubed)

79
Q

What is the Avagadro constant?

A

The number of atoms, molecules or ions in one mole of a substance

It is 6.02 x 10 to the power 23

80
Q

How do you calculate the number of moles given the mass of a substance

A

moles = mass/ Mr

  1. Calculate the Ar or Mr value from the periodic table depending on whether it is an element or a compound
  2. Divide the mass by the Mr or Ar value

Eg how many moles are there in 112g of carbon monoxide
1. Mr of CO = 12 + 16 =28
2. 112/28 = 4 moles

81
Q

Element R is extracted from its oxide by reduction with hydrogen.
The equation for the reaction is:
3 H2 + RO3 → R + 3 H2O
The sum of the relative formula masses (Mr ) of the reactants (3 H2 + RO3) is 150
Calculate the relative atomic mass (Ar ) of R.
Relative atomic masses (Ar ): H = 1 O = 16 [2 marks]
Identify element R [1 mark]

A

6 H atoms = 6 x 1 = 6
3 O atoms = 3 x 16 = 48

150 - 6 - 48 = 96 therefore the relative atomic mass of element R is 96

R must be molybdenum

82
Q

How many atoms are there in a mole of any substance?

A

6.02 x 10 to the power 23

83
Q

How many atoms of each element are there in the molecule Ca(HCO3)2

A

Ca 1
H 2
C 2
O 6

84
Q

Finding an equation using the masses of the reactants and products involves 4 steps, what are they.

A
  1. Calculate the Mr for each product and reactant
  2. Divide the mass by the Mr to find the number of moles.
  3. Divide all of the answers by the smallest one then manipulate the number of moles using division or multiplication to make them all whole numbers keeping the ratios the same.
  4. When they are whole numbers you have the equation
85
Q

How can you tell how many moles of each substance there are in an equation?

A

The number before the formula of each reactant and product is the number of moles.