Isotonicity Flashcards
Freezing temperature of blood
-0.52°C
Kf
Cryoscopic constant
Kb
Ebullioscopic constant (melting-point )
Raoult’s law equations
For non-volatile solutes…
* P_solution = X_(solv) x P_(solv)
* P_total = P_solute + P_solvent
Henry’s equation
p2/p1 = S2/S1
C = kP
* k = Henry’s gas constant
* C = concentration of dissolved gas
* S = Solubility
* p = vapour pressure
* P= partial pressure
Collegiative properties
The properties affected by the increase of solute concentration in a solution.
- Freezing-point depression
- Boiling-point elevation
- Osmotic pressure increase
- Vapour pressure decrease
Freezing-point depression
ΔT = (m)(Kf)(i)
* m = Molality = mol/kg
* Kf = Cryoscopic constant
* i = Van’t Hoffs factor
- ΔT = The temp change from the solvent freezing-point to solution’s freezing-point
Boiling-point elevation
ΔT = (m)(Kb)(i)
* m = Molality = mol/kg
* Kb = Ebullioscopic constant
* i = Van’t Hoffs factor
- ΔT = The temp change from the solvent’s boiling temperature to the solutions boiling-point.
Isoosmoticity | Iso osmolarity
A system in which two solutions have an equal osmotic pressure as each other.
This is due to an equal amount of solute particles in both solutions
Van’t Hoff factor
The symbol for this value is i .
It is the number of species a compound can dissosiate to.
E.g. NaCl -> Na+ + Cl- ergo i=2