IR Frequencies Flashcards

1
Q

sp3 C-H

A

2850 - 2960 (s)

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2
Q

sp2 C-H

A

3010 - 3095 (w - m)

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3
Q

O=C-H (aldehyde)

A

2700 - 2900 (w)

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4
Q

sp C-H

A

3300 sharp (s)

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5
Q

N-H

A

3300-3500 (m)

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6
Q

O-H (free)

A

3590-3600 (s) sharp

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7
Q

O-H (normal H-bonded)

A

3200 - 3600 (s) broad

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8
Q

O-H (strongly H-bonded)

A

2500-3200 (s) broad

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9
Q

nitriles (RCN)

A

2200-2260 (v)

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10
Q

alkynes (RC≡CR’)

A

2150-2260 (w)

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11
Q

alkynes (RC≡CH)

A

2100-2140 (w)

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12
Q

Alkenes

A

1620 - 1680 (v)

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13
Q

Enones (C=C-C=O)

A

1590 - 1640 (s)

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14
Q

aromatics: one, two or three of:

A

1600, 1580, 1500 (v)

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15
Q

nitro (NO2)

A

1560, 1350 (s)

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16
Q

Carbonyl group (C=O) Standard

A

1715 ±10

16
Q

Carbonyl Group (aldehyde - H)

A

+15

16
Q

Carbonyl Group (anhydride - OCOR)

A

+35, +110

16
Q

Carbonyl Group (acid chloride - Cl)

A

+85

17
Q

Carbonyl Group (aryl ketone - Ar)

A

-25

18
Q

Carbonyl Group (enone C=C)

A

-35

19
Q

Carbonyl Group (amide - NH2)

A

-65

20
Q

Carbonyl Group (ester - OR)

A

+25

21
Q

Carbonyl Group (Carboxylic acid - OH)

A

0