IQ1 Flashcards

1
Q

what is an open system

A

exchange energy and matter with the surroundings

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2
Q

what is a closed system

A

only exchange energy with surroundings

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3
Q

what is an isolated system

A

do not exchange matter or energy with the surroundings

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4
Q

define dynamic equilibrium

A

rates of forward and backward reactions are equal and no macroscopic changes take place

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5
Q

define static equilibrium

A

a completion reaction involving limiting agent and rates of forward and backward reaction are zero

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6
Q

sharp decrease in one substance is due to

A

concentration

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7
Q

sharp increase in one substance is due to

A

concentration

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8
Q

gradual increase in all substances

A

temperature

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9
Q

gradual decrease in all substances

A

temperature

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10
Q

sudden decrease in all substances

A

pressure

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11
Q

sudden increase in all substances

A

pressure

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12
Q

When ๐›ฅ๐บ is negative

A

the reaction is spontaneous

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13
Q

When ๐›ฅ๐บ is positive

A

the reaction is non-spontaneous

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14
Q

When ๐›ฅ๐บ is 0

A

the reaction is at equilibrium

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15
Q

why isnโ€™t photosynthesis a equilibrium reaction

A

requires an input of energy and a catalyst to lower the activation energy in order to proceed
multi-step process
non-spontaneous as Gibbs free energy is greater than 0
change in entropy is less than 0 so becomes more ordered forming glucose molecules
open system

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16
Q

when โˆ†S<0

A

system is more ordered

17
Q

when โˆ†S>0

A

system is more disordered

18
Q

why isnโ€™t combustion a equilibrium reaction

A

negative value for Gibbs free energy
spontaneous reaction
energy is released and proceeds until oxygen is consumed
open system