ionisation energy Flashcards
def ionisation energy (no mol!!)
amount of energy needed to remove 1 electron from a GASEOUS atom
def FIRST ionisation energy
minimum energy (/mol) needed to remove the 1st electron from 1 mol of gaseous atoms to form 1 mol of gaseous singly positive IONS!!
factors affecting i.e (2)
nuclear charge (number of protons), atomic size (electron shells)
how does nuclear charge (number of protons) affect i.e
more protons –> nuclear charge becomes more +ve
attraction btw +vely charge nucleus & -vely charged electrons increases
–> i.e increases
how does atomic size (electron shells) affect i.e
more electron shells, dist of valence electrons from nucleus increases
attraction of +vely charged nucleus & -vely charged valence electrons decreases
–> i.e decreases
i.e across periods
same number of e shells, 1 additional proton
–> nuclear charge increases, increased force of attraction on all -vely charged electrons –> stronger force of attraction to protons
–> more energy needed to remove v electrons
–> i.e increases
i.e down groups
1 additional electron shell
–> atomic size increases, +vely charged nucleus further away from -vely charged v electrons
–> weaker force of attraction btw +vely charged nucleus & -vely charged v electrons
less energy needed to remove v electrons
–> i.e decreases
successive i.e’s
more energy is needed to remove an electron from a singly +ve ion
electrons are being removed from increasingly +ve ions
–> greater electrostatic foa btw +vely charged nucleus & -vely charged v electrons (2nd i.e > 1st i.e)