Ionisation Energy Flashcards

1
Q

Define ionisation

A

The conversion of an atom to an ion

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2
Q

Define the first ionisation energy

A

The energy needed to remove one mole of electrons from one mole of a gaseous element to form one mole of gaseous positive ions

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3
Q

What are the 3 factors that effect ionisation energy

A

Nuclear charge, distance of valence electron and shielding

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4
Q

What is nuclear charge

A

The attraction on the electrons surrounding the nucleus from the positive protons located within the nucleus of an atom or ion

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5
Q

What does nuclear charge depend on

A

Number of protons (the more protons the greater the nuclear charge)

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6
Q

What is the relationship between nuclear charge and ionisation energy

A

The greater the nuclear charge the greater the ionisation energy

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7
Q

how does the distance of valence electrons impact IE

A

as the atomic radi increases, the distance increases and so the attractions between the nucleus and the valence electrons decrease and so this tends to decrease IE

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8
Q

What is the shielding effects

A

It is the lowering of the nucleus pull/attraction on the electron furthest away from the nucleus due to electrons in closer energy shells

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9
Q

Why does the nucleus attract electrons

A

Because the nucleus has a positive charge whilst an electron has a negative charge and opposite charges attract

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10
Q

When is always needed to remove electrons

A

An input of energy

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11
Q

What is the general ionisation energy reaction

A

X(g) —> X+(g) + e-

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12
Q

How can you identify which ionisation energy the equation is

A

With whatever charge the ion created has

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13
Q

What is a successive ionisation energy

A

The 2nd 3rd 4th ect… ionisation energys

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14
Q

What happens the atomic radi when electrons are removed

A

Decreases

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15
Q

what do scientists use to study ionisation energies

A

Spectroscope

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16
Q

how is a spectroscope used to study ionisation energy

A

the light (electromagnetic waves) that are let out by atoms when they are heated, is studied

17
Q

what does a spectroscope physically show

A

bright lines on a black background

18
Q

what happens to atoms when heated

A

they get energy so the electrons jump to a higher energy level

19
Q

what is a line emission spectrum

A

where each line in the spectrum arises from the energy released as the electrons drop back from a a higher energy level to a lower level

20
Q

why is each elements spectrum different

A

bveacuse each element has its own characteristic set of lines as they are unique to themselves

21
Q

what does the line emission spectrum provide evidence for

A

the existence of quantum shells in an atom

22
Q

what doe successive ionisation energies provide evidence for

A

the existence of groups and subshells

23
Q

how does electron shielding work

A

the inner electron exerts a repulsion force on outer shell electrons and this reduces attraction to the nucleus

24
Q

what is the relationship between no of shells and shielding effect

A

the greater the no of shells, the greater the increase in shielding effect

25
Q

what is the relationship between shielding effect and IE

A

the higher the shielding effect, the lower the ionisation energy because there is a reduced attraction to the nucleus

26
Q

does it get more or less difficult to remove successive electrons from an atom?

A

more

27
Q

as the number of IE increases, the difficulty in removing electrons….

A

also increases

28
Q

what does successive IEs depend on

A

electronic configuration of the atom

29
Q
A