IONIC EQUILIBRIA AND BUFFERED SOLUTIONS Flashcards

1
Q

a substance that ionizes in water to produce hydrogen ions, H+

A

Arrhenius acid

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2
Q

a substance that dissociates in water to produce hydroxide ions, OH

A

Arrhenius base

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3
Q

acid is a proton (hydrogen ion) donor.

A

Brønsted-Lowry Acid

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4
Q

is a proton (hydrogen ion) acceptor.

A

Brønsted-Lowry base

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5
Q

Proton concept of Brønsted-Lowry

A

base + acid ↔ conjugate acid + conjugate base

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6
Q

The original BONDing Scientist

A

GILBERT N. LEWIS

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7
Q

electron-pair acceptor

A

Lewis Acid

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8
Q

electron-pair donor

A

Lewis base

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9
Q

Electron-pair concept

A

Lewis theory

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10
Q

Electron-pair concept

A

A substance that can act either as an acid or base

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11
Q
  • Numeric scale used to specify the acidity or alkalinity of an aqueous solution

The negative logarithm of H+ concentration

“power of hydrogen”

A

pH

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12
Q

Danish chemist in pH

A

Søren Peder Lauritz Sørensen in 1909

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13
Q

> pH 7
up to 14

A

Basic

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14
Q

=pH 7

A

Neutral

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15
Q

<pH7
down to o

A

Acidic

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16
Q

May be considered as weak acids or weak bases that exhibit color changes as their degree of dissociation varies with pH.

A

pH
indicators

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17
Q

Partially ionized in their solutions

A

Weak acids and bases

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18
Q

HCOOH

A

Formic

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19
Q

CH3COOH

A

Acetic

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20
Q

CC3COOH

A

Trichloroacetic

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21
Q

Hydrofluoric

A

HF

22
Q

Hydrocyanic

A

HCN

23
Q

Hydrogen Sulfide

A

H2S

24
Q

NH3

A

Ammonia

25
Q

N(CH3)3

A

Trimethyl Ammonia

26
Q

C5H5N

A

Pyridine

27
Q

NH4OH

A

Ammonium hydroxide

28
Q

NH4

A

Ammonium

29
Q

acid dissociation constant

A

Ka

30
Q

negative logarithm of Ka

A

pKa

31
Q

base dissociation constant

A

Kb

32
Q

negative logarithm of Kb

A

pKb

33
Q

pH = -log [H+]

A

Strong acids

34
Q

pOH = -log [OH]
pH = pKw - pOH

A

Strong bases

35
Q

pH> pKa
pH

A

High (Basic)

36
Q

pH> pKa
H+

A

Decreased

37
Q

pH> pKa
lonization

A

> 50% IONIZED

38
Q

pH<pKa
pH

A

Low (Acidic)

39
Q

pH<pKa
H+

A

Increase

40
Q

pH<pKa
lonization

A

> 50% UN-IONIZED

41
Q

pH = pKa
pH

A

Neutral

42
Q

pH = pKa
H+

A

H+= OH-

43
Q

pH = pKa
lonization

A

50% IONIZED 50% UN-

IONIZED

44
Q

lonized
Water Soluble

A

Water Soluble

45
Q

lonized
Lipid Membrane

A

DO NOT CROSS

46
Q

Un-lonized
Solubility

A

Water Insoluble

47
Q

Un-lonized
Lipid Membrane

A

CAN CROSS

48
Q

A solution that resists major change in pH when small amounts of strong acid or strong base are added

A typical huffer system contains a weak acid and its conjugate base

A

BUFFER SOLUTION

49
Q

Common biochemical buffer systems are

A

H2CO3/HCO3 −
H2PO4/HPO4 2+

50
Q

The buffer component that reacts with added base Reaction converts it into its conjugate base

A

Weak Acid

51
Q

The buffer component that reacts with added acid
Reaction converts it into its conjugate acid

A

Conjugate Base of Weak Acid