Investigating Solubility Flashcards

1
Q

How can you investigate how temperature affects solubility?

A
  1. Make a saturated solution by adding an excess of ammonium chloride to 10cm³ of water in a boiling tube. You will know when ammonium chloride is in excess because it will start to sink to the bottom of the tube.
  2. Give the solution a good stir and place the boiling tube in a water bath set to 25°C.
  3. After 5 minutes, check that all of the excess solid has sunk to the bottom of the tube and use a thermometer to check that the solution has reached 25°C.
  4. Weigh an empty evaporating basin. Pour some of the solution into the basin, making sure not to pour in any of the undissolved solid.
  5. Re-weigh the basin and its contents, then gently heat it using a Bunsen burner to remove all the water.
  6. Once all the water has evaporated, you’re left with pure ammonium chloride. Re-weigh the evaporating basin and its contents.
  7. Repeat steps 1-6 twice more, but with the water bath at different temperatures (e.g. 35°C and 45°C).
  8. You can use the different masses to work out the solubility at each temperature. Then you are able to plot the results on a graph.
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2
Q

In step 5, why should you not heat the basin too strongly?

A

If you heat the basin too strongly, some of the ammonium chloride might turn into a gas and escape. This will cause the mass of the solid in the basin to decrease, and your solubility value will be lower than it should be.

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3
Q

Why should you make sure that the solute is in excess in this experiment?

A

It’s important that you make sure the solute is in excess in this experiment, so that you end up with a saturated solution. If the solution is unsaturated, this means that more solute can be dissolved in the solvent, so the calculated solubility will be less than the true value.

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