introduction to transition elements Flashcards

1
Q

Why are Sc and Zn categorized as d block elements?

A

They have their highest energy electrons in a d sub shell/orbital.

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
2
Q

Give 3 typical properties of d block elements.

A

High mp/bp, shiny, good conductors of heat & electricity, malleable, ductile.

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
3
Q

What are common uses of iron?

A

Construction, tool production.

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
4
Q

What are common uses of copper?

A

Electrical cables, water pipes.

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
5
Q

What are common uses of titanium?

A

Aerospace industry, medical applications such as joint replacements.

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
6
Q

Why do copper and chromium not follow the normal pattern of filling 4s before 3d?

A

A half filled d5 sub shell and full d10 sub shell give additional stability to the atoms.

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
7
Q

Which electrons are lost first when d block elements form ions?

A

4s.

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
8
Q

Define ‘transition metal’.

A

A d block element which forms at least 1 ion with a partially filled d sub shell.

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
9
Q

Why are Sc and Zn not transition metals?

A

Sc only forms 3+ ion which has an empty d subshell; Zn only forms 2+ ion which has a full d subshell. Transition elements must have a partially filled d sub shell.

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
10
Q

State the 3 properties of transition metals that other metals do not have.

A

Variable oxidation states, coloured compounds, compounds and elements can act as catalysts.

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
11
Q

What colour is potassium dichromate?

A

Bright orange.

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
12
Q

What colour is cobalt II chloride?

A

Purple pink.

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
13
Q

What colour is nickel II sulphate?

A

Green.

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
14
Q

What does the colour of transition element compounds vary with?

A

Oxidation number.

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
15
Q

What is the catalyst in the Haber process?

A

Fe.

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
16
Q

What is the catalyst in the contact process?

A

V2O5.

17
Q

What is the catalyst in catalytic decomposition of hydrogen peroxide?

A

MnO2.

18
Q

What is a homogenous catalyst?

A

Catalyst and reactants are in same physical state.

19
Q

What is a heterogenous catalyst?

A

Catalyst is in different physical state to reactants.

20
Q

Why do Zn compounds dissolve to form a colourless solution?

A

Colour is associated with presence of a partially filled d orbital; Zn only forms Zn2+ ions; Zn2+ ions have a full d sub shell.