Introduction to Organic Chemistry Flashcards

1
Q

Define empirical formula

A

Simplest whole number ratio of atoms of an element in a molecule or compound

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2
Q

Define molecular formula

A

Gives the actual number of atoms of different elements in a molecule

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3
Q

Define displayed formula

A

Shows every atom and every bond in a molecule

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4
Q

Define structural formula

A

Shows arrangement of atoms in a molecule without showing every bond

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5
Q

Define skeletal formula

A

Drawn as lines with each vertex being a carbon atom. Carbon atoms not drawn, assumed each C atom has all unspecified bonds as C-H

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6
Q

Give the suffix for no double bonds

A

-ane

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7
Q

Give the suffix for at least one double bond

A

-ene

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8
Q

Give the suffix for an alcohol

A

-ol

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9
Q

Give the suffix for an aldehyde

A

-al

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10
Q

Give the suffix for a ketone

A

-one

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11
Q

Give the suffix for a carboxylic acid

A

-oic acid

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12
Q

Give the prefix for a CH3 group

A

methyl-

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13
Q

Give the prefix for a C2H5 group

A

ethyl-

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14
Q

Give the prefix for a C3H7 group

A

propyl-

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15
Q

Give the prefix for a C4H9

A

butyl-

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16
Q

Give the prefix for a Cl group

A

chloro-

17
Q

Give the prefix for a Br group

A

bromo-

18
Q

Give the prefix for a I Group

A

iodo-

19
Q

Define structural isomerism

A

When molecules have the same molecular formula but different structural formula

20
Q

What is positional isomerism?

A

Functional group is attached to the main chain at a different place

21
Q

What is functional group isomerism?

A

Same atoms but a different functional group due to a different arrangement of atoms

22
Q

What is chain isomerism?

A

Hydrocarbon chain organised differently e.g. branched chains

23
Q

Define stereoisomerism

A

When molecules have the same structural and molecular formula, but have a different arrangement of atoms in space

24
Q

What is E-Z isomerism and how are the E and Z isomers decided?

A

E-Z isomerism is caused by the limited rotation about C=C
double bonds
If the two substituents with the highest molecular mass are on
the same side of the double bond, it is the Z (zusammen)
isomer
If they are on different sides, it is the E (entgegen) isomer