Introduction Flashcards

1
Q

Scientific notation set up?

A

Coefficient
Base: always ten when dealing with scientific notation
exponent

Decimal goes after the first non-zero digit

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2
Q

Why do we use scientific notation?

A

It’s easier and more convenient and helps express numbers with the right number of sig figs.

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3
Q

Why do we use sig figs? Precision? Accuracy?

A

We use sig figs to communicate the precision of our measurements

Precision: same thing again and again.
Accuracy: the correctness of your answer. Less sig figs leads to less accuracy.

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4
Q

Sig fig rules?

A

All non-zero digits are significant.

Zeros between sig figs are significant.

Other zeros are significant if they come after a decimal and after a sig fig.

Exact values have an infinite number of sig figs (counted items and defined values like how 100cm is equal to 1 meter like in dimensional analysis)

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5
Q

Sig figs when using operations?

A

The sun or difference must have the same number of decimal places as the least precise measurement.

The product or quotient must have the same number of sig figs as the least precise measurements.

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6
Q

Measuring with correct sig figs?

A

Analog devices are not digital and we have to read them. We estimate to one digit.

Look at the bottom of the meniscus curve.

For digital measuring tools just record what’s given.

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7
Q

What did Democritus do?

A

Democritus who lived in Greece during the fourth century suggested that matter was made of tiny particles that can’t be divided. He called these tiny particles atoms. He was the first to suggest the existence of atoms that were indivisible and indestructible.

However, his ideas weren’t useful in a scientific sense as they did not explain chemical behaviour and lacked experimental support because his approach was not based on the scientific method.

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8
Q

Dalton?

A

The modern process of discovery about atoms began with the theories of an English school teacher named John Dalton.

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9
Q

John Dalton’s Atomic theory?

A

All elements are composed of tiny indivisible particles called atoms.

Atoms of the same element are identical and made of the same atom, but differ from the atoms of another element.

Atoms of different elements can physically mix together, or can chemically combine in simple, whole number ratios to form compounds

Chemical reactions occur when atoms are separated, joined, or rearranged; however, atoms of one element are never changed into atoms of another element by a chemical reaction.

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10
Q

How is the atomic theory that is accepted today different from Daltons atomic theory?

A

Atoms now are known to be divisible. They can be broken down into smaller particles called subatomic particles like electrons, protons, and neutrons.

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11
Q

Terms of Jj Thompson experiment? Cathode ray tube

A

Anode: an electrode with a positive charge.

Cathode: an electrode with a negative charge.

Cathode ray: a glowing beam travelling between charged electrodes.

Electron: a negatively charged particle.

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12
Q

Why does production of cathode rays not depend on the kind of gas in the tube or the type of metal used for the electrodes?

A

Electrons must be part of the atoms of all elements.

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13
Q

Robert Millikan?What two properties of an electron did Robert Millikan determine from his experiments?

A

Was a US physicist
Wanted to find the quantity of charge carried by an electrons and found them from experiments.

Using charge to mass ration, he calculated the mass of an electrons.

Charge and mass
Electrons carry exactly one unit of negative charge.
It’s mass is 1/1840 the mass of a hydrogen atom.

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14
Q

What is true about atoms, matter, and electric charge.

A

Electric charges are carried by particles of matter.

Electric charged always exist in whole number multiples of a single basic unit.

When positively charged particles combine with an equal number of negatively charged particles, and electrically neutral particle is formed.

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15
Q

Positively charged subatomic particle

A

Proton

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16
Q

What charge does a neutron carry

A

None/zero

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17
Q

Why does an alpha particle have a double positive charge?

A

It’s a helium atom that lost two electrons

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18
Q

Rutherford experiment b

A

1911 shot a beam of alpha particles through a thin sheet of gold foil

A lot of the alpha particles passed through the gold atoms without deflecting

A small fraction bounced off at big angles. Some even bounces strait back toward the source.

Originally there should have been slight deflection due to the positive charge thought to be spread out.

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19
Q

What is true about the nuclear theory of atomic suggested by Rutherford experiment.

A

An atom is mostly empty space

All the positive charge of an atom is concentrated in a small central region called the nucleus.

The nucleus is small compared with the atom as a whole.

Nearly all the mass of an atom is in it’s nucleus.

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20
Q

Elements are diff because?

A

Their atoms contain diff numbers of protons.

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21
Q

What is atomic mass?

A

Weighted average

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22
Q

Isotopes

A

Diff formed of elements that are chemically alike because the have the same number of protons and electron, but a different number of neutrons.

Diff neutrons means diff mass numbers.

But protons and electrons are responsible for chemical behaviour and they have the same amount so they are chemically alike.

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23
Q

Different types of hydrogen?

A

Hydrogen 1- hydrogen

Hydrogen 2- deuterium

Hydrogen 3- tritium

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24
Q

Why is AMU used instead of grams to express mass number.

A

In grams the number is too inconveniently small and impractical to work with. It’s more useful to compare the relative masses of atoms using a reference isotope as a standard.

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25
Q

What carbon isotope is the reference isotope for amu

A

Carbon-12
12.000 amu

26
Q

Does the atomic mass of an element always have to be a whole number of amu. How to calculate?

A

No

In nature most elements exists as a mixture of two or more isotopes.

Each isotope has a fixed mass and percent natural abundance.

The atomic mass of an element is a weighted average of a sample.

Take the mass of each isotope of the element and multiply it by its percent abundance and add the products to get the atomic mass.

27
Q

What is true about the average atomic mass of an element and the relative abundance of its isotopes?

A

In nature, most elements exist as a mixture of two or more isotopes.

The average atomic mass of an element is usually closer to that of the isotope with the highest abundance.

28
Q

In the period table, the elements are organized into groups based on?

A

A set of repeating properties.

So you could compare the property if an element to the properties of another group.

29
Q

What are horizontal rows called?

A

Periods

30
Q

Atomic number?

A

The number of protons in an atom

31
Q

What is mass number?

A

The number of protons plus the number of neutrons in an atom.

32
Q

Except for hydrogen-1 the mass number of an isotope is greater than its atomic number? Is the mass number reasonable?

A

Yes

33
Q

Isotopes?

A

Atoms with the same number of protons but different numbers of neutrons.

34
Q

Neutrons?

A

Subatomic particles with no charge

35
Q

Atom?

A

The smallest particle of an element that retains its identity in a chemical reaction

36
Q

Atomic Mass Unit?

A

Defined as 1/12 of the mass of a carbon-12 atom

37
Q

Group?

A

A vertical column of elements in a periodic table

38
Q

Nucleus?

A

Central core of an atom, which contains most of the atoms mass

39
Q

Periodic table?

A

An arrangement of elements according to similarities in their properties.

40
Q

Discovery of elements?

A

13 elements were discovered by the year 1700

Rate of discovery increased after 1700 as chemists began to use the scientific method to search for elements.

Chemists used the properties of elements to sort them into groups.

41
Q

Who is dmitri Mendeleev?

A

A Russian chemist who proposed a periodic table that could be used to predict the properties of undescovered elements.

He was writing a textbook a needed a way to show the relationship between 60 elements so he wrote the properties of the elements on a separate card and moved them around until the organization worked.

He called it the periodic table and organized it in order of increasing atomic mass.

42
Q

How are elements arranged in the modern periodic table?

A

In order of increasing atomic mass.

There are more elements at higher periods because there are more orbitals at higher energy levels.

43
Q

The periodic law?

A

When elements are arranged in order of increasing atomic number, there is periodic repetition of physical and chemical properties.

Move left to right, properties of the elements change, so it repeats every period.

44
Q

Henry Mosley

A

Determined the atomic number for each known element.

45
Q

Jw dobereiner

A

German chemist

Created a classification system where elements were grouped into triads: sets of 3 elements with similar properties.

Not all elements could be grouped into triads.

46
Q

Colour coding of squares and three main classes of elements?

A

Yellow is metals
Green is metalloids
Blue is non metals.

47
Q

Metals?

A

80%
Good for heat and electric current
Have a sheen and luster (reflects light)
All are solid at room temperature but mud yet
Ductile
Malleable

48
Q

Non-metals?

A

Greater variation in properties as compared to metals.

Mostly gasses at room temperature, sometimes solid.

Hard to describe one set of general properties.

Not malleable

Bad at conducting.

Except for carbon^

49
Q

Metalloids?

A

Properties are similar to both metals and non-metals.

It can behave like both metal and non-metal depending on conditions.

50
Q

What subatomic particle plays a key role in determining the properties of an element? Electron configuration groups?

A

Electrons

Noble gasses
Representative elements
Transition metals
Inner transition metals

51
Q

Jj Thompson experiment?

A

English physicist who discovered electrons

He passed electric currents through a gas at low pressure.

Gas was in a glass tube that had electrode metal discs at each end which were connected to an electricity source.

One electrode got a positive charge and one got a negative charge.

Resulted in a cathode ray that was made of electrons moving really fast. It was attracted to the anode and magnets and positive plates.

Electrons exist.

52
Q

Eugen Goldstein

A

Found rays travelling the opposite direction of cathode rays.

These were called canal rays composed of protons.

Provided evidence for protons

53
Q

James Chadwick

A

Neutrons have no charge but almost equal mass to a proton.

54
Q

What are all things made of? Flow chart

A

All things are either matter or energy.

Energy is not matter (light, sound, heat?

Matter is anything that has mass and occupies space. Could be either mixture or pure substance.

Mixtures could be homogenous (solutions) or heterogeneous (mechanical mixtures).

Pure substances are either elements (atoms) or compounds (molecules)

55
Q

What are molecules?

A

Particles of a compound.

56
Q

What are elements?

A

Pure substances found on the periodic table made up of atoms.

57
Q

What do models do?

A

A representation of what we know now and change over time as knowledge advances.

58
Q

Atomic number, atomic mass, chemical symbol?

A

Atomic number: the # of protons in each atom of an element.

Atomic mass: average mass of all the atoms of this element in the universe based on abundance of isotopes.

Chemical symbol: based on Latin names.

59
Q

Periodic table fun facts?

A

Arranged in order of increasing atomic #
Have repeating patterns of behaviour.
Hydrogen appears twice because it’s a non-metal that often behaves like elements in group 1.

60
Q

What does the staircase do?

A

Separate metals and non metals.

61
Q

How do you read the periodic table?

A

Horizontal rows are called periods.

Vertical columns are called groups or families.

Gr 1: alkali metals
Gr 2: alkaline earth metals
Gr 3-12 transition metals
Gr 7 halogens
Gr 8 noble inert gasses

62
Q

What are ions and how are they formed?

A

Ions are atoms with a charge.

Positively charged ions are called cations
Negatively charged ions are called anions.

Formed when an atom gains for loses electrons.