Introduction Flashcards

1
Q

Spectroscopy

A

Study of the interaction between light and matter through qualifying and quantifying radiation that is absorbed emitted or scattered.

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2
Q

Electromagnetic wave

A

A mutual induction of electric and magnetic fields. Which are generated by a moving charged particle and the flucuation between an electric and magnetic fields over time

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3
Q

Photon

A

An object btwn a particle and wave which has an energy proportional to the radiation wave frequency
E=hv
h is the Planck’s constant 6.626 x 10-34 J s

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4
Q

C
λ
v
T

A

C=Light Speed = 299,797,2 458 m/s C = λv
or 2998・10 5 m /s

λ = Wavelength = Distance of a single wave

v = Frequency = the number of wave maxima crossing an imaginary surface perpendicular to the propagation direction (s -1) or Hz (1 Hz = 1 s-1) V = 1/T

h =

T = Period = Period (s) the time the wave electric or magnetic field takes to complete an oscillation

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5
Q

Electric Field

A

Movement (attraction or repulsion) of a charged particle creates an electric force, An electric field is the result of a charged particle. The force of a particle divided by a charge

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6
Q

Magnetic field

A

A charged particle in motion creates a magnetic field. True source is the time changing electric field. A force divided by a charge and by a velocity

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7
Q

Light Intensity - as a particle

A

Energy carried in a unit per time per space. Density of photons by the speed of light. Measured as W/m2
I = Uc

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8
Q

c =λv

A

Wavelength and frequency are always
inversely proportional so 𝜆 = 𝑐/𝜈 and 𝜈 = 𝑐/𝜆
and Wavenumber 𝜈’ = 1/
𝜆

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9
Q

E = hv

A

Einstein’s law of photon
energy)
This formula gives the energy which a photon carries. Energy = Planks constant (h) times frequency or E = hc/λ

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10
Q

Light Intensity
I = Uc

A

Intensity (as a particle) = Radiation energy density (U=Ed) * speed of light.

Intensity (as a wave) = ½ c e0E0^2
b/c U as a wave = ½
e0*E0^2
Where E0 is the maximum electric field value of the radiation.

The energy carried by radiation through 1 m 2 in 1 s. It is proportional to the square of the electric field.

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11
Q

h or Planks Constant

A

6.626 ・ 10-34 J s
Defines the quantum nature of energy and relates the energy of a photon to its frequency

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12
Q

Chemical symbol of elements

A

A = top left = Mass number. The number of neutrons +
protons present in the nucleus.

Z = bottom left = Atomic number which is equal to the number of neutrons in the atom. Atoms with the same
atomic number are chemically identical

X = Chemical symbol of an element expressed as Letter(s)

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13
Q

Proton, Neutron, Electron

A

Neutron = Mass is 1.6748 x 10^-24 g Charge is neutral

Proton = Mass is 1.6725 x 10^-24 g Charge is + 1 e, corresponding to +1.602 x 10-19 C

Electron = mass is 9.108 x 10^-28 g charge is -1 e, corresponding to -1.602 x 10^-19 C

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14
Q

Atomic mass unit
Amu or u

A

The mass corresponding to 1/12 of the mass of the
isotope 12C. Carbon12 equals 12u.
1 u = 1.661 x 10^-24 g

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15
Q

Isotope

A

Atoms having the same atomic number, but different mass number, i.e., the same
number of protons, but different number of neutrons.

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16
Q

Cations and Anions

A

Cations = Ions with positive charge = less electrons than pro

Anions = Ions with negative charge = more electrons than pro

An atom is more or less likely to become a cation or anion according to its atomic number. The atoms on the top-right of the periodic
table are called non-
metals, and are electron-withdrawing. The atoms on the bottom-left are metals,
and loose easily electrons.

17
Q

Ionic bond or compound

A

Chemical bound formed by positive and negative ions, which attract each other, building up an ordered, periodical structure.

18
Q

Covalent bond

A

Sharing of a couple of electrons. The shared electrons stay exactly in the middle of the two atoms. The electrons act as a «glue» (bonding electrons)

19
Q

Polar Covalent bond

A

When atoms are not identical and non metals a covalent bond occurs which has unequal “pull” towards atom with the greater electron withdrawing capability. So positive charge on one
atom and a partial negative charge on the other. The two partial charges are equal in value, but opposite in sign, which results in a contribution of electrostatic attraction between the two atoms

20
Q

Electronegativity

A

Tendency for an atom of a given chemical element to attract the shared
electrons in a chemical bond. If difference is 0 = covalent, if > 2 = ionic, if < 2 = polar covalent

21
Q

Molecule

A

A group of two or more atoms, united each other with covalent or polar covalent bonds

22
Q

Chemical compound

A

Microscopic definition: a pure substance formed by two or more atoms, chemically different, occurring with well-defined proportion in any point of the substance.

Macroscopic definition: a pure substance formed by two, or more, different chemical elements, with a defined proportion determining composition

can be covalent, polar, or ionic