Introduction Flashcards

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1
Q

not a p-block element

A

He

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2
Q

group 1

A

alkali metal

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3
Q

group 2

A

alkaline earth metals

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4
Q

group 18

A

inert gases
noble gases
zero group

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5
Q

group 17

A

halogens

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6
Q

group16

A

calcogens

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7
Q

group 15

A

pnictogens

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8
Q

metalloids

A

B, Si, Ge, Ar, Sb, Te, Po

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9
Q

d-block

A

transitional elements

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10
Q

f-block

A

inner transitional elements

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11
Q

s and p block

A

representative elements

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12
Q

magic numbers

A

2,8,8,18,18,32,32

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13
Q

low MP metals

A

Ga, Cs, Hg

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14
Q

lusturous non-metal

A

I

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15
Q

non-conductor of heat and electricity (metal)

A

Bi, Pb

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16
Q

electricity conducting non-metal

A

graphite

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17
Q

heat conducting non-metal

A

diamond

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18
Q

high MP and BP non-metal

A

B and C

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19
Q

low density metal

A

Li

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20
Q

shielding effect along the period

A

decreases

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21
Q

shielding effect down the group

A

decreases

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22
Q

order of atomic radius

A

10^-10 m

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23
Q

order of nucleus

A

10^-15 m

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24
Q

Rv, Rm, Rc (compare)

A

Rv > Rm > Rc

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25
Q

atomic radius along the period

A

decreases

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26
Q

atomic radius down the group

A

increases

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27
Q

largest element in a period

A

noble element

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28
Q

M, M+, M- (atomic radius compare)

A

M- > M > M+

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29
Q

ionisation enthalphy along the period

A

increases

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30
Q

ionisation enthalphy down the group

A

decreases

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31
Q

I.E.1, I.E.2 (compare)

A

I.E.1 < I.E.2

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32
Q

I.E. is always

A

endothermic

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33
Q

Be > B

A

full filled s-subshell

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34
Q

N > O

A

half filled p-subshell

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35
Q

order of shielding power

A

ns > np > nd > nf

36
Q

compare size of 4d and 5d elements (except Y , La)

A

nearly same due to poor shielding of 4f element

lanthanide contraction

37
Q

compare I.E. of 4d and 5d elements (except Y , La)

A

5d > 4d

38
Q

compare density of 4d and 5d elements (except Y , La)

A

5d > 4d

most densest metals of the periodic table are found in 5d series.

39
Q

inert pair effect

A

due to poor shielding of 4f sub-shell, lower oxidation state become more stable

40
Q

Ga > Al comparing I.E.

A

first time entry of d orbitals

d block contraction

41
Q

Ga < Al comparing atomic radius

A

first time entry of d orbitals

d block contraction

42
Q

Tl > In comparing I.E.

A

lanthanide contraction

43
Q

electron gain enthalphy along the period

A

increases

44
Q

electron gain enthalphy down the group

A

decreases

45
Q

E.G.E. is endothermic for

A

noble gas
Be, Mg
Zn, Cd, Hg

46
Q

nitrogen have low E.G.E.

A

half filled sub-shell

47
Q

maximum E.G.E.

A

Cl

48
Q

2nd maximum E.G.E.

A

F

49
Q

in calcogens, maximum E.G.E.

A

S

50
Q

in calcogens minimum E.G.E.

A

O

51
Q

2nd E.G.E. is always

A

endothermic

52
Q

1st E.G.E. positive then E.A. is

A

0

53
Q

highest E.A.

A

Cl

54
Q

pauling scale

A

Δ=(EA−B)​−(EA−A​×EB−B​)
energy in kJ/mol
​EN(A) - EN(B) = 0.1017 (Δ1/2)

55
Q

pauli assigned an arbitrary value to most EN elements as

A

F (4)

56
Q

ideology of pauli

A

more EN diff. > more polarity> more partial charges > % ionic chac.

57
Q

Hannay-smith formula

A

% ionic=16(XA−XB)+3.5(XA−XB)2

58
Q

ideology of hannay-smith

A

more EN diff. > more polarity> more partial charges > % ionic chac.

59
Q

stevenson schomaker formula

A

dA-B = rA + rB – 0.09 (xA – xB)

60
Q

ideology stevenson schomaker

A

En diff > bond length(dA-B)

61
Q

ideology of mulkin jaffe scale

A

En > ionisation and E.A.

62
Q

mulkin jaffe fromula

A

X = I.P. + E.A. / 2

63
Q

relation between paulin and mulkin

A

Xm = 2.8 * Xp

64
Q

allred rochow scale

A

X = 0.744 + 0.359 Zeff/r2

65
Q

ideology of allred rochow

A

E.N. > Zeff / r^2

66
Q

metallic nature along the period

A

decreases

67
Q

metals are

A

good reducing agent

68
Q

non-metals are

A

good oxidising agent

69
Q

diagonal relationship

A

Li Be B

Mg Al Si

70
Q

normal oxide

oxidation state of oxygen

A

-2

71
Q

super oxide

oxidation state of oxygen

A

-1/2

72
Q

per oxide

oxidation state of oxygen

A

-1

73
Q

basic strength along the period

A

decreases

74
Q

basic strength down the grp

A

increases

75
Q

acidic strength down the group

A

decreases

76
Q

acidic strength along the period

A

increases

77
Q

amphoteric oxides

A

act as both acidic and basic oxide

78
Q

neutral oxides

A

neither act as acidic nor as basic oxide

79
Q

metals that form amphoteric oxides

A
Be
Al
Zn
Sn
Pb
Ga
Sb
80
Q

examples of neutral oxides

A

CO
N2O
NO
H2O

81
Q

oxidation state is directly proportional to

A

acidic strength

electronegativity

82
Q

naming of oxides

A

hypo_ous
_ous
_ic
per_ic

83
Q

naming of ions

A

hypo_ite
_ite
_ate
per_ate

84
Q

if electronegativity of A is greater than _____, then it is usually acidic

A

1.7

85
Q

thermal stability down the group

A

decreses