Intro To Electroanalytical Chem Flashcards
How do potentials arise in chemistry
How is it cause
Due to a buildup of electrons (charge)
Caused by redox rxns
What is the anode
What does it mean
Oxidation
Loses electrons
Leo
What is the cathode
What happens to it
Reduction
Gain electrons
Ger
Who do you convert reduction potential to oxidation potentials
Flip the sign
What is the potential of the SHE
what are all standard reduction potentials relative to
0V
RELATIVE TO THE SHE
What are galvanic cells
Two half cells that help measure the voltage (potential difference) between two electrodes
What is voltage
A measure of the tendency to be reduced or oxidized
From a diagram to see which is the anode and cathode:
- side of voltmeter is anode oxidation loss
+ side of voltmeter is cathode reduction gain
What is measure and controlled in
Potentiometer
Amperometry
Voltammetry
Direct coulometry
Conductometry
Impedimetry
E i=0
i (current) E
i=f(t) E=f(t)
——
Conductivity
Electrical impedance E= constant+f(t)