inorganic definitions Flashcards

1
Q

Relative isotopic mass

A

The mass of an atom relative to the mass of 1/12th of the mass of carbon-12.

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2
Q

Relative atomic mass

A

The weighted mean mass of an atom relative to 1/12th of the mass of an atom of carbon-12.

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3
Q

Bronsted-lowry acid

A

A species that is a proton, H+, donor.

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4
Q

Bronsted-lowry base

A

A species that is a proton, H+, acceptor.

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5
Q

Acid

A

A species that releases H+ ions in aqueous solution.

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6
Q

Base

A

A compound that neutralises an acid to form a salt.

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7
Q

Coordination number

A

The total number of coordinate bonds formed between a central metal ion and ligands.

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8
Q

First electron affinity

A

The enthalpy change that takes place when one electron is added to each atom in one mole of gaseous atoms to form one mole of gaseous 1- ions.

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9
Q

First ionisation energy

A

The energy required to remove one electron from each atom in one mole of gaseous atoms of an element to form one mole of gaseous 1+ ions.

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10
Q

Ligand

A

A molecule or ion that can donate a pair of electrons to the transition metal ion.

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11
Q

Ligand substitution

A

A reaction in which one or more ligands in a complex ion are replaced by different ligands.

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12
Q

pi bond

A

A bond formed by the sideways overlap of 2 p orbitals, with the electron density above and below the plane of the bonded atoms.

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13
Q

sigma bond

A

A bond formed by the sideways overlap of one orbital from each bonding atom, consisting of 2 electrons with the electron density centred around a line directly between the nuclei of the 2 atoms.

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14
Q

Electronegativity

A

A measure of the attraction of a bonded atom for the pair of electrons in a covalent bond.

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15
Q

Transition element

A

A d-block element which forms an ion with an incomplete d sub-shell.

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16
Q

standard enthalpy change of atomisation

A

The enthalpy change that takes place when one mole of gaseous atoms forms from the elements in its standard state.

17
Q

standard enthalpy change of combustion

A

The enthalpy change that takes place when one mole of a substance reacts completely with oxygen under standard conditions, all reactants and products being in their standard states.

18
Q

standard enthalpy change of formation

A

The enthalpy change that takes place when one mole of a compound is formed from its constituent elements in their standard states under standard conditions.

19
Q

standard enthalpy change of hydration

A

The enthalpy change that takes place when one mole of isolated gaseous ions is dissolved in water forming one mole of aqueous ions under standard conditions.

20
Q

standard enthalpy change of neutralisation

A

The enthalpy change that accompanies the reaction of an acid by a base to form one mole of H2O(l) under standard conditions with all reactants and products in their standard states.

21
Q

standard enthalpy change of reaction

A

The enthalpy change that accompanies a reaction in molar quantities expressed in a chemical equation under standard conditions with all reactants and products being in their standard states.

22
Q

standard enthalpy change of solution

A

The enthalpy change that takes place when one mole of a compound is completely dissolved in water under standard conditions.