inorganic definitions Flashcards
Relative isotopic mass
The mass of an atom relative to the mass of 1/12th of the mass of carbon-12.
Relative atomic mass
The weighted mean mass of an atom relative to 1/12th of the mass of an atom of carbon-12.
Bronsted-lowry acid
A species that is a proton, H+, donor.
Bronsted-lowry base
A species that is a proton, H+, acceptor.
Acid
A species that releases H+ ions in aqueous solution.
Base
A compound that neutralises an acid to form a salt.
Coordination number
The total number of coordinate bonds formed between a central metal ion and ligands.
First electron affinity
The enthalpy change that takes place when one electron is added to each atom in one mole of gaseous atoms to form one mole of gaseous 1- ions.
First ionisation energy
The energy required to remove one electron from each atom in one mole of gaseous atoms of an element to form one mole of gaseous 1+ ions.
Ligand
A molecule or ion that can donate a pair of electrons to the transition metal ion.
Ligand substitution
A reaction in which one or more ligands in a complex ion are replaced by different ligands.
pi bond
A bond formed by the sideways overlap of 2 p orbitals, with the electron density above and below the plane of the bonded atoms.
sigma bond
A bond formed by the sideways overlap of one orbital from each bonding atom, consisting of 2 electrons with the electron density centred around a line directly between the nuclei of the 2 atoms.
Electronegativity
A measure of the attraction of a bonded atom for the pair of electrons in a covalent bond.
Transition element
A d-block element which forms an ion with an incomplete d sub-shell.
standard enthalpy change of atomisation
The enthalpy change that takes place when one mole of gaseous atoms forms from the elements in its standard state.
standard enthalpy change of combustion
The enthalpy change that takes place when one mole of a substance reacts completely with oxygen under standard conditions, all reactants and products being in their standard states.
standard enthalpy change of formation
The enthalpy change that takes place when one mole of a compound is formed from its constituent elements in their standard states under standard conditions.
standard enthalpy change of hydration
The enthalpy change that takes place when one mole of isolated gaseous ions is dissolved in water forming one mole of aqueous ions under standard conditions.
standard enthalpy change of neutralisation
The enthalpy change that accompanies the reaction of an acid by a base to form one mole of H2O(l) under standard conditions with all reactants and products in their standard states.
standard enthalpy change of reaction
The enthalpy change that accompanies a reaction in molar quantities expressed in a chemical equation under standard conditions with all reactants and products being in their standard states.
standard enthalpy change of solution
The enthalpy change that takes place when one mole of a compound is completely dissolved in water under standard conditions.