Inorganic 2: Group 2 Flashcards

1
Q

What ions do group 2 elements form?

A

2+ ions

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2
Q

Why are group 2 elements called alkaline earth metals?

A

Their oxides and hydroxides are alkaline
Are found in the Earth’s crust

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3
Q

Describe the trend in reactivity down group 2.

A

Reactivity increases as you go down the group

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4
Q

What are CaO and Ca(OH)2 used for?

A

Neutralising acids in soil
Most plants have an optimum level of acidity or alkalinity

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5
Q

How does magnesium react with water and steam?

A

Reacts very slowly with cold water, but rapidly with steam

Mg(s) + H2O(g) –> MgO(s) + H2(g)

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6
Q

How does calcium react with water?

A

More vigorously than magnesium
Ca(s) + 2H2O(l) –> Ca(OH)2 + H2(g)

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7
Q

Describe trend in reactivity of group 2 elements with water.

A

Reactivity increases
M(s) + 2H2O(l) –> M(OH)2(aq) + H2(g)

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8
Q

Describe trend in solubility of hydroxides down group 2.

A

Solubility of hydroxides increases down group 2

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9
Q

Describe the solubility of Mg(OH)2.

A

Almost insoluble

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10
Q

What is Mg(OH)2 used for?

A

Milk of magnesia
Used to treat indigestion

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11
Q

Describe solubility of Ca(OH)2.

A

Sparingly soluble

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12
Q

Describe solubility of Ba(OH)2.

A

Strongly alkaline solution
Ba(OH)2(s) + H2O(l) –> Ba2+(aq) + 2OH-

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13
Q

Describe the trend in solubility of sulfates down group 2.

A

Solubility decreases
MgSO4 is soluble
BaSO4 is virtually insoluble

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14
Q

What is BaSO4 used for in medicine?

A

Barium meal
Outlines the gut in medical X-Rays

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15
Q

What is BaSO4 used for in chemistry?

A

As a test for sulfate ions
1) Acidify sample solution with HNO3 or HCl to remove carbonate ions as CO2, as carbonate ions would also form a white precipitate
2) Add BaCl2 to the sample solution
3) A white precipitate of BaSO4 will form if sulfate ions are present

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16
Q

Describe the bonding of group 2 metals.

A

Giant metallic lattice
Positive (2+) ions
In a sea of delocalised electrons
Forms strong electrostatic attraction

17
Q

Describe how magnesium is used to extract titanium.

A

1) TiO2 converted into TiCl4:
TiO2 + 2Cl2 + 2C –> TiCl4 + 2CO

2) TiCl4 purified in fractional distillation, and then reacted with magnesium:
TiCl4 + 2Mg –> Ti + 2MgCl2

18
Q

Why is titanium expensive?

A

Magnesium is expensive
Batch process
High temperatures needed

19
Q

What is CaO used for?

A

removing SO2 from waste gases