Infrared Spectroscopy Wavenumbers Flashcards
C-H stretch frequency
3000cm-1
C-O stretch frequency
1100cm-1
C-Cl stretch frequency
700cm-1
C—O frequency
2143cm-1
C–O frequency
Anywhere between 1900-1500cm-1
Frequency region of bonds to hydrogen
4000-3000cm-1
Triple bond region frequency
3000-2000cm-1
Double bond region frequency
2000-1500
Single bond region frequency
1500-1000cm-1
N-H stretch frequency
3300cm-1
O-H stretch frequency
3500cm-1
True or false, an antisymmetric stretch is at a lower frequency than a symmetric stretch
False. An antisymmetric stretch requires more energy therefore is at a slightly higher frequency.
Terminal alkyne C-H differences to regular alkyne C-H stretches
Terminal alkyne stretches have shorter stronger peaks
Nitrile frequency
2250cm-1
Alkyne frequency
2100
Hydrogen bonded O-H frequency and shape
3500-3000cm-1
Broad peak
C-H terminal alkyne frequency
3300cm-1
Most important absorption in the double bond region?
Carbonyl
C–C stretch frequency and intensity
Weak band at 1640cm-1
NO2 band frequency and intensity
2 strong peaks in the mid 1500s and 1300s
Arene frequency
2-3 peaks in the 1600-1500cm-1 region
Define a strong absorption….
A stronger absorption gives rise to a more intense peak.