Impression Materials (2) Flashcards
What are the categories of impression material types? Which are we focused on?
Rigid or Brittle
Plastic
*Elastic - but really viscoelastic
What are the different types of hydrocolloids?
Reversible (agar)
Irreversible (Alginate)
What are the basic categories of polymers
Thermoplastic
Termoset
Termoplastic polymers
No cross-linking
Physical state is reversibly controlled by temperature - fluid when heated, and harder when cooled
Thermoset polymers
Transformation from monomer to polymer involves irreversible cross-linking
Synthetic elastomers
Oligomers polymerize into elastomers
What are the physical phenomena that occur during polymerization
Advantageous final properties are increased
Inherent density increase, causing a volumetric contraction
Heat of reaction causes material to heat up
There is a contraction on cooling
Polysulfide
Low molecular weight oligomers
Conform well to a prepped tooth, resulting in good surface detail
What oxidizes polysulfide?
Lead dioxide or copper hydroxide to form a polysulfide rubebr
What helps a polysulfide impression be accurate?
Rigid custom tray for minimal thickness of impression material
Silicones are inherently ____________
Hydrophobic
What type of silicones can be made hydrophilic? How?
The addition type.
By the simple addition of surfactant or
Chemical incorporation of hydrophilic moieties to the silicone backbone
What is the contact angle important for?
Unset impression material over wet structures
Unset gypsum-water mix into set impression
What are the requirements of Ideal impression materials
Low cost
Long shelf life
Biocompatibility
Pleasant to the patient
What properties of an impression are ideal before setting
Ease of manipulation
Control over working time
Good wetting on moist oral structures