IMF Flashcards

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1
Q

What factors increase as you move from left to right across the periodic table?

A

Atomic/Proton number, Atomic mass, Electronegativity, Ionization energy.

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2
Q

Describe the elements on the left of the periodic table.

A

Because they have low ionization energies, they easily lose electrons and become cations.

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3
Q

Define intramolecular forces.

A

They hold atoms together within a molecule.

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4
Q

Name the types of intramolecular forces.

A

Ionic bonds and Covalent bonds, the latter which is sub-typed into Nonpolar, Polar, and Metallic.

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5
Q

Define intermolecular forces.

A

They are forces that exist between molecules, and are therefore much weaker than intramolecular forces.
Intermolecular forces are electrostatic in nature and include van der Waals forces and hydrogen bonds

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6
Q

Name the types of intermolecular forces.

A

Dipole-dipole interaction, which is sub-typed into Hydrogen bonding, Ion-dipole interaction, and London dispersion.

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7
Q

When does a dipole-dipole interaction occur?

A

When a partially negatively charged parts of a molecule interacts with a partially positively charged part of a neighboring molecule.

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8
Q

When does hydrogen bonding occur?

A

It occurs specifically between an H atom bonded to an O (Oxygen), N (Nitrogen), or F (Fluorine).

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9
Q

When does London dispersion occur?

A

It occurs between all kinds of molecules, however, they are stronger in molecules with more electrons. They are only temporary on induced dipoles.

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10
Q

Describe the relative strength of dipole-dipole interactions.

A

Strong.

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11
Q

Describe the strength of hydrogen bonds.

A

They are the strongest of the dipole-dipole bonds.

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12
Q

Describe the strength of London dispersion forces.

A

They are the weakest intermolecular force.

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13
Q

Where are ion-dipole bonds evident?

A

They are evident in solutions because they are the forces that allow polar solvents to dissolve ionic substances.

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14
Q

What is electronegativity?

A

Electronegativity is the tendency for an atom to attract shared electrons.

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15
Q

What does the octet rule state?

A

It states that atoms tend to form compounds in ways that give them eight valence electrons and thus the electron configuration of a noble gas.

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16
Q

Describe what occurs between atoms in covalent bonds.

A

Two atoms share electrons to fill their outer shells.

17
Q

Describe what occurs between atoms in ionic bonds.

A

One atom loses one or more electrons and the other atom gains one or more electrons.

18
Q

What is the main reason that atoms form ions?

A

To fill their outer electron shells.

19
Q

What does bond polarity refer to?

A

Bond polarity refers to the polarity of covalent BONDS. It is responsible for such formation.

20
Q

What does molecular polarity refer to?

A

Molecular polarity refers to the polarity of covalent COMPOUNDS. It is responsible for such formation.

21
Q

What does bond polarity depend on?

A

Electronegativity values.

22
Q

What does molecular polarity depend on?

A

Molecular geometry.

23
Q

What cause London dispersion forces?

A

The movement of electrons.

24
Q

What strengthen London dispersion forces?

A

Molecular mass and shape. The bigger they are, the stronger the force.

25
Q

What strengthen dipole-dipole forces?

A

An increase in electron count and atomic mass, a decrease in distance between atoms.

26
Q

How does a molecule’s structure influence its boiling point?

A

The more linear a molecule is, the higher its boiling point.