IGCSE Edexcel- Chemistry: Chemical Analysis Flashcards
Oxygen
glowing splint relights
Hydrogen
lit splint combusts with a pop
Carbon dioxide
bubble through colorless limewater, turns cloudy due to formation of white ppt
Chlorine
damp blue litmus paper bleaches white
Ammonia
damp red litmus paper turns blue, add HCl white solid
Water
anhydrous copper sulfate white to blue, anhydrous cobalt(II) chloride paper blue to pink
Hydrogen chloride
damp blue litmus paper turns red, add Ammonia white smoke (solid)
Alkenes
bromine water orange to colorless
Hydrogen ions
add indicator, reactive metal/carbonate effervesces
Li+
Red
Na+
Yellow
K+
Lilac
Ca²+
Orange red, Brick red
add sodium hydroxide dropwise then in excess formation of white ppt
Cu²+
Blue green,
add sodium hydroxide dropwise then in excess formation of blue ppt
Ba²+
Apple green
NH₄+
add sodium hydroxide and heat. no precipitate, smells of ammonia. Ammonia gas released turns damp red litmus blue
Fe²+
add sodium hydroxide dropwise then in excess formation of green ppt turns brown on standing
Fe³+
add sodium hydroxide dropwise then in excess formation of brown ppt
Mg²+
add sodium hydroxide dropwise then in excess formation of white ppt
CO₃²-
add acid effervescence milky limewater due to white ppt
SO₄²-
add dilute HCl then barium chloride white ppt of BaSO₄ forms
Cl-
add dilute HNO₃ then AgNO₃ white ppt
Br-
add dilute HNO₃ then AgNO₃ cream ppt
I-
add dilute HNO₃ then AgNO₃ pale yellow precipitate
OH-
damp red litmus turns blue
thermal decomposition of CuCO₃
green to black
thermal decomposition of ZnCu₃
white to yellow (white on cooling)
Soluble
All Nitrates, sodium, potassium, ammonium, all chlorides except Ba and Pb(II), all sulfates except Ba, Ca, Pb(II)
Insoluble
all carbonates and hydroxides except sodium, potassium and ammonium