Identifying elements Flashcards
qualitative and quantitative methods
1
Q
What is emission spectroscopy
A
- all elements have specific energy levels
- electrons exist in the lowest possible energy level
- when energy is supplied, it’s absorbed by the electrons and they jump to a higher level (excited state)
- but this is unstable so it quickly drops back to a lower energy level
- when it does this, it releases energy in the form of light of a specific frequency
- then a spectroscope is used to separate frequencies to form an emission spectral lines
- can be used to identify elements
2
Q
What is the flame test?
A
- all elements have specific energy levels
- electrons exist in the lowest possible energy level
- when they’re heated, the energy is absorbed by the electrons and they jump to a higher level (excited state)
- but this is unstable so it quickly drops back to a lower energy level
- when it drops, it emits a specific coloured flame, with a specific wavelength of light
- the colour can be used to identify the element
3
Q
Atomic absorption spectroscopy:
A
- it uses light absorption to measure the amount of an element present in a sample
Steps:
1. Element is analysed using a qualitative method - helps to focus on just one element
2. Light of the correct wavelength is generated - using a hollow cathode lamp made of the element being detected so that it generates the correct wavelength
3. Sample is vaporised - done by spraying liquid form into an energy source turning it into individual atoms
4. The light passes through the sample - only the element being tested will absorb it
- greater concentration = more light absorbed
5. Light that passes through is focused through a slit and enters a monochromator - separates absorbed wavelengths from others
6. The specific selected wavelength goes through a detector - measures intensity of light
- a calibration curve can be used to determine concentration
higher amount of the element = more absorbed
4
Q
Absorbance value
A
measure of how much light passed without being absorbed