Identifying elements Flashcards

qualitative and quantitative methods

1
Q

What is emission spectroscopy

A
  • all elements have specific energy levels
  • electrons exist in the lowest possible energy level
  • when energy is supplied, it’s absorbed by the electrons and they jump to a higher level (excited state)
  • but this is unstable so it quickly drops back to a lower energy level
  • when it does this, it releases energy in the form of light of a specific frequency
  • then a spectroscope is used to separate frequencies to form an emission spectral lines
  • can be used to identify elements
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2
Q

What is the flame test?

A
  • all elements have specific energy levels
  • electrons exist in the lowest possible energy level
  • when they’re heated, the energy is absorbed by the electrons and they jump to a higher level (excited state)
  • but this is unstable so it quickly drops back to a lower energy level
  • when it drops, it emits a specific coloured flame, with a specific wavelength of light
  • the colour can be used to identify the element
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3
Q

Atomic absorption spectroscopy:

A
  • it uses light absorption to measure the amount of an element present in a sample
    Steps:
    1. Element is analysed using a qualitative method
  • helps to focus on just one element
    2. Light of the correct wavelength is generated
  • using a hollow cathode lamp made of the element being detected so that it generates the correct wavelength
    3. Sample is vaporised
  • done by spraying liquid form into an energy source turning it into individual atoms
    4. The light passes through the sample
  • only the element being tested will absorb it
  • greater concentration = more light absorbed
    5. Light that passes through is focused through a slit and enters a monochromator
  • separates absorbed wavelengths from others
    6. The specific selected wavelength goes through a detector
  • measures intensity of light
  • a calibration curve can be used to determine concentration
    higher amount of the element = more absorbed
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4
Q

Absorbance value

A

measure of how much light passed without being absorbed

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