Identifying compounds Flashcards
What is the test for carbonates and hydrocarbonates?
Add acid to the carbonate (HCl)
Connect to test tube with limewater
If present the CO2 produced will turn limewater cloudy
What is the result of the flame-test of Sodium?
Yellow-orange flame
What is the result of the flame-test of Potassium?
Lilac flame
What is the result of the flame-test of Calcium?
Brick red flame
What is the result of the flame-test of Lithium?
Crimson red flame
What is the result of the flame-test of Rubidium?
Reddish-violet
What is the result of the flame-test of Caesium?
Blue-violet
What is the result of the flame-test of Strontium?
Red
What is the result of the flame-test of Barium?
Pale green
What is the result of the flame-test of Copper?
Blue-green
How do you perform a flame test?
Clean a nichrome wire in conc hydrochloric acid and put into Bunsen flame
Dip into small amount of solid and put into the Bunsen flame
How is the test for halide ions done?
Dissolve solid in pure water
Acidified using dilute nitric acid
Silver nitrate (aqueous) added
Why is dilute nitric acid when testing for halide ions?
Reacts with and removes other ions which may give a precipitate with silver nitrate
What coloured precipitate forms if F- ions are present in a compound?
No precipitate
What coloured precipitate forms if Cl- ions are present in a compound?
White precipitate
What coloured precipitate forms if Br- ions are present in a compound?
Cream precipitate
What coloured precipitate forms if I- ions are present in a compound?
Yellow precipitate
How does AgCl react with ammonia solution?
Dissolves in dilute ammonia solution
How does AgBr react with ammonia solution?
Precipitate doesn’t dissolve in dilute ammonia solution
Precipitate dissolves in conc ammonia solution giving colourless solution
How does AgI react with ammonia solution?
Precipitate is insoluble in all concentrations of ammonia
Which colour is fluorine?
Pale yellow
Which colour is chlorine gas?
Green
Which colour is bromine liquid?
Red-brown
Which colour is iodine solid?
Grey solid
What colour is chlorine in water and hexane?
Water: Virtually colourless
Hexane: Virtually colourless
What colour is bromine in water and hexane?
Water: Yellow/orange
Hexane: Orange/red
What colour is iodine in water and hexane?
Water: Brown
Hexane: Pink/violet
How do you test for sulphate ions?
Add dilute HCl
Add Barium chloride solution
Positive result gives a white precipitate
Why is hydrochloric acid added in the test for sulphate ions?
Removes any traces of carbonate ions before the test
What is the test for ammonium compounds?
Add some NaOH
Gently heat
Put damp litmus paper over test tube
Positive test turns red litmus paper blue
Where should the test for ammonia compounds be done?
Fume cupboard as produces an irritant gas
Why does the litmus paper have to be damp when testing for ammonia ions?
Ammonia gas can dissolve and make the colour change
What is the test for metal ions with NaOH?
Add sodium hydroxide to the metal ion solution
What is the result for copper (II) sulphate when NaOH added?
Light blue precipitate forms
What is the result for iron (II) when NaOH added?
Green precipitate
Darkens on standing as it forms iron (III) hydroxide
What is the result for iron (III) when NaOH added?
Orange precipitate
Darkens on standing
What is the result when cobalt (II) when NaOH is added?
Blue precipitate
Turns brown on standing
What is the colour of copper(II) solution?
Pale blue solution
What is the colour of iron(II) solution?
Pale green solution
Why does iron(II) precipitate darken on standing?
Oxidised by water and oxygen in air Forms iron(II) hydroxide
What is the colour of iron(III) solution?
Yellow solution
What is the colour of cobalt(II) solution?
Pale pink solution
What is the colour of cobalt nitrate?
Yellow-brown solution
What is the colour of Chromium nitrate?
Purple
What is the colour of Copper chloride?
Yellow solution
What is the colour of cobalt chloride?
Blue
How do you test for SO2?
Turns potassium dichromate paper orange to green
How do you test for H2S?
Turns lead ethanoate paper from white to black
How could you tell the difference between an aldehyde and ketone using 2,4-DNP?
React both with 2,4-DNP Take yellow precipitate and recrystallise Make crystal dry Determine melting point Compare to data booklet value