Ideal Gases Flashcards

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1
Q

One mole definition

A

the amount of substance that contains as mamy elementary entities as there are atoms in 0.012kg of carbon-12

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2
Q

what does 1 mol of any substance contain

A

6.02 * 10^23 individual atoms or molecules

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3
Q

total number of atoms in a substance equation

A

N (total no. of molecules) = n (number of moles) x avagadro’s constant

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4
Q

How do atoms in an ideal gas cause pressure?

A

The atoms or molecules in a gas are always moving and when they collide with the walls of the container , the container exerts a force on them (Newton’s 3rd Law), changing their momentum as they bounce off the wall.

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5
Q

What happens to the velocity of the atom when it bounces off the container?

A

It becomes negative since velocity is a vector

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6
Q

pressure and volume relationship

A

if the temperature and mass of gas remain constant then the pressure of an ideal gas is inversely proportional to its volume.

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7
Q

what is boyle’s law

A

pressure exerted by a gas at constant temperature varies inversely with the volume of the gas.

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8
Q

Pressure and temperature relationship

A

if the volume and mass of a gas remains constant, the pressure of an ideal gas is driectly proportional to its absolute (thermodynamic) temperature in kelvins

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9
Q

what is the combined gas law

A

P1V1/T1 = P2V2/T2

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10
Q

what is the combined gas law constant, nR

A

pV/t

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11
Q

what is the value for the molar gas constant

A

8.31 JK -1 mol -1

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12
Q

what is the equation of state of an ideal gas

A

pV/T = nR OR pV = nRT

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13
Q

how is the Boltzmann constant calculated

A

the molar gas constant/ avagadro’s constant

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14
Q

what is the boltzmann constant

A

1.38 x 10^-23

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15
Q

equation of state of an ideal gas with the boltzmann constant

A

pV = N(number of particles in gas sample)k(avagadro’s constant)T

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16
Q

what affects particles having different speeds

A

particles have different masses so their r.m.s. speeds will be different

17
Q

what is the internal energy of a gas

A

the sum of the kinetic and potential energies

18
Q

what is the nature of internal energy in an ideal gas

A

one of the assumptions of an ideal gas is that the electrostatic forces between particles is negligible except during collisions, so there is no electric potential energy in an ideal gas. all the internal energy is in the form of the KE of particles.

19
Q

Why does higher temperature lead to higher pressure

A

The hotter the gas, the faster the molecules move
Hence the molecules collide with the surface of the walls more frequently
Since force is the rate of change of momentum:
Each collision applies a force across the surface area of the walls
The faster the molecules hit the walls, the greater the force on them
Since pressure is the force per unit area
Higher temperature leads to higher pressure

20
Q

pressure in an ideal gas

A

The frequency of collisions of the gas molecules per unit area of a container

21
Q

what does isothermic mean

A

if a change in a gas is isothermic it means temperature is constant

22
Q

what does isobaric mean

A

when change has no change in pressure