Ideal And Real Gases Flashcards
state variables
variables that we can use to describe the conditions in which a material can exist.
Examples of state variables
pressure
volume
temperature
equation of state.
An equation of state describes a simple relationship between variables where changes effect each variable
m = nM
m = the total mass of a given quantity of a compound. n = the number of moles present. M = the molar mass of a compound (the molecular weight)
V ∝ n
The volume is proportional to the number of moles
Double the number of moles, whilst keeping the pressure and temperature constant, and you will double the volume.
V ∝ 1/p
The volume varies inversely with the pressure
(Double the pressure whilst keeping the temperature and number of moles constant, and you will cause the gas to compress to half its original volume.)
p ∝ T
The pressure is proportional to the absolute temperature
(Double the temperature (measured in kelvins) whilst keeping the volume and number of moles constant, then the pressure doubles.)
The ideal gas equation
pV =nRT
pV =nRT
p = pressure ( V = volume ( n = number of moles R = molar (ideal) gas constant. R ≃ 8.314 J mol−1 K−1 T = temperature