HYDROGEN Flashcards
hydrogen has properties similar to …….&…….
akali metals halogens
Electronic congiguration of hydrogen
1s2
resemblance of hydrogen with group 1 elements
forms +ve univalent ion
has one electron in outermost shell
forms stable oxides , sulphides and halides
difference between hydrogen and group 1 metals
Ionization enthalpy of hydrogen is higher than that of the other group one elements
hydrogen ion is way smaller than the ions of other group 1 metals and it is always associated with other atoms or molecules
similarity of hydrogen with halogens
gains an electron to attain nobel gas configuration
forms hydrides with carbon just like how halogen forms halides with carbon
similar ionization enthalpy
molecular forms are diatomic
differnce between hydrogen and halogens
hydrogen is less reactive
electron affinity of hydrogen is lesser
name the isotopes of hydrogen
protium (1H1)
deuterium (1H2)
tritium (1H3)
heavy hydrogen is
deuterium
which isotope of hydrogen is radioactive and what particles does it emmit
tritium
beta particles
abundance of of the isotopes of hydrogen (order)
P > D > T
Mass of hydrogen isotopes (order)
T>D>P
MP of isotopes of hydrogen (order)
T>D>P
BP of isotopes of hydrogen(order)
T>D>P
enthalpy of bond dissociation of isotopes of hydrogen(order)
T>D>P
Why is impure zinc not used to form dihydrogen
it reacts very slow
therefor impurities are added
why isnt zinc reacted with concentrated H2SO4 for dihydrogen formation
forms SO2 instead of dihydrogen
therefor dilute h2so4 is used
what electrodes are used in electrolysis of acidic water to form dihydrogen
platinum electrodes
what electrodes are used in electrolysis of barium hydroxide to form dihydrogen
nickle
what is brine
aqueous NaCl
during electrolysis of Brine what gas is released at the cathode
H2
during elctrolysis of Brine what gas is released at the anode
Cl2
what are the products when Zn reacts with NaOH
Sodium zincate (Na2ZnO2) and dihydrogen
formation of dihydrogen from carbon and water is catalysed by ……….. at ……….. kelvin
nickle
1270 K
what is water gas
mixture of CO and H2
Wter gas AKA
synthesis gas
Syn gas
production of syn gas from coal is called
coal gasification
it is difficult to obtain dihydrogen from water gas
therefor what is done
CO of water gas is reacted with steam
reaction of CO and steam is catalyzed by what at what temperature
Iron chromate (FeCrO4)
673 K
physical properties of hydrogen
oudourless
colourless
combustible
tasteless
comment on the solubility of dihydrogen in water
insoluble
reaction of hydrogen and chlorine is aided by
sunlight
reaction of hydrogen and bromine is aided by
heat (673 K )
reaction of hydrogen and iodine is aided by
catalyst platinum and heat (673 K )
Hydrogen reacts with
oxygen
nitrogen
metals
TO FORM
water
ammonia
metal hydride
addition of hydrogen to unsaturated hydrocarbons is catalyzed by what at what temperature
Ni
473 K
vegetable oil on addition of Hydrogen gets converted into
solid fat
hydrogenation of vegetable oil catalyzed by what at what temperature
Ni
473 K
olefins + dihydrogen + corbone monoxide =
aldehyde
addition of dihydrogen to aldehyde forms
alcohol
aldehyde to alcohol by dihydrogen is catalyzed by
platinum
production of NH3 from N2 and H2 is catalyzed by what at what conditions
Fe
200 Atm
673 K
production of methyl alcohol from CO and H2 is catalyzed by
cobalt
name the type of hydrides
ionic hydride
covalent hydride
metallic hydride
ionic hydriges are formed with every s-block element except
Be , Li , Mg