Hydrogen Flashcards

1
Q

How can you obtain hydrogen using a reactive metal?

A

Some H2SO4 is poured by means of the dropping funnel onto the zinc dust and effervescence, indicating liberation of hydrogen. Write the equation.

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2
Q

Other acids and metals can be used to obtain hydrogen. Mention two.

A

Reaction of Magnesium with HCL and reaction of iron with HCL. Write the equation.

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3
Q

What do I need to add to require dry hydrogen when i use magnesium and iron with HCL?

A

Pass it through anhydrous calcium chloride in a U-Tube or concentrated sulphuric acid in a wash bottle (upward delivery)

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4
Q

How can i obtain hydrogen with a reaction of metal with water?

A

The metals are potassium, sodium, calcium. (write the equations)

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5
Q

How can i obtain hydrogen by the reaction of metals with steam? Write the equations.

A

The metals are Mg, Zn and Fe.

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6
Q

How can i obtain hydrogen by the reaction of amphoteric metals with caustic alkalis?

A

Amphoteric metals such as Al and Zn react with sodium hydroxide or potassium hydroxide to obtain hydrogen.

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7
Q

What are amphoteric metals?

A

They are metals that react both with acids and base.

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8
Q

What are caustic alkalis?

A

They are strong corrosive alkali like hydroxide

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9
Q

How can you acquire hydrogen by electrolysis?

A

By dilute acids and dilute alkalis such as sulphuric acid, which gives hydrogen at the cathode and oxygen at the anode.

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10
Q

How can i obtain hydrogen from methane? (industrial)

A

If methane is heated, in the absence of air, to a high temperature (1000°C) in the presence of a catalyst, e.g. aluminium oxide, the gas breaks down into carbon and hydrogen. The process is known as cracking.
CH4 (g) → C (s) + 2H2 (g)

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11
Q

What is methane?

A

Methane is a colourless, odourless flammable gas and is a member of hydrocarbons.

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12
Q

How can i obtain hydrogen mixed with steam? (industrial)

A

A mixture of natural gas (methane) and steam is passed over a
nickel catalyst. The process occurs in a number of stages but the overall reaction is mainly:
CH4 (g) + H2O (g) → CO (g) + 3H2(g)
The carbon monoxide is converted to carbon dioxide
The carbon dioxide is removed by dissolving it in water under pressure to leave hydrogen.

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13
Q

Describe the bosch process.

A
  1. Pass steam over red hot coke. C(s) + H2O (g) → CO (g) + H2 (g)
  2. The bosch process involves passing H2O (g) over iron(3) oxide catalyst. CO is converted to CO2.
  3. CO2 is removed by dissolving it under pressure.
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14
Q

Hydrogen is also obtained as a by product in the electrolysis of ….. (industrial)

A

brine (sodium chloride solution)

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15
Q

Name 6 physical properties of hydrogen.

A
odourless gas
colourless
less dense than air
neutral
diffuses very rapidly.
slightly soluble in water.
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16
Q

Test for hydrogen in a lab

A

a burning splint is put near hydrogen and it burns with a pop sound.

17
Q

Combustion of hydrogen in air to form water

A

Pure hydrogen burns steadily and quietly in air with a pale blue flame.
the product of combustion of hydrogen is water.
H2 (g) + O2 (g) → H2O (l)
The reaction is very exothermic (heat is liberated) so hydrogen is a very good fuel.

18
Q

Advantages of hydrogen as a fuel

A

Harmless to environment
very light
can be obtained via unpolluting sources ex: electrolysis of water
does not occupy a lot of space

19
Q

disadvantages of hydrogen as a fuel

A

difficult to produce
difficult to store
difficult to transport

20
Q

Chemical reaction involving hydrogen

A
  1. Reaction of hydrogen with metals (groups 1 and 2)
  2. Reaction of hydrogen with non- metals ( with halogens and with nitrogen). Note :
    When it reacts with nitrogen it forms ammonia.
  3. Hydrogen as a reducing agent. (it removes oxygen from oxides of metals ex: CuO
    e.g. CuO (s) + H2(g) → Cu (s) + 2H2O (g)
    Copper oxide is reduced to copper, by loss of oxygen. Hydrogen itself is oxidised to water
    by gain of oxygen.
21
Q

Uses of hydrogen

A

Fuel
manufacture of margarine, ammonia, HCL
cutting of steel