HM Flashcards
EPA
Environmental Protection Agency (Title 40)
DOT
Department of Transportation (Title 49)
Code of Federal Regulations
CFR ***Title, Chapter, Part, Sub-part, Section, Paragraph, Sub-Paragraph
HMTUSA
Hazardous Materials Transportation Uniform Safety Act
POPS
Performance Oriented Packaging Standards (HM181)
RQ
Reportable Quantity
OSHA
Occupational Safety and Health Administration (Title 29)
PSN
PROPER SHIPPING NAME
DOT HAZARD GROUPS
I = Great Danger
II = Moderate Danger
III = Minor Danger
Packaging Groups
PG I
PG II
PG III
Hazmat Regulations
49 CFR 172 . 101
(Title) [DOT] (Part) . (section)
ORM
Other Regulated Materials
HAZPOWER
Hazardous Waste Operations and Emergency Response
(29 CFR 1910.120)
SARA
Superfund Amendments and Reauthorization Act
Law on October 17th, 1986
Known as EPCRA (Emergency Planning and Community Right to Know Act)
Requires governors to designate a State Emergency Response Commission (SERC)
{Section 301 to 303 of Emergency Planning}
Local Emergency Planning Committees (LEPC)
Section 304 Emergency Release Notifications
Facilities must notify LEPC of any possible environmental release of specific chemicals
Section 311 – 312 Reporting requirements
Facilities must provide MSDS if
500 lbs. Extremely Hazardous
10,000 lbs. All Other
Hazmat Regulations
29 CFR 1920.120
40 CFR 311
49 CFR 172.101
Table 1Materials – Placard ANY amount (1.1 / 1.2 / 1.3 / 2.3 / 4.3 / 5.2 / 6) Rad III
Flammable vs. Combustible – Flash Point (FP) of 141°F
Vapor Pressure
: How fast a liquid vaporizes or evaporates
Physical States
solid-liquid-gas
**Liquid
> 0mmHg / < 760mmHg
**Gas
> 760mmHg
VP H2O @ 68°F
18mmHg
Boiling Point
Temperature at which a liquid starts to boil.
Flash Point
Minimum temperature at which a liquid gives off enough vapors to form an
ignitable mixture.
Vapor Density
All liquid vapors are heavier than air
VAPOR DENSITY ( * VD) of Air
= 1
Specific Gravity : *SG of Air
= 1 (0.9 will float / 1.1 will sink)
Molecular Weight * MW of Air
= 28.96
~Methane
=16 (raises in air)
~Propane
= 44 (drops in air)
1% OF LEL OR UEL IS EQUAL TO?
= 10,000 PPM
LEL / UEL: Range of flammability
Concentration (percentage) of a gas or a vapor in air
capable of producing a flash of fire in presence of an ignition source
LEL:
Minimum mixture in air to ignite
UEL:
: Too rich, mixture will not ignite
i.e. Methane: LEL 5% / UEL 15%
Photo Ionization (PID)
10.6 bulb
Flame Ionization (FID)
Must have hydrogen
PPM
= Lower the #, more toxic.
Mg/m³
MILLIGRAMS OF MERCURY CUBED
~ Polar
= mixes
(~ Non Polar
= does not mix
Corrosive
= Burns, irritates or destructively attacks organic tissues
~ 0 to 6 = acid ~ 7 = neutral ~ 8 to 14 = base
Polymerization
= Process of combining single chemical units to form larger chemical
units. (Monomers > Polymers)
Miscible:
When a liquid is infinitely soluble in water
Sublimation
When a solid turns to gas (the change from a solid to gas without entering
liquid phase) skips liquid phase
1
= Air’s Vapor density
1
= Air’s Specific Gravity
29
molecular weight of air
10 is key for?
10% the LEL
10 PPM -CO
10 PPM-H2S
10-mr/hr
2=
2X Background (Rad)
PROPANE
44 DROPS IN AIR
VAPOR PRESSURE OF WATER
18
ACCEPTABLE OHMS LEVEL FOR A GROUNDING AND BONDING OPERATION
25 OHMS IS THE ACCEPTABLE LEVEL FOR GROUNDING AND BONDING
GASOLINE KEY FACTS
(BP-100F); (VP 38F); (FP -44*F)
760mm/Hg= 1ATM
=14.7PSI= 1 BAR
IDLH(RESPIRATORY STANDARDS)
PPM: THE LOWER NUMBER THE MORE TOXIC A PRODUCT IS
1300 RULE >
1300 X VP=PPM CONCENTRATION IN THE HEAD SPACE OF A CONTAINER
REGULATIONS
FEDERAL REGULATIONS/LAWS USED TO OVERSEE THE STORAGE AND TRANSPORT OF HAZARDOUS MATERIALS IN THE US
CFR
CODE OF FEDERAL REGULATIONS
DOT: DEPARTMENT OF TRANSPORTATION
CFR 49 (ONLY APPLIES TO COMMERCIAL TRANSPORT)
OSHA: OCCUPATIONAL SAFETY & HEALTH ADMINISTRATION
CFR 29
EPA: ENVIRONMENTAL PROTECTION AGENCY
CFR 40
HAZARD CLASSES
9 HAZARD CLASSES EXIST
HAZARD CLASS #1
EXPLOSIVES (1.0-1.6)
- Division 1.1 Mass explosion hazard (Black powder, TNT)
- Division 1.2 Projection hazard (Aerial Flares, Detonating cord)
- Division 1.3 Fire and minor blast hazard. Minor projection hazard (Liquid-fueled
Rocket motors) - Division 1.4 Explosive devices w/minor explosion hazard. No more than
25g/0.9oz of detonating material. (Line throwing rockets, practice ammo - Division 1.5 Very insensitive explosives. (Pilled Ammonium Nitrate, Fertilizerfuel Mixtures)
- Division 1.6 Extremely insensitive articles without explosive hazard.
HAZARD CLASS #2
GASES (2.1-2.3) - Division 2.1 Flammable gases: Gases at 68°F or less and 14.7 psi ignitable when
in a mixture of 13% or less by volume with air.
- Division 2.2 Non-Flammable: Non-poisonous compressed gas or mixture with an
absolute pressure of 41psi. at 68°F and does not meet the definition of 2.1 or 2.3.
- Division 2.3 Poisonous by inhalation. A (most poisonous) to D (Least poisonous)
HAZARD CLASS #3
FLAMMABLE AND COMBUSTIBLE LIQUIDS
- Flammable: Flashpoint of less than 141°F/60.5°C
- Combustible: Flashpoint greater than 141°F and less than 200°F
HAZARD CLASS #4
FLAMMABLE SOLIDS (4.1-4.3)
- Division 4.1 Flammable solids (Metal powders, self-reactive materials)
- Division 4.2 Spontaneously Combustible and Self Heating Materials within 5
minutes of contact with air. - Division 4.3 Dangerous when wet
HAZARD CLASS #5
OXIDIZERS 5.1-5.2
- Division 5.1 Oxidizers (yields oxygen, causes or enhances combustion of organic
materials. - Division 5.2 Organic Peroxides [Tendency to deflagrate (to burn, specially
suddenly and violently)]
HAZARD CLASS #6
POISONS 6.1-6.2
- Division 6.1 Materials other than gases known to be toxic during transport or have
a toxic effect on animals. - Division 6.2 Contains a viable microorganism or microbial toxin with potential to
cause disease.
HAZARD CLASS #7
RADIOACTIVE MATERIALS I-III
- Radioactive III: More than 50 milliroentgents/hr
- Radioactive II: More than 0.5mr/hr and less than 50mr/hr
- Radioactive I: Equal or less than 0.5mr.hr
HAZARD CLASS #8
CORROSIVE MATERIALS I-III
Solid or liquid that causes irreversible harm to human skin
(necrosis) over a 4 hour period.
Assigned to packing groups based on necrosis time:
I. Less than 3 minutes of necrosis time
II. 3 to 60 minutes of necrosis time
III. 60 to 240 minutes of necrosis time or ¼” corroding steel or aluminum surfaces
per year.
HAZARD CLASS 9
MISCELLANEOUS HAZARDOUS MATERIALS
Material which presents a hazard during transport but it is not included in any other
hazard class.
Other Regulated Materials
No longer exists
ORM-D is the exception. Consumer commodities packaged and distributed in a form
intended for retail sale or consumption by individuals for the purpose of personal care or
household use.
Shipping Papers
Specific to the mode of transportation.
Highway: Bill of Lading / Hazardous Waste Manifest (Driver)
Rail: Waybill (Crew)
Water: Dangerous Cargo
Manifest (Captain)
Air: Air Bill (Pilot)
Basic Shipping Description
*Proper Shipping Name >Hazmat Table Column 2
*Hazard Class >Hazmat Table Column 3
- ID Number >Hazmat Table Column 4
*Packing Group – Hazmat Table Column 5
Technical Shipping Name
*Used when transporting a single Hazardous Material
*Words “Mixture” or “Solution” are added if the material has been mixed with a Non-Hazardous or Non-regulated ingredient.
Generic Shipping Name
*Used when transporting a mixture of 2 or more Hazardous Materials
*Identifies the generic Shipping Name by the letters N.O.S.
Labeling and Markings
*Label: Describes the Hazardous Material within a container
*Multiple Hazards = Multiple labels
*Should be located near the proper shipping name and same surface
*Should not be placed on the bottom of the container
29 CFR – OSHA
*Sets regulations for the handling and storage of Hazardous Materials
*HAZPOWER 29 CFR 1910.120 deals with hazardous waste operations and emergency
respond
40 CFR – EPA
Regulates the federal system of Hazardous Waste management.
Shipping Papers
*UN ID #
*Emergency Contact / Phone number
*RQ when applicable
- Shipping name
*Hazard Class
- Can be found in: Cab of vehicle
Train crew member
Holder on the bridge of vessel
Aircraft’s pilot possession
Placards
*Diamond shaped sign used on transport vehicles
*Include: Name / ID Number / Hazard Class
ID Number
4 digit number found on: Placards
Shipping Papers
Packing
Bulk Storage Containers
(DOT CFR 49)
BULK STORAGE
Bulk containers with an internal volume greater than
Liquid: 118.9 gallons (450 Litters)
Solid: 881.8 lbs. (400 kg)
Gas: 1000 lbs. (456.6 kg, water capacity)
Cargo Tanks
Non-pressure tanks (MC306 / DOT406)
*Designed to carry petroleum products or alcohol.
*1,500 to 12,000 gallons of product.
*Internal pressure of 2.65 psi (min) to 4 psi (max)
*Top loaded only
Low Pressure (MC307 / DOT407)
Circular cross section
*5,000 to 8,000 gallons of product.
*Working pressure of 25 to 35 psi/g
*Flammable and combustible liquids, mild corrosives, poisons.
Corrosives (MC312 / DOT412)
- Single compartment
- Working pressure of 15 to 50 psi/g
- 3,000 to 5,000 gallons of product
- Liner bonded to the tank
- Stiffening rings
Pressure Cargo Tanks (MC331)
Working pressure of 100 to 500 psi/g
- 8,000 to 15,000 gallons of product
- Rounded ends
- Values labeled as “vapor” or ”liquid”
Cryogenic Cargo Tanks (MC338)
Keeps product very cold (-130°F)
- 8,000 to 10,000 gallons of product
- Highly insulated
- Working pressure of 25.3 to 500 psi
Tube Trailers
2 to 20 tubes
- 9 to 48 inches in diameter
- Up to 5,000 psi/g working pressure
- Carry only gas under pressure (not liquid)
Rail Road Tank Cars
*Waybill: information specific to a particular rail car
- Consist / Wheel Report: Lists all of the cars and their location and also identifies the
Hazmat cars.
Non-Pressure Cars (DOT 111)
Up to 100 psi/g
- Relieve valve set at 75 psi/g
- No expansion dome
Pressure Cars (DOT 105 / DOT 112)
Up to 600 psi/g
- Carries 4,000 to 45,000 gallons of product
- Process chemicals, Anhydrous Ammonia, LPG
- Round Ends
Cryogenic (DOT 113)
Pressure of 25 psi/g or lower
- -115°F
- Liquid Oxygen, Nitrogen, Carbon Dioxide, Argon, Hydrogen
- No topside fittings
Ton Containers
180 to 320 gallons of product
- Up to 1,000 psi/g
- Use to carry Chlorine, Phosgene
Intermodal Tank Containers
IM-101 / IM-102
- Up to 100 PSI
- All mode of transport
Asphyxiant
Simple→Displaces Oxygen
Chemical→Prevents the body from using Oxygen.
Corrosive
Effects depends on concentration
Acid or Base
Irreversible tissue damage
Irritant
Temporary but occasionally severe inflammation of eyes, skin or respiratory
tract.
Sensitizers
Cause allergic reactions
Carcinogens
agent directly involved in causing cancer
Neurotoxins
substance that inhibits the function of neurons, cells in the nervous system
Mutagens
agent which induces genetic mutation
Teratogens
lead to structural and/or functional birth defects
What makes a substance toxic?
Have a physical and chemical properties capable of causing harm
- Be present in sufficient amounts to do harm
- Be present for a sufficient amount of time
- Have a route of entry to the body
- Be able to reach a susceptible body organ or tissue
Exposure:
When a toxic substance or infectious agent is taken into the body or in direct contact
with the body
TYPES OF EXPOSURE
- Acute: Short period, high concentration
- Chronic: Long term, long concentration
Contaminants:
Material clings to or saturates clothing or parts of your body
Measures of toxicity:
- LD50: Lethal Dose 50. Amount of the substance required to kill 50% of the test
population - LD100: Lethal Dose 100. Amount of the substance required to kill 100% of the test
population - LC100: Lethal Concentration 100. Lethal concentration of a substance required to kill
100% of the test population
Threshold Limit Value (TLV)
Average airborne concentration of substances to which is believed nearly all adults may
be repeatedly exposed in the work environment for an 8hr. workday without adverse
effects
Short Term Exposure Limit (STEL)
Standard or legal limit. Maximum duration of exposed at this level is 15 minutes with no
more than 4 exposures in an 8hr day
Immediately Dangerous to Life or Health (IDLH)
Exposure to airborne contaminants that is “likely to cause death or immediate or delayed (within 30 minutes)
permanent adverse health effects or prevent escape from such an environment.
Routes of Entry: 5 ROUTES
Skin Absorption - Toxic substances can be absorbed through the skin or may enter the
bloodstream through broken skin.
- Inhalation – Most common. Rate and depth of respiration affect the amount of material
absorbed. - Ingestion – Toxic materials can be swallowed if contaminated hands or clothes come in
contact with the mouth. - Injection or puncturing – Result from contact with physical agents (syringes, high
pressure devices or sharp objects) - Eyes – 90% of chemicals can be absorbed through the eyes
Three key reasons for pre-incident planning:
- Pre-incident planning provides a mechanism for making decisions calmly and rationally,
in advance of an emergency. The emergency incident scene is a poor environment in
which to make decisions. - Pre-incident planning provides an opportunity to gather information prior to an
emergency. Timely, accurate information may be difficult to obtain during a hazardous
materials emergency.
*Pre-incident planning provides response agencies and personnel with the information
needed to act in an effective, well-coordinated manner. Coordination of responders is
often a problem at hazardous materials emergencies.
Priorities and Objectives
- Compiling Information:
Additional information will help you conduct site surveys. Obtain information from
public records regarding material usage and waste, traffic patterns, past experience and
observation, and other sources of information about each facility. - Preparing for On-Site Surveys
Once you have established priorities and tapped and analyzed available sources of
information, conduct the on-site surveys. An on-site survey helps you assess relevant
information, including the location of utility and product shutoffs, built-in protection
systems, and areas where spilled products may pool.
Before you conduct an inspection at the site, review all available information on the facility,
including:
- Previous inspection reports * Drawings * Permit applications * History of fires or chemical
incidents * MSDSs or lists of chemicals * Maps * Adjacent vulnerable locations
To develop comprehensive hazardous materials pre-plan for a facility, consider the following
characteristics:
- Location/exposures * Type of construction * Type of business/process * Water supply *
Building access * Communications and security * Electrical/gas shutoffs * Water shutoffs and
sprinklers * Location/type/quantity of chemicals and their hazards * Emergency medical support
available * Work schedules/number of employees * Emergency resources on site/contingency
plans * Protective clothing available on site * Vulnerability of surrounding area/ability to
evacuate * Adjacent facilities and other exposures that cannot be evacuated or shut down *
Compatibility of resources * Waterways and storm sewers, particularly those that empty into
waterway
Chemical Hazards
Once materials have been identified, assess the hazards posed by each material and those that
could result from a combination of these materials. Flammability, reactivity, and other hazards
can be assessed using a variety of sources.
Potential Health and Environmental Effects
Among the most critical areas of pre-incident planning are the specific health and environmental
effects of materials that could be involved in a hazardous materials emergency. The safety of
emergency personnel as well as civilians is directly related to health effects of materials.
Features of the Site or Area
When you assemble information about a site or transportation corridor, include activities that
take place prior to, during, and after visiting the site or area
Access for Emergency Responders
INFORMATION Regarding access to and exit from a site or area is essential to a comprehensive pre–INCIDENT PLAN
Geography and Topography
The location of incidents may also present major problems for fire fighters. The presence of large
bodies of water, steep hills, high buildings, confined spaces, very porous or very compact soil,
hot asphalt, or uneven terrain all increase the likelihood of injuries and add to the complexities of
dealing with an incident
Physical Conditions
Noise is a major but often overlooked hazard. It often interferes with communications between
the entry team and command. Noise may be generated by sirens, radios, explosions, air horns,
machinery, or venting from containers under pressure
Exposures
Hazardous materials emergencies often expand beyond the initial hazard area. Runoff, vapor
clouds, and fire exposures are a few of the potential avenues for spreading a hazard. An
additional function of pre-incident planning is to provide information on exposures
Protective Systems and In-House Resources
Pre-incident planning helps you identify the protective features of a site and to recognize the
abilities and limitations of any in-house response forces. Understanding their capabilities and
limitations in advance helps you assign roles and avoid misunderstandings during an emergency
Emergency Response Capability
A key task in pre-incident planning is the objective assessment of the capabilities and limitations
of response personnel in dealing with potential emergencies at a fixed site or in a particular
transportation corridor.
Melting Point
– Temperature at which a solid becomes a liquid
Freezing Point
Temperature at which a liquid becomes a solid.
Boiling Point
Temperature at which a liquid becomes a vapor.
Vapor Pressure
Measurement of the ability of a material to evaporate
760 mm/hg = 1 ATM = 14.7 psi = 1 BAR
Vapor Density
Measurement of the tendency of a gas to either sink or rise
Air = 1 > 1 = sink
< 1 = rise
Molecular Weight
Air = 29 > 29 = sink
< 29 = rise
Concentration
How much of one material is in relation to another. Factor that
determines the toxicity of a substance.
LEL / UEL
Concentration of a vapor or gas in the air.
Specific Gravity
Weight of a material compared to water (1)
> 1 = sink
< 1 = rise
Solubility
Degree that one substance will mix completely with another substance
Water Miscible
Liquid is infinitely soluble in water
Polarity
Polar = Positive and Negative charges are present – Non Polar = Positive and
Negative charges are evenly distributed within the structure thereby balancing each other
out
Oxidizers and Peroxides
Oxidizers
- Can make a fire burn hotter, faster and cause explosions
- Unstable and reactive
- Usually does not need air to burn
Inorganic Peroxides
- Act as both Oxidizer and Corrosive
Organic Peroxide:
- Contains both an Oxidizer and a compound that can act as fuel.
- Should be treated as Class 1 Explosive.
Chlorate and Percolates:
- Unstable molecules containing excess Oxygen
- Decompose rapidly when subjected to heat
Polymerization:
- Process of combining single chemical units (Monomers) to form a larger chemical
unit (Polymer)
Corrosivity:
- Material that burns, irritates or destructively attacks organic tissue (skin)
- Based on the PH Scale (0 to 14)
- Acid 0 to 7
- Base 7 to 14
Reactivity:
- Ability of a material to undergo a chemical reaction
Flash Point:
- Minimum temperature at which a spark or flame can cause an instantaneous flash in
the vapor space above the liquid.
Ignition Temperature:
- Temperature at which a material’s vapor start to burn without a flame or other
ignition source (Solids=400°F)
MSST:
- Maximum Safe Storage Temperature: Above this temperature a chemical may
become unstable, spontaneously igniting and rupturing the container
SADT:
- Self-Accelerating Decomposition Temperature: Above this temperature a chemical
will become unstable and could rupture it’s container and ignite violently.
Viscosity:
- Ability of a liquid to pour: - Low Viscosity (water) pours easily
- High Viscosity (oil) pours slowly