Heavy Metals And Solid Waste, Noise pollution and ionising radiation Flashcards

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1
Q

What happens with enzyme inhibition in heavy metals?

A

Heavy metals inhibit enzymes particularly those in the nervous system (neurotoxins), high doses cause damage to liver and kidney

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2
Q

How do heavy metals bioaccumulate?

A

They are liposoluble so may be stored in fat droplets in living cells so that chronic exposure to small doses may eventually produce toxic concentrations, passage along a food chain may also lead to biomagnification

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3
Q

What is the solubility and pH of heavy metals?

A

They are more soluble at a lower pH. Therefore pollution caused by heavy metal wastes can be reduced by increasing the pH to reduce solubility

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4
Q

What are the different chemical forms of mercury?

A

Liquid- Not easily absorbed in the gut but is easily absorbed in the lungs as vapour
Inorganic compounds- Absorbed through the gut and skin. It is not liposoluble so cannot pass across cell membranes
Organic compounds- Easily absorbed in the gut or as vapours in lungs, they are liposoluble so pass easily into the brain, across the placenta or into breast milk

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5
Q

How does lead get into our water?

A

Lead used to make water pipes or soldering to join pipes, water can corrode the pipes over time- small amounts of lead dissolve in the water which is then drunk- chronic exposure

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6
Q

What is the solution to lead pollution in water?

A

Lead pipes replaced by copper, zinc or tin
In areas that still have lead pipes- phosphoric acid can be added which prevents lead dissolving

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7
Q

How does lead pollution occur in industry?

A

Lead dust from mining
Dust can be inhaled or even absorbed through skin if dissolved in sweat

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8
Q

What is the solution to lead pollution in industry?

A

Water sprays to allow dust to settle and dust masks to reduce inhalation

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9
Q

How does lead pollution occur from petrol?

A

Tera ethyl lead (TEL) formerly added to petrol as valve lubricant and anti-knock agent (prevents pre ignition)
Lead present in exhaust fumes and dust can be inhaled

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10
Q

What is the solution to petrol lead pollution?

A

Most countries have phased out leaded petrol by replacing TEL with other agents or using alternative fuels e.g. diesel, hydrogen

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11
Q

How does lead pollution from paint occur?

A

Lead used to be used in many paints and is still used in some specialised paints
Old flaking/ peeling paint can be dangerous to children (swallowing the paint)
Paint removal with blow lamps may also produce lead vapours

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12
Q

What is the solution to lead pollution in paint?

A

Hot air paint removal guns use lower temps so are less likely to produce lead vapours

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13
Q

How does lead pollution occur from fishing and hunting?

A

Lead has been used for fishing weights and shotgun pellets in the past
Weights may be discarded or lost and swallowed by swans/ ducks while shotgun pellets that miss their target may also be swallowed by water birds

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14
Q

What is the solution to lead pollution in fishing and hunting?

A

Alternative materials such as tungsten steel can be used for shotgun pellets and smaller fishing weights

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15
Q

How does Cadmium pollution occur?

A

Found in old batteries as well as used in certain photovoltaic solar panels
Impacts include lung cancer, paralysis and brain damage

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16
Q

What is a property of Cadmium Tin and Iron?

A

Can bioaccumulate

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17
Q

How can Cadmium pollution be managed?

A

Waste needs to be disposed in hazardous waste landfill or may be recycled e.g. batteries

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18
Q

What can be the effect of iron pollution?

A

Not directly toxic but can lead to deoxygenation in water when leached from spoil heaps

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19
Q

How can iron pollution be contolled?

A

By passing spoil heap drainage water over mesh screens to oxidise and deposit the metal on the mesh

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20
Q

How can tin pollution occur?

A

Used as an antifouling paint on boats to stop the growth of marine organisms
Can damage marine organisms and enter humans when seafood is eaten

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21
Q

How can tin pollution be reduced?

A

Paint now replaced with less toxic metals and paint residues now removed to landfill rather than washed out at sea

22
Q

How does affluence impact waste production?

A

Buy more goods- less essential
Less incentive to reuse ‘throwaway society’
Many products designed with short shelf life e.g. disposable
Over packaging

23
Q

What are the issues dealing with domestic waste?

A

Large volume produced weekly
Produced by every household rather than a few larger sources
Composition varies seasonally
Mixture of many different types of waste

24
Q

What are the factors impacting waste treatment?

A

Population density
Per Capita production
type of industry
land availability
available technology for recycling
environmental awareness
legislation

25
Q

What are the features of good landfill site management?

A

Separation of different waste types and recording of their composition and locations
Polymer liner to prevent the escape of leachate fluids
Perimeter fence to trap litter blown by winds
Regular covering with soil to reduce pest problems
collection and treatment of leachate fluids
collection of methane and its use as a fuel

26
Q

What are the disadvantages of of landfill?

A

The potential resource value is lost, metals, glass plastics
They use large areas of land
Organic matter decays anaerobically releasing methane
Toxic leachate may leak from poorly managed landfill sites
wildlife habitats and farmland may be lost

27
Q

What are the advantages of incineration?

A

The volume of ash produced is much less than the original waste
The heat produced may be used for district heating or electricity generation
No sorting or compliment management is needed

28
Q

What are the disadvantages of incineration?

A

The resource value of recyclable materials is lost
toxic dioxins may be produced by reaction of organic wastes and chlorine
The fuel used to maintain combustion of wet or non flammable wastes is expensive
The wastes may need to be separated to remove wet wastes increasing processing costs

29
Q

How can the topography of spoil heaps be resolved?

A

Landscaping can be used to reshape the heap although this may require more land

30
Q

How can the instability/ risk of landslides of spoil heaps be resolved?

A

Stability can be improved through compaction or by constructing buildings on concrete rafts to reduce uneven settling, reducing the risk of subsidence

31
Q

How can the low pH of spoil heaps be resolved?

A

The addition of lime reduces the acidity of spoil

32
Q

How can the lack of nutrients in a spoil heap be resolved?

A

The addition of topsoil, sewage sludge and fertilisers are common techniques to improve the nutrient content and incease plant growth

33
Q

How can the toxic materials of spoil heaps be resolved?

A

These should be collected and treated to prevent them from entering water courses
Deeper layers of soil should be applied during reforestation so that plant roots cannot reach the layer containing toxic materials

34
Q

How can the contamination with petrochemicals in spoil heaps be resolved?

A

Petrochemical waste can be treated by bioremediation
Certain species of bacteria will digest the oil if appropriate conditions of temperature, water supply and aeration are maintained

35
Q

What are the levels of the waste hierarchy?

A

Prevention- Avoid waste production in the first place
Preparing for reuse - Referbish and repair when possible
Recycling- turning waste into new materials
Other recovery - Anaerobic digestion and incineration with energy recovery
Disposal- Disposal and incineration without energy recovery

36
Q

What are the issues with recycling aluminium?

A

Not all material can be recycled unavoidable losses
Energy used to transport and recycle must be less than energy used to extract out the ground initially
Will be less energy efficient if small quantities are used
Alloys are not easily separated and so recycled alloys cannot be used
Identifying from other resources is slow and labour intensive
Public recycling schemes require cooperation

37
Q

What are the different methods of recycling aluminium?

A

Use of offcuts
Reduced material use in manufacture
Replacing scarce materials with more abundant or more easily recycled versions

38
Q

What is the scale that measures the unit of sound?

A

DeciBel scale

39
Q

What is the scale modified to weight the frequencies most sensitive to the human ear?

A

dB(A) scale

40
Q

What is the measure of traffic noise pollution during the noisiest points?

A

L10 18h

41
Q

What is the measure of traffic noise pollution for noisier and quieter times?

A

TNI

42
Q

What is the measure to monitor aircraft noise pollution?

A

NNI

43
Q

Why is using a logarithmic scale dB appropriate?

A

Human ear sensitive to a very wide range of sound levels
0dB is set as the quitest sound that can be heard at 1000hz and is the threshold for human hearing
Age along with prolonged exposure to loud noises can reduce the sensitivity and range of hearing

44
Q

What are the effects of noise pollution on organisms?

A

Deafness
Stress
Irritability
Heart diseae
Headaches
Disturbance to breeding birds
Livestock can panic and injure themselves due to sudden noises
reduced feeding success in e.g. owls, dolphins
Behavioural changes in cetaceans e.g. strandings

45
Q

What are the effects of noise pollution of non living objects (acoustic fatigue)?

A

Sounds that cause objects to vibrate at their resonant ( natural frequency at which they vibrate) can lead to acoustic fatigue by causing stress cracks to appear
Repetitive vibration can also cause damage to buildings, bridges and underground pipes caused by wheel vibrations of trucks
Sonic booms from aircraft can also damage e.g. smashed windows

46
Q

What is ionising radiation?

A

Energy or particles emitted from a source, which when absorbed produces ions (charged atoms)
These ions may cause abnormal chemical reactions to occur or change the chemical properties of the material that absorbed it

47
Q

What does the unit of radiation becquerel measure?

A

The level of activity of the source

48
Q

What does the unit of radiation gray measure?

A

Measures the absorbed dose

49
Q

What does the unit of radiation sievert measure?

A

The effective dose taking into account the type of radiation

50
Q

What is the difference between exposure and contamination?

A

Exposure- when a person or object absorbs ionising radiation when within range of a source of radiation
Contamination- Direct contact with a source of radiation

51
Q

What are some examples of sources of radiation?

A

Radon from the ground- 50 percent
Internal body sources- 11 percent
Medical exposure
gamma rays- 14 percent

52
Q

What are the effects of ionising radiation on living organisms?

A

Formation of free radicals-
Ions are highly reactive with unpaired electrons
Can cause biologically damaging reactions
They may produce more stable molecules that cause damage within the cell
Damage to the nucleus of the cell-
Impacts existing and future cells
Damage to egg and sperm cells (gonadic effects)
cells that are more genetically active are most impacted (divide rapidly)

Low doses may cause no long term effects
High doses cause rapid cell death, damage to bone marrow