Hazmat Responses: Surviving the Initial Response Flashcards
A first responders success depends upon these 5 things
- Level of planning before the incident
- Training
- Ingenuity
- Capabilities and limitations of equipment
- Ability to use equipment
Defined as anything that can harm people, property, or the environment
Hazardous material
A material or device created specifically to explode on demand
Explosive
Liquid with a flashpoint below 100F
Flammable liquid
Liquid with a flashpoint of 100F or greater
Combustable liquid
Controlling factor in determining the flashpoint of a liquid
Temperature of the liquid
Poisons can enter the body in one of four ways
- Inhalation
- Ingestion
- Absorption
- Entry through a wound
Where the term ionizing radiation originates
When particles collide with an electron, the tendency is to remove that electron from the atom thus leaving a particle that is now an ion
Hazard classes
- Class 1
- Class 2
- Class 3
- Class 4
- Class 5
- Class 6
- Class 7
- Class 8
- Class 9
- Class 1 = Explosives
- Class 2 = Gases
- Class 3 = Flammable liquids
- Class 4 = Flammable solids
- Class 5 = Oxidizers
- Class 6 = Poisonous
- Class 7 = Radioactive
- Class 8 = Corrosive
- Class 9 = Misc hazards
Precedence of Hazard Table
Used to classify hazardous materials
OSHA uses this term to define any chemical which is a physical hazard or health hazard
Hazardous chemical
OSHA Hazardous Waste Operations and Emergency Response Standard uses this term
Hazardous substance
First responders trained to this level are to initiate an emergency response sequence
Awareness level
The first responders trained to this level function to contain the release from a safe distance and keep it from spreading and prevent exposures
Operations level
The responder trained to this level will respond to an incident with the purpose of stopping the release
Technician level
This responder is trained to provide support to the technician
Specialist
The process of containing a release may be …
- Passive
- Active
Important actions to take prior to even considering containing a release (5)
- Identify the material and asses potential harm
- Isolate affected areas
- Account for all personnel who might have been exposed
- Provide medical care and decontamination to those exposed
- Protect people from the potential of exposure
First responders consider this to be “aspirin” for all incidents
Water
Clean up involve three distinct steps
- Removal of waste
- Disposal of the waste material
- Restoration of the contaminated area
Most valuable (important) role of a first responder
Ensure everyone goes home
Defesive practices include (4)
- Contain release
- Protect people
- Protect property
- Protect environment
To encourage and support emergency planning efforts at the state and local levels and provide the public and local governments with information concerning potential chemical hazards present in their communities
Purpose of Emergency Planning and Community Right-to-Know Act (EPCRA)
EPCRA include 4 major sections
- Emergency planning
- Community Right-to-Know requirements
- Emergency release notification
- Toxic chemical release reporting
This tier identifies a hazard by category and is the minimum requirement by law
Tier I
This tier provides greater detail and identifies materials by specific chemical name
Tier II
Tier reports must be submitted every
Year
TPQ
Threshold Planning Quantities
TPQ quantities are measured in ___ rather then in ___
- Pounds
- Gallons
Local Emergency Planning Committee (LEPC) is responsible for developing an emergency response plan that should include these 7 components
- Emergency response procedure
- Evacuation plan
- Notification procedure
- Determination of the severity of a release and the populations likely affected
- Ways to notify the public when a release happens
- Identification of emergency resources and equipment
- Determination of training for local responders
LEPC is responsible for evaluating the emergency response plan every ..
Year
Hazard assessment involves three factors
- The material
- The container
- The environment
- Its physical state
Three stages of hazardous materials incident
- Containers that have released their contents
- Containers that have an ongoing release
- Containers that have not yet released their contents (but have the potential to do so)
Two components to aid in determining the amount of gas that could release from a container
- Size of the compressed gas cylinder
- Pressure at which the material is stored
Defensive actions (3)
- Protect People
- Protect Property
- Protect environment
When deciding on how best to manage an incident these 3 things must be considered
- Material
- Container
- Environment
Regulation governing ground transportation requires an emergency telephone number to be included on shipping papers
Code of Federal Regulations
Emergency telephone must be monitored at all times while material is …
In transportation and storage incidental to transportation
CHEMTREC
Chemical Transportation Emergency Center
CHEMNET
Nationwide network of response contractors
Support during hazardous materials incidents can be divided into the following three categories
- Technical support
- Legal support
- Logistical support
At the local and state level first responders should be able to contact the following 9 agencies
- Emergency management
- Public works
- Highway dept
- Health dept
- Game dept
- Environmental regulatory and enforcement
- Motor carrier law enforcement
- Occupational safety
- Public affairs
3 documents capable of providing first responders with specific info
- Emergency Response Guidebook
- MSDS
- Hazardous Materials Guid for First Responders
Latest edition of the ERG
2004
ERG2004 contains ___ individual guides
61
When finding n.o.s. (not otherwise specified) in the ERG2004
Means the actual chemical name is not listed in the regulations
A distinct advantage provided by the ERG2004
Provides recommendations for the size of immediate isolations areas
Color pages where the “Table of Initial Isolation and Protective Action Distances” is found in the ERG
Green pages
Atmospheric mixing is ___ effective at dispersing vapor plums during nighttime thus protective action distances ___
- Less
- Increase
Should be one of the first decisions made
To isolate and evacuate
Each MSDS shall contain at least the following (12)
- Identity used on the label
- Physical and chemical characteristics
- Physical hazards of the hazardous chemical
- Health hazards
- Primary routs of entry
- OSHA permissible exposure limits
- If listed in the National Toxicology Program (NTP)
- Precautions for safe handling
- Control measures
- Emergency and first aid procedures
- Date MSDS was prepared
- Name, address, telephone number of the chemical manufacture
On MSDS, N/A =
Not Available
MSDS sheets are required on products known to have either a ___ hazard or a ___ hazard
- Health
- Physical
Type of hazard that includes carcinogens, toxins, irritants, corrosive, sensitizers, and agents that damage the lungs, skin, or eyes
Health hazard
Type of hazard that includes chemicals that are compressed gas, flammable, an oxidizer, or water reactive
Physical hazard
Chemical and physical properties that are of importance to first responders (4)
- Specific gravity
- Vapor density
- Miscibility
- Solubility
Capable of being liquified or dissolved
Solubility
Will mix with another material, such as water
Miscibility
minimum temperature of a liquid at which it gives off sufficient vapors to form an ignitable mixture with the air near the surface
Flash point
Defined as the maximum concentration of chemical to which an individual can be exposed during various periods of time without suffering adverse health effects
Exposure limit
Those requiring access to MSDS sheets (3)
- Employees who use the chemicals in the workplace
- Vendors who sell to employers
- LEPC
Those exempted from access to MSDS
- Retail vendors who do not sell to employers and operations where employees only handle chemicals in sealed containers
- Employee exposure is no greater then normal consumer use
Intended users of the Hazardous Materials Guide for First Responders
First responders trained to the Awareness and Operations level
To select appropriate response tactics first responders should alway pay attention to four things
- Specific gravity
- Vapor density
- Miscibility
- Solubility
The lower the ppm value for any exposure limit the more ___ the material
Harmful
Best way to determine how to effectively manage any hazardous material incident
Identify it by name
Use of a materials identification number is referred to as a ___ in the federal transportation regulations
Marking
Hierarchy of hazardous materials identification Best = Better = Good = (*) =
Best = Name Better = 4-diget id number Good = Hazard class (*) = Synonym for various names
Types of stress a container can be exposed to (3)
- External heating
- Chemical reaction inside the container
- Physical damage
General characteristics of containers (2)
- Size
- Used for transport or fixed
Special characteristics of containers (4)
- What the container is constructed from
- Pressurized or not
- Type and configuration of intended openings
- Whether the container has the means to relieve internal pressure
Capacity of bulk highway cargo tank
9,000 gal of liquid
Capacity of high pressure containers intended for transport
11,000 gal
Capacities of bulk rail tank cars:
Non-pressurized =
Pressurized =
Chlorine =
Non-pressurized = 10,000 - 26,000 gal Pressurized = 30,000 gal Chlorine = 90 tons
Bulk fixed storage tank capacities
Several hundren to several thousand gallons
Type of cargo tank that has a distinctive horseshoe shape
Insulated highway cargo tank
Type of container that usually presents the greatest danger
Pressurized container
Container pressure:
Low-pressure container=
High-pressure bulk transport container =
Low-pressure container= 25 to 75 psi
High-pressure bulk transport container = As high as 300 psi
Two primary characteristics for most compressed gas cylinders
- Pressure relief valve
- Rounded tank ends
Damage is especially troublesome when it occurs at ___ on a high pressure metal containers
The weld lines
Propane has an expansion rate of
270 to 1
The vapor space in a container is sometimes as high as ___% to ___% of the capacity of the container
15% to 20%
Presence of a container with an OPD is usually indicated by a ___
Triobular hand wheel
Defined as molecules with extremely high levels of energy and normal temps so that no reasonable about of pressure is capable of compressing these molecules into a liquid state
Nonliquified gas (eg. oxygen, nitrogen)
Cryogenics can reduce the temp of a material to …
-150F
Expansion ratios:
Liquid oxygen =
Liquid nitrogen =
Liquid oxygen = 857 to 1
Liquid nitrogen = 694 to 1
Factors to consider when evaluating the location of an incident and its exposures (5)
- Population density
- Location of highway
- Waterways
- Railroads
- Environmentally sensitive areas
Environmental factors (2)
- Weather
- Time of day
A communities critical systems include (4)
- Highways
- Waterways
- Utilities
- Industrial / Commercial areas
One of the best ways to provide for safe working conditions at night
Provide portable lighting
Defensive actions tat first responders can undertake (5)
- Prevent release
- Contain the release of liquid
- Contain the release of gas and vapor
- Contain the release of solid
- Protective action (evacuation/in-place protection)
Assessment of conditions should attempt to determine (3)
- Containers that have already released their contents
- Containers that have an ongoing release
- Containers that have not released their contents
Types of stress (3)
- Thermal
- Mechanical
- Chemical
The sound of gas and vapor escaping from an operating pressure relief device during a fire will increase in both __ and __ as internal pressure continues to rise
Volume and pitch
The weakest locations of non pressure containers
Ends
Indicators that underground utilities are nearby (4)
- Pad-mounted tranformers
- Manhole covers
- Valve boxes
- Utility poles outfitted with an attached cable that runs from the pole to an underground connection at its base
Booms are manufactured in ___ ft sections
10 foot