HazMat Flashcards
13 Lighter Than Air Gases
4H MEDIC ANNA
- Hydrogen
- Hydrogen Cyanide
- Helium
- Hydrogen Flouride
- Methane
- Ethylene
- Diborane
- Illuminating Gases
- Carbon Monoxide
- Acetylene
- Neon
- Nitrogen
- Ammonia
Elevated Temp Materials
- Liquid phase at a temp at or above 212oF
- Liquid phase with a flash point at or above 100oF that is intentionally heated and offered for transportation or transported at or above its flash point
- Solid phase at a temp at or above 464oF
ERG (Emergency Response Guide)
- ERG ID # Index (Yellow Pages)
- ERG Material Name Index (Blue Pages)
- ERG Initial Action Guides (Orange Pages)
- 3 Main Sections
- Potential Hazards
- Public Safety
- Emergency Response
- 3 Main Sections
Release
- Detonation - Instantaneous and explosive release of stored chemical energy of material. Results include framentation, disintegration, or shattering of the container; Duration: hundreds or thousands of a second
- Violent Rupture - Immediate release caused by runaway cracks. Ballistic behavior of container and contents. Occurs in 1 sec or less
- Rapid Relief - Fast release of pressurized haz material through properly operating safety devices caused by damaged valves. Several seconds to several minutes
- Spill/Leak - Slow release of material under atmospheric or head pressure thru holes, rips, tears or usual openings. Several minutes to several days
Dispersion Patterns/Engulfment
- Physical/chemical properties
- Prevailing weather conditions
- Local topography
- Duration of the release
- Control efforts of responders
- Hemispheric - Semicircular or dome-shaped
- Cloud - Ball-shaped
- Plume - Irregularly shaped
- Cone - Triangular
- Stream - Surface-following affected by gravity
- Pool - Three-dimensional
- Irregular
Awareness Level Personnel
- Recognize the presence or potential presence of a hazardous material
- Recognize the type of container at a site and indentify the material in it if possible
- Transmit info to an appropriate authority and call for appropriate assistance
- Establish scene control by isolating area and denying entry
Operations-Level Responders
Operations-Level Responders
.
- Indentify material
- Analyze an incident to determine the nature and extent of the problem
- Protect themselves, nearby persons, the environment and property
- Develop defensive plan of action (plan a response)
- Implement the planned response to mitigate or control a release from safe distance
- Evaluate progress of the actions
NFPA 704 diamond
- 12 O’clock: Red; Flammability
- 3 O’clock: Yellow; Instability
- 9 O’clock: Blue; Health hazard
- 6 O’clock: No specified color; White most common; Reactivity w/ water; oxidizer0

Department of Energy (DOE)
- Manages the national nuclear research and defense programs
- Including storage of high-level nuclear waste
Department of Homeland Security
- Prevent terrorist attacks within the US
- Reduce America’s vulnerability to terrorism
- Minimize the damage from potential attacks and natural disasters
- FEMA and US Coast Guard
Consumer Product Safety Commission
- Oversees and enforces compliance with the Federal Hazardous Substances Act, which requires that certain hazardous household products carry labeling for hazards
Dept of Defense Explosives Safety Board
- Provides oversight of the develpment, manufacture, testing, maintenence, demilitarization, handling, transport and storage of explosives, including chemical agents on DOD facilities worldwide
ATF and Department of Treasury
- Enforces laws relating to alcohol, tobacco, firearms, explosives and arson
Dept of Justice
- Assigns primary responsibility for response to threats or acts of terrorism within US territory to the FBI
- FBI is lead agency on terrorist incident scenes
- FBI duties:
- Investigate the theft of hazardous materials
- Collects evidence
- Prosecutes criminal violations
Corrosives
- Destroy or burn living tissue and have bad effects by virtue of thier corrosivity
- With exception of liquid and gas fuels, corrosives comprise the largest usage class (by volume) in industry
- Divided into 2 broad categories
- Acids
- Bases (alkalis or caustics)
- Hydrogen Peroxide is neither
Acid
- Any chemical that ionizes (breaks down) to yield hydrogen ions in water
- pH values 0-6.9
- May cause severe chemical burns to flesh and eye damage
- Contact causes immediate pain
- Examples: Hydrochloric acid, nitric acid, sulfuric acid
Base (alkalis)
- Water soluble compound that breaks apart in water to form a negatively charged hydroxide ion
- pH values of 8-14
- Breaks down fatty skin tissues and penetrate deeply into the body
- Can cause severy eye damage from adhering to eye tissues (More than acid)
- Does not normally cause immediate pain
- Common sign - greasy or slick feeling of skin
- Examples: Caustic soda, potassium hydroxide and other alkaline materials commonly used in drain cleaners
Aboveground Nonpressure tanks (aka atmospheric tanks)
- Up to 0.5 psi inside
- Common types:
- horizontal
- ordinary cone roof
- floating roof
- lifter roof
- vapordome roof
Aboveground Pressure storage tanks
- Low-pressure: 0.5-15 psi
- Pressure vessels: 15+ psi
- Examples:
- Dome roof
- Spheroid tank
- Noded spheroid
- Horizontal pressure vessel
- Spherical pressure vessel
- Cryogenic-Liquid storage tank
Bulk Transportation Containers
3 Main Categories
- Tank cars (railroad)
- Cargo tank trucks (highway)
- Intermodal containers (highway, railroad, or marine vessel)
Railroad cars
- Low-pressure or general service tank cars (nonpressure)
- transport haz and nonhaz w/ vapor pressures <25 psi at 105o - 115oF
- 4,000-45,000 gallons
- cylindrical w/ rounded ends (heads)
- Pressure tank cars
- flammable, non-flammable, poisonous gases
- >25psi at 68oF
- Cryogenic liquid tank cars
- tank-within-a-tank
- insulation and vacuum protects contents for 30 days
*
Other railroad cars
- Covered hopper cars
- dry bulk; grain, calcium carbide, ammonium nitrate, cement
- Uncovered hopper cars
- Coal, sand, gravel, rocks
- Pneumatically unloaded hopper cars
- unloaded by air pressure
- 20 - 80 psi
IM 102 intermodal tanks
- 14.5 - 25.4psi
IM 101 intermodel tanks
- 25.4 - 100 psi
Pressure intermodal tanks
- 100-500 psi
Nonintervention reasons
- Pre-incident eval calls for it
- Beyond capabilites
- Explosions imminent
- Container damage threatens massive release
Nonintervention actions
- Withdraw to safe distance
- Report scene conditions to telecommunications center
- Inititiate an incident mgmt system
- Call for additional resources
- Isolate the hazard area and deny entry
- Commence evacuation
Defensive operations reasons
- Pre-incident eval calls for it
- Responders have training and equip necessary to confine the incident to the area of origin
Defensive operations actions
- Report scene conditions
- Iniitiate incident mgmt system
- Call for additional resources
- Isolate hazard area and deny entry
- Establish and indicate zone boundaries
- Commence evac where needed
- Control ignition sources
- Use appropriate defensive control tactics
- Protect exposures
- Perform rescues when safe and appropriate
- Evaluate and report incident progress
- Perform emergency decon procedures
Defensive spill-control tactics
- Absorption
- Adsorption
- Blanketing/Covering
- Dam, dike, diversion, retention
- Vapor suppression
Tactics for reducing harm of material or diluting concentration
- Vapor dispersion
- Ventilation
- Dispersion
- Dilution
- Dissolution
- Neutralization
Physical methods of decon
- Remove the contaminant from a contaminated person without changing the material chemically
- Examples:
- Absorption
- Adsorption
- Brushing and scraping
- Dilution
- Evaporation
- Isolation and disposal
- Washing
- Vacuuming
Chemical methods for decon
- Chemical degradation
- Sanitization
- Disinfection
- Sterilization
- Neutralization
- Solidification
High explosives
- Detonate
- Detonation velocities 3,300 feet per seconde to 29, 900 fps
- Faster than speed of sound
- Plastic explosives
- Nitroglycerin
- TNT
- Blasting caps
- Dynamite
- Ammonium nitrate and fuel oil
Low explosives
- Deflegrate (burn rapidly; black powder)
- Confined in small spaces are used as propellants (bullets and fireworks)
Primary explosives
- Easily initiated; highly sensitive to heat
- Used as detonators
- Lead azide
- Mercury fulminate
- Lead styphnate
Secondary explosives
- Detonate only under specific circumstances
- Usually by activation energy from primary
- Less sensitive to initiating stimuli like heat and flame
- TNT
Liquified gas
- Propane or carbon dioxide
- Partially liquid at 70oF
Cryogen
- Refrigerated liquified gas
- Gas that turns into a liquid at or below -130oF
- Liquid oxygen
- Nitrogen
- Helium
- Hydrogen
- Argon
- LNG (Liquified natural gas)
Biological hazards
- Viruses
- Simplest types of microorganisms that can only replicate themselves in the living cells of their hosts
- Do not respond to antibiotics
- Bacteria
- Microscopic, single celled organisms
- Most do not cause diseases
- Rickettsias
- Specialized bacteria that live and multiply in the gastrointest tract of carriers (fleas and ticks)
- Smaller than bacteria; larger than virus
- Spread through bite and not human contact
- Biological toxins
- Produced by living organisms
- Organism is not harmful to people
- Some made synthetically and genetically altered in labs
- Botulinum and Ricin
Containers for radioactive materials
- Excepted - Very limited; no risk
- Industrial - Limited hazard; not identified
- Slightly contaminated clothing
- Lab samples
- Smoke detectors
- Type A - Maintain sufficient shielding under normal transportation conditions
- Type B - Normal shipping and sever accident conditions;
- Type C - Very rare packages for high-activity materials (plutonium) transported by aircraft
UN Hazard Classes
EGFFOTRCM
- Explosives
- Gases
- Flammable liquids
- Flammable solids; spontaneous combustion; emit flammable gases on contact with water
- Oxidizing substances and organic peroxides
- Toxic and infectious
- Radioactive materials
- Corrosive
- Miscellaneous dangerous
Emergency Response Guidebook
- Primarily a guide to aid emergency responders in quickly identifying the specific or generic hazards of materials involved in an emergency incident and protecting themselves and general public during the initial phase
- Does not address all circumstances
- Primary used for highway and railroad
- Limited value at fixed-facility
Degrees of Solubility
- Negligible - Less than 0.1%
- Slight - 0.1-1%
- Moderate - 1-10%
- Appreciable - 10-25%
- Completely - 25-100%
Non-water soluble liquids
- Gasoline
- Diesel fuel
- Pentane
Water-soluble liquids
- Alcohol
- Methanol
- Methyl ethyl ketone (MEK)
Six sides of incident
- Alpha
- Bravo
- Charlie
- Delta
- Top
- Bottom
Potassium chlorate
- White crystal or powder form explosive
- 83% of the power of TNT
- Common ingredient in fireworks
Urea nitrate
- Fertilizer based explosive
- Nitric acid and urea
- Prill used for de-icing sidewalks is urea
- Often sulfuric acid is added
- Similiar to ammonium nitrate
Peroxide based explosives
- Acetone peroxide
- Hexamethylene triperoxide diamine
- Mix hydrogen peroxide, acetone, and hydrochloric or sulfuric acid
- TATP is white crystalline powder; acrid smell
- TATP is yellowish to white
Vehicle bombs
- Most devestating of IED’s
- Easy to conceal
- Located in trunk
Pipe bombs
- 4-14 inches
- Steel or plyvinyl chloride pipe sections filled with explosive and capped on ends
- Filled w/ black powder or match heads
- Filled with nails to throw shrapnel 300 ft
- May be detonated with homemade fuse
- Explosive filler can get into the threads of pipe and make sensitive to shock or friction
Backpack bombs
- Electronic timers or radio controoled triggers so no external wires
- Even as small as cigarette pack
Blister agents
- Burn and blister skin or any party of body they contact
- Act on eyes, mucous membranes, lungs, skin and blood-forming organs
- Damage resp. tract when inhaled
- Vomiting and diarrhea when ingested
- Usually persistant
- May be employed as a colorless gas and liquid
- Oily liquids range from colorless to pale yellow to dark brown
- Several days or weeks to evaporate
Nerve agents
- Affect trasmission of impulses
- Most toxic of chemical warfare agents
- Stable, easily dispersed, highly toxic, and rapid effects when absorbed thru skin or respiratory system
- Tabun: low volatile; skin or inhaled
- Sarin: volatile; inhaled
- Soman: moderate; skin or inhaled
- Cyclohexyl sarin: low volatile; skin and inhaled
- V-Agent: low volatile; remains for long periods; skin and inhaled
Blood agents
- Chemical asphyxiant
- Interferes w/ body’s ability to use oxygen by preventing red blood cells from carrying oxygen or inhibiting cells to use oxygen for producing energy required for metabolism
- Arsine
- Hydrogen cyanide
- Cyanogen chloride
Choking agents
- Chlorine -
- Used during WWI
- Turns into gas heavier than air
- Not flammable, but can react explosively or form explosive compounds w/ other chemicals
- Odor like bleach
- Phosgene -
- colorless, nonflammable
- odor like freshly cut hay
- accounted for majority of chemical fatalities in WWI
- Gas at room temp
- boiling point is 47oF
Supplied-Air Respirators (SAR)
- Airline respirator
- Atmosphere suppying
- User does not carry air source
- Facepiece, belt or facefiece mounted regulator, voice comm, 300 ft of hose, emerg. escape pack
- Attached to air cylinders on cart or portable breathing-air compressor
- 5, 10, or 15 min worth of air to escape
- Type C respirator
- Adv: remove weight of SCBA
- Dis: Supply line damage; no more than 300 ft; hose entanglement
Air-Purifying Respirators (APRs)
- 3 types
- Particulate removing APRs
- Vapor and gas removing APRs
- Combo
- Powered or nonpowered
- No oxygen supply
- Protect only against specific contaminants at or below certain concentrations
- Do not protect against all chemical hazards
- Do not protect agains oxygen enriched or deficient atmospheres
- Disadv:
- Limited life of filters and canisters
- Need for constant monitoring of contaminated atmosphere
- Need for normal oxgen content of atmosphere
Particulate-Removing Filters
- 3 levels of filtration - 95, 99, 99.97%
- Filter degradation:
- N - Not resistant to oil
- R - Resistant to oil
- P - used when oil or nonoil lubricants are present
- Toxic dusts, mists, metal fumes, asbestos, some biological hazards
- HEPA filters for medicasl must be 99.97% efficient
- Particle masks (dust masks) protect from large size particles
- Very limited protection
- Not to be used chemical hazards or small particles such as asbestos
Vapor and Gas Removing Filters
- Use sorbent material to remove targeted vapor from air
- Color-coded
NFPA 704
- Standard System for the Identification of the Hazards of Materials for Emergency Response
Safety Data Sheets
- ID
- Hazard(s) id
- Composition/info on ingredients
- First aid measures
- Firefighting measures
- Accidental release measures
- Handling and storage
- Exposure controls/ personal protectoin
- Physical and chemical properties
- Stability and reactivity
- Toxilogical info
- Ecological info
- Disposal considerations
- Transport info
- Regulatory info
- Other info
Vapor pressure
- Pressure exerted by a saturated vapor above its own liquid in a closed container
- High temp = high vapor pressure
- Vapor pressures reported on MSDS’s are low
- Lower boiling point = Higher pressure
3 incident-based elements that affect selection of strategic mode
- Value
- Time
- Size
Simple asphyxiant vs Chemical asphyxiant
- Simple - Gases that displace oxygen necessary for breathing
- Chemical - Substances that prohibit the body from using oxygen. Even though oxygen is available, these substances starve the cells of the body for oxygen
Routes of entry
- Inhalation
- Ingestion
- Absorption
- Injection
Types of radiation
- Alpha - Not harmful outside the body. Very harmful if ingested or inhaled. Can be stopped by skin or sheet of paper
- Beta - More hazardous when inhaled or ingested. Travel up to 20 ft. Stopped by clothing or by less than .08 aluminum
- Gamma - X rays. Can pass thru body or be absorbed by tissue. 2 ft of concrete, several ft of earth or 2 inches of lead to stop
- Neutron - Highly penetrating. Soil moisture density gauges are source. Can cause secondary release of radiation when they interact with human body
Fire point
- Temp at which a liquid fuel produces sufficient vapors to support continuous burning. A few degrees above flash point.
Consist
- Rail shipping paper that contains a list of cars in the train by order
- Indicates cars that contain hazardous material
- Some include info on emerg ops
Polar solvent
- Flammable liquids that have an attraction for water
- When combined with water, the 2 liquids mix easily
- Alcohol, Methanol, MEK
SLUDGEM
Chemical warfare symptoms
- Salivation
- Lachrimation (tearing)
- Urination
- Defecation
- Gastrointestinal upset (cramping)
- Emesis (vomiting)
- Miosis (pinpointed pupils or Muscular twitching
Hydrocarbon
- Non-water soluble liquid
- Gasoline, diesel fuel, pentane
Alpha
- Rapidly lose energy when passing thru matter
- Emitted int the decay of the heaviest radioactive elements
- Uranium
- Radium
- Blocked by skin
- Very harmful if ingested or inhaled
- Stopped by sheet of paper
Beta
- Fast moving
- Positively or negatively charged electrons
- Tritium, carbon-14, strontium-90
- More penetrating than alpha but less damaging over equal distances
- Capable of penetrating skin
- Travel 20 ft in air
- Stopped by layer of clothing or aluminum
Gamma
- High energy photons
- Often accompany alpha or beta particles from nucleus
- No charge, no mass
- Very penetrating
- Potassium-40, cobalt-60, iridium-192, cesium-137
- Easily passes thru body
- 2 ft of concrete, several feet of earth, 2” of lead
Neutron
- Ultrahigh energy particles
- Have a mass but no electrical charge
- Highly penetrating
- Soil moisture density gauges; research labs; operating nuclear power plants
- Release secondary radiation when they interact with human body