Haz Com Flashcards

1
Q

If you are exposed to hazardous chemicals at work, WHICH standard will help you identify the hazards of those materials and how to use them safely.

A

OSHA’s Hazard Communication Standard: 29 CFR 1910.1200

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2
Q

OSHA’s Hazard Communication Standard (HCS) requires

employers and manufacturers to develop and distribute WHAT chemical information? (for each)

A

Manufacturers: the chemical hazards in the workplace must be classified, and labels and SDS information must be prepared and properly convey those hazards. Employers: must establish a workplace program and train employees on the chemical hazards.

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3
Q

OSHA’s Hazard Communication Standard (HCS) requires what 4 things be provided as information to employees regarding the hazardous chemicals to which they are exposed?

A
  1. a hazard communication program* (HCP),
  2. labels and other forms of warning,
  3. safety data sheets, and
  4. information and training.
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4
Q

What does HCS stand for and what does it refer to?

A

Hazard Communication Standard- is the OSHA rule which requires “Right to Understand (2012)” for chemical hazards in the workplace.

Note: The old HCS 1994 gave workers the right to know, but the new HCS 2012 gives workers the right to understand

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5
Q

The HCS 2012 provides a common and coherent approach to _____ chemicals and communicating hazard information.

A

classifying

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6
Q

Physical hazards - a chemical that is classified as posing one of the following hazardous effects (8):

A

explosives
flammables (gases, aerosols, liquids, or solids)
oxidizers (liquid, solid or gas)
self-reactive; pyrophoric (liquid or solid)
self-heating
organic peroxides
corrosive to metals
gas under pressure or in contact with water emits flammable gas

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7
Q

a chemical which is classified as posing one of the following hazardous effects (9):

A
acute toxicity (any route of exposure)
skin corrosion or irritation
serious eye damage or eye irritation
respiratory or skin sensitization
germ cell mutagenicity
carcinogenicity
reproductive toxicity
specific target organ toxicity (single or repeated exposure) or
aspiration hazard
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8
Q

Under the HCS 2012, which of the following is an example of a physical hazard?

a. Reproductive toxicity
b. Skin irritant
c. Corrosive to metal
d. Carcinogen

A

C. Corrosive to metal

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9
Q

Which of the following are small particles, usually formed when solid metal is heated and vaporized and then condenses as tiny particles?

a. Mists
b. Vapors
c. Gases
d. Fumes

A

D. Fumes

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10
Q

Define:

Dusts 
Fumes
Fibers 
Mists 
Vapors 
Gases 
Solids
A

Dusts - are finely divided particles. Example - wood dust.

Fumes - are even smaller particles usually formed when solid metal is heated and vaporized, and then condenses as tiny particles.

Fibers - are similar to dusts but are of an elongated shape. Examples - asbestos and fiberglass.

Mists - are liquid droplets that have been sprayed into the atmosphere.

Vapors - are gases formed when liquid evaporates.

Gases - are substances that are normally airborne at room temperature. A vapor is the gaseous phase of a substance which is a normally a liquid or solid at room temperature.

Solids - such as metal, treated wood, plastic.

Liquids - the most common form in the workplace.

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11
Q

What is the most common route of entry for hazardous substances?

a. Ingestion
b. Inhalation
c. Absorption
d. Injection

A

b. Inhalation

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12
Q

To eliminate or reduce exposure to hazardous chemicals, the use of an effective “Hierarchy of Controls” (HOC) is encouraged by WHAT standard?

A

ANSI/ASSP Z10-2012 Standard; Occupational Health and Safety Management Systems.
-This standard defines minimum requirements for an occupational health and safety management system (OHSMS)

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13
Q

What is the list of the hierarchy of controls (6)?

A

ESEWAP:
Elimination: The best solution is to totally eliminate hazardous substances in the workplace.
Substitution: Substitution is the next-best solution. Replace a toxic substance with a less-toxic substance. If you can’t get rid of the toxic substances, you may be able to replace them with substances that are at least less toxic.
Engineering Controls: Redesign or modify processes that use toxic chemicals to eliminate or reduce exposure to the chemical hazard itself.
Warnings: Use container labels and signs to warn employees about the dangers of the chemicals they are using.
Administrative Controls: The primary focus is to develop and incorporate safer behaviors and work practices through written safety policies and rules, supervision, and training. This strategy is a challenge because supervisors must regularly monitor their employees as they perform tasks. Bottom line, these controls work only so long as employees “behave” properly.
Personal Protective Equipment (PPE): The use of PPE is probably the most common strategy, and mandatory when working with hazardous chemicals. PPE forms a barrier between workers and hazards. Once again, the chemical hazard is neither eliminated nor reduced, and a high reliance is placed on appropriate use of PPE for this strategy to be successful.

(The first three strategies focus on doing something with the hazard. The last three strategies focus on doing something with behaviors to reduce exposure to the hazard.)

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14
Q

Under the Hierarchy of Controls, elimination, substitution, and engineering controls are given higher priority because _____.

a. they are most effective in manipulating behaviors
b. they focus on the greatest number of causes for accidents
c. they are used when behaviors can’t be effectively controlled
d. they focus on doing something with the hazard

A

d. they focus on doing something with the hazard

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15
Q

Under the new HCS 2012, labels on containers shipped from manufacturers or distributors must be labeled, tagged or marked with the following six items:

A
  1. Product Identifier - This should include the chemical identity of the substance.
  2. Signal word - Signal words used in GHS are “Danger” and “Warning.” Danger is for the more severe hazard categories.
  3. Hazard Statements - This is a phrase assigned to a hazard class and category that describes the nature of the hazards of a hazardous product, and the degree of the hazard.
  4. Pictograms - These include symbols plus other elements, such as a border, background pattern or color that conveys specific information.
  5. Precautionary statements - These are phrases (and/or pictograms) that describe the recommended measures to minimize or prevent adverse effects resulting from exposure to a hazardous product.
  6. Supplier identification - This contains the name, address, and telephone number of the manufacturer or supplier of the substance or mixture.
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16
Q

What is the most common OSHA citation related to the HCS 2012 standard?

a. Lack of proper SDS documentation
b. Use of primary containers in the workplace
c. Improperly labeled secondary containers
d. Insufficient personal protective equipment

A

c. Improperly labeled secondary containers

17
Q

The employer must ensure that each workplace or secondary container of hazardous chemicals in the workplace is labeled, tagged or marked with either:

A

The information required on shipped container labels;
OR
Product identifier and words, pictures, symbols, or combination thereof, which provide at least general information regarding the hazards of the chemicals, and specific information regarding the physical and health hazards of the hazardous chemical.

18
Q

If you saw a container with a pictogram with a skull and crossbones, what would it mean to you?

a. Target organ toxicity
b. Acute toxicity (fatal or toxic)
c. Carcinogenic
d. Toxic narcotic effects

A

b. Acute toxicity (fatal or toxic)

19
Q

While the GHS uses a total of nine pictograms, OSHA will only enforce the use of eight. Which one will it NOT enforce?

A

The environmental pictogram is not mandatory but may be used to provide additional information.

20
Q

Which SDS section includes containment and cleanup practices to prevent or minimize exposure to people, properties, or the environment?

a. Section 5: Fire-Fighting Measures
b. Section 6: Accidental Release Measures
c. Section 7: Handling and Storage
d. Section 8: Exposure Controls/Personal Protection

A

b. Section 6: Accidental Release Measures

21
Q

In which section of the SDS would you find a description of the delayed, immediate, or chronic effects from short- and long-term exposure?

a. Section 9: Physical and Chemical Properties
b. Section 10: Stability and Reactivity
c. Section 11: Toxicological Information
d. Section 16: Other Information

A

c. Section 11: Toxicological Information

22
Q

How soon must manufacturers add new information to an SDS after becoming aware of any significant new information regarding the hazards of a chemical, or ways to protect against the hazards?

A

Within three months

23
Q

In terms of SDS training requirements, Employees must be informed of (3):

A
  1. the requirements of the HCS 2012
  2. any operations in their work area where hazardous chemicals are present
  3. the location and availability of the written hazard communication program (including the required list(s) of hazardous chemicals and SDSs required by the HCS)
24
Q

Additional HazCom training requirements: (4)

A
  1. Methods and observations that may be used to detect the presence or release of a hazardous chemical in the work area.
  2. The physical hazard, health hazards, simple asphyxiation, combustible dust, and pyrophoric gas hazards, as well as hazards not otherwise classified, of the chemicals in the work area.
  3. The measures employees can take to protect themselves from these hazards, including specific procedures the employer has implemented to protect employees from exposure to hazardous chemicals, such as appropriate work practices, emergency procedures, and personal protective equipment to be used.
  4. The details of the hazard communication program developed by the employer, including an explanation of the labels received on shipped containers and the workplace labeling system used by their employer; the safety data sheet, including the order of information and how employees can obtain and use the appropriate hazard information.
25
Q

Who is responsible for training temporary employees (the host company or employment agency)?

A

Training temporary employees is a responsibility that is shared between the host employer and temporary agency.

Host Employer: The host employer is responsible for training on the company’s HCS program requirements including specific labeling, chemical hazards and safe work procedures in their workplace.

Temporary Agency: The temporary agency, in turn, maintains a continuing relationship with its employees and would be expected to inform employees of the general requirements of the HCS standard.

26
Q

What training is required for employees expected to moderate or control the impact of the emergency in a manner similar to a first responder?

A

Where employees are expected to moderate or control the impact of the emergency in a manner similar to an emergency responder, training on an Emergency Response Plan as described in 1910.120(l), Hazardous Waste and Emergency Operations (HAZWOPER), would be required.

27
Q

If the employer merely intends to evacuate the work area, training should focus on the _____.

a. Emergency Action Plan
b. Command Post Operations Plan
c. Fire Brigade Operations Plan
d. Emergency Response plan

A

a. Emergency Action Plan