Halogens Flashcards

1
Q

At room temperature what colour is Fluorine

A

Yellow gas

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2
Q

At Room temp what colour is Chlorine

A

Pale green

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3
Q

At room temp what colour is Bromine

A

Brown LIQUID

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4
Q

At room temp what colour is iodine

A

dark grey SOLID

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5
Q

Why do boiling points of halogen increase down the group

A

Number of electrons in Halogen molecules increases so strength of van der waals forces of attraction between molecules increases

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6
Q

What is an oxidising agent

A

A species that oxidises another substance by removing electrons from it

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7
Q

Halogens are good…

A

oxidising agents

- they are reduced themselves during reaction

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8
Q

What happens to oxidising ability down the group

A

decreases, the atomic radii increases and so does shielding meaning attraction between nucleus and electron decreases and oxidising ability decreases and it cannot gain electrons as easily

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9
Q

What colour is Chlorine in water

A

pale green

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10
Q

What colour is Bromine in water

A

orange

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11
Q

what colour is iodine in water

A

brown

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12
Q

What colour is chlorine in Cyclohexane

A

pale green

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13
Q

Colour of bromine in cyclohexane

A

orange

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14
Q

colour of iodine in cyclohexane

A

violet

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15
Q

Halide ions are good…

A

reducing agents

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16
Q

Trend in reducing ability of halide ion

A

the reducing ability increases down the group as the ion is lager and loses the electron more easily

17
Q

How can you identify Halide ions

A

acidified silver nitrate solution

18
Q

When you react fluoride with acidified silver nitrate solution what is observed

A

Fluoride ions from silver fluoride (AgF) no precipitate seen
soluble salt

19
Q

When you react Chloride with acidified silver nitrate solution what is observed

A

AgCl
White precipitate
insoluble

20
Q

When you react bromide with acidified silver nitrate solution what is observed

A

AgBr
cream precipitate
insoluble

21
Q

When you react iodide with acidified silver nitrate solution what is observed

A

AgI
Yellow
insoluble

22
Q

Other than colours of silver salt, what can confirm the identity of halide ions

A

Solubility of silver halides in ammonia

23
Q

What is the solubility of AgCl in ammonia

A

Dissolves in DILUTE ammonia solution

24
Q

Solubility of AgBr in ammonia

A

Does not dissolve in dilute ammonia solution

DOES dissolve in CONCENTRATED ammonia solution

25
Q

Solubility of AgI in ammonia

A

Doesn’t dissolve in dilute or conc ammonia solution

26
Q

What is a disproportionation reaction

A

simultaneously oxidised and reduced

27
Q

What is the Chlorine and water treatment equation

A

Cl2(aq) + H2O(l) <=> HClO(aq) + HCl(aq)

28
Q

Why is silver nitrate acidified

A

to remove ions that would interfere with test

prevent formation of silver precipitate compounds that would interfere with test

remove ions thats react with silver nitrate

29
Q

Why is Hcl not used to acidify silver nitrate solution for the test for halide ions

A

would form a white precipitate which would interfere with results of the test