Halide tests Flashcards

1
Q

What are halide tests based on?

A

Precipitate formation and solubility

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2
Q

How can the halide ion be determined in aqueous solution?

A

Use of a solution of silver nitrate followed by the addition of dilute ammonia solution

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3
Q

What can be observed when reacting chloride ions with silver nitrate?

A

White precipitate

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4
Q

What can be observed when reacting bromide ions with silver nitrate?

A

Cream precipitate

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5
Q

What can be observed when reacting iodide ions with silver nitrate?

A

Yellow precipitate

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6
Q

What can be observed when reacting chloride ions with dilute ammonia?

A

White precipitate dissolves

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7
Q

What can be observed when reacting bromide ions with dilute ammonia?

A

No observable reaction

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8
Q

What can be observed when reacting iodide ions with dilute ammonia?

A

No observable reaction

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9
Q

What can be observed when reacting chloride ions with concentrated ammonia?

A

N/A

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10
Q

What can be observed when reacting bromide ions with concentrated ammonia?

A

Cream precipitate dissolves

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11
Q

What can be observed when reacting iodide ions with concentrated ammonia?

A

No observable reaction

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12
Q

Write ionic equation for the reaction between the chloride ions and silver ions

A

Ag+ (aq) + Cl- (aq) → AgCl (s)

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13
Q

Write ionic equation for the reaction between the chloride ions and silver ions

A

Ag+ (aq) + Cl- (aq) → AgCl (s)

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14
Q

Write ionic equation for the reaction between the bromide ions and silver ions

A

Ag+ (aq) + Br- (aq) → AgBr (s)

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15
Q

Write ionic equation for the reaction between the iodide ions and silver ions

A

Ag+ (aq) + I- (aq) → AgI (s)

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16
Q

Why is the halide test left til last?

A

Both silver carbonate and silver sulphate are insoluble white precipitates
Would give false positives for chloride ions