Gypsum Products Flashcards
Rocks or solid particles which were ground to powder form and the heated
Gypsum
Example of gypsum products
- Orthoplaster
- Dental stone
- Plaster of paris
Gypsum produced for dental applications
Calcium sulfate dihydrate
Process of heating gypsum
Calcination
Heating is done in a kettle or an open bath
Open calcination
Stirring in open calcination
110 degrees celcius to 120 degrees celsius or
230 degrees farenheit to 250 degrees fahrenheit
Product of open calcination
Beta hemihydrate or plaster of paris
Beta hemihydrate is also known as
Plaster of paris
Consists of large, irregularly shaped orthorombic crystal particles with capillary pores
Plaster of paris
Spongy and irregular in shape
Crystals
Done in an autoclave and there’s a pressure involved
Closed calcination
Pressure and temperature of closed calcination
16 psi
120 degrees celcius to 130 degrees celcius
Product of closed calcination
Alpha hemihydrate or dental stone
Alpha hemihydrate is also known as
Dental stone
Consists of smaller, regularly shaped crystalline particles in the form of rods or prisms
Dental stone
Crystals are prismatic and more regular in shape
Dental stone
Used to take impression
Impression/ soluble plaster
Used to make study cast or model for records purposes
Plaster of paris
Stronger than plaster of paris
Dental stone ( class 1 )
Used as working cast that can withstand forces applied
Dental stone (class 1)
Stronger than class 1 dental stone
Dental stone high strength or class 2 dental stone
Used as working die for crown restoration and other treatments needing accurate measurements
Dental stone high strength (class 2 dental stone)
Refers to single tooth or several teeth
Die material
Used as inventing medium to compensate the high shrinkage of metals such as chrome cobalt ion
Dental stone high strength high expansion
Other uses of gypsum products:
- Used for ceramics
- Used for medical purposes: cast for broken bones
- Used to stabilize articulation between upper and lower cast
Addition of powder to water until the mixing time is completed
Mixing time
Time of mechanical mixing
20 to 30 seconds
It requires atleast a minute to obtain a smooth mix
Hand spatulation
Time available to use a workable mix
Working time
Maintained to perform one or more tasks
Uniform consistency
Measured from the time of mixing to the point where the consistency is no longer acceptable for the product’s intended purpose
Working time
Time adequate for working time
3 minutes
Time that elapses from the beginning of mixing until the material hardens
Setting time
Measured by penetration tests
Setting time
Types of penetration test
- Vicat needle
2. Gilmore needle
Measure initial setting time (1/4 lb)
Vicat needle
Measures final setting time 1/4 and 1 lb
Gilmore needle
Measured from the start of mixing until the 2nd increase of temperature
Initial setting time
Time for initial setting time
7-13 minutes
Measured from the start of mixing until the 2nd decrease of temperature
Final setting time
Time for final setting time
20 minutes
Significance of finding initial setting time
- Time to trim off extra plaster or stone that overflowed
2. To prevent the breakage of the cast
Significance of finding final setting time
- To prevent premature separation
2. To prevent powdery casts
Manipulation of gupsum products:
✔️ know the WP ratio
✔️ put the water first then the powder in the bowl
✔️ let them settle for 30 seconds to remove air
✔️ mix it using rotatory motion at 120 rpm for 1 1/2 minutes
✔️ tap the mixture to released entrapped air
Theoretical factors affecting setting time
- Number of nuclei
- Solubility of the hemihydrate
- Rate of crystal growth
Number of nuclei crystallization
Greater number of nuclei, decrease ST, the shorter
Lesser number of nuclei, increase ST, the longer
Solubility of the hemihydrate
More soluble, the faster the ST
Rate of crystal growth
Faster rate of crystallization, faster ST
Practical factors affecting setting time
- Presence of impurities
- Fineness
- WP ratio
- Mixing time
- Temperature
- Accelerators and retarders
Decrease ST =
Faster setting
Particle size and shape of crystals
Fineness
Smaller crystals, more soluble, faster
Fineness
Too thin
Prone to air bubbles
Too thick
Not all powder will be mixed with water
WP ratio
More water, less powder, longer setting time
Less water, more powder, shorter setting time
Mixing time
2 minutes
Longer time, faster mixing rpm, faster setting time
Mixing time
Up to 50 degrees celcius
Accelerator
Above 50 degrees celcius
Retarder
Most practical way for a clinician to control setting time
Altering temperature
Tend to remove the surface coating of crystals making them more soluble to water
Accelerators
Best accelerator regardless of concentration
K2SO4
Tend to create surface coating of crystals making them less soluble to water
Retarders
Examples of retarder
- Borax
- Nitrates
- Citrates
- Higher conc of NaCl and Na2SO4
Plaster impression
WP ratio:
Psi:
Setting expansion:
.50-.75
290-870
0-.15 %
Plaster of paris
WP ratio:
Psi:
Setting expansion
.45-.50
1300
0-.30%
Dental stone
WP ratio:
Psi:
Setting expansion
.28-.30
3000
0-.20%
Die stone
WP ratio:
Psi:
Setting expansion
.22-.24
5000
0-.10%
Dental stone high strength hig expansion
WP ratio:
Psi:
Setting expansion
.18-.22
7000
.10-30%
Why is that the WP ratio for plaster impression is high?
So that it can flow more because it’s for impression taking
Factors affecting compressive strength
- Shape and size of the particles
- WP ratio
- Mixing technique
- Use of chemical modifiers
Factors affecting setting expansion
- WP ratio
- increase water, decrease setting expansion
- increase powder, increase setting expansion - Addition of chemical modifiers
- potassium sulfate
Accelerators
ST: -
SE: -
S : -
Retarders
ST: +
SE: -
S: -
Particle size
ST: +
SE: +
S: +
WP ratio
ST: +
SE: -
S: -
Spatulation
ST: -
SE: +
S: -
Temperature
ST: -
SE: 0
S: 0
Care for gypsum products
- Put it in a cool dry place
2. Place it in air tight container