Gypsum Flashcards

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1
Q

How does a gypsum cast replicate the dentition?

A

Provides a positive replica of the dentition (as opposed to negative i.e impression)

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2
Q

What are the main functions of gypsum study casts?

A
  1. Records the position, shape and dimensions of teeth
  2. aids visualisation/assessment of dentition
  3. Enables manufacture of dental prostheses
    - e.g denture framework, crowns etc
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3
Q

What are some uses of gypsum?

A
  1. Cast (plaster/stone)
  2. Die (stone/improved stone)
  3. Mould material (stone)
  4. Investment binder (stone)
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4
Q

How is gypsum manufactured?

A
  1. Calcium sulphate do hydrate is heated to produce calcium sulphate hemihydrate
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5
Q

What are the 3 main types of gypsum?

A
  1. Plaster (beta-hemihydrate)
  2. dental stone (alpha-hemihydrate)
  3. Densite (improves stone)
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6
Q

How is gypsum plaster produced?

What structure does it have?

A
  1. Heated in open vessel

- creates powder with large porous, irregular crystalline structure

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7
Q

How is dental stone produced?

What is it’s structure?

A
  1. Heated in an autoclave

- non-porous, regular crystalline structure (requires less water)

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8
Q

How is densite produced?

What is its structure?

A
  1. Heated in presence of calcium chloride and magnesium chloride
    - compact smooth particles
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9
Q

How is gypsum study cast material produced?

A
  1. Reverse of manufacturing process

- water is added to the powder to produce the setting material

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10
Q

What are the mixing ratios of plaster and stone?

A

Water Powder
Plaster 50-60ml 100g
Stone 20-35ml 100g

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11
Q

The theoretical mixing ratio is 18.6ml of water to 100g of powder - why is this less than the values used?

A
  1. In practice excess water is needed for a workable mass and correct consistency
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12
Q

Summarise the setting process of gypsum

A
  1. Hemihydrate dissolves in water
  2. Dihydrate forms
  3. Dihydrate solubility los = supersaturated solution
  4. Impurities are present
  5. Dihydrate crystals precipitate on impurities as crystals
  6. More hemihydrate dissolved
  7. Continues until all hemihydrate is dissolved
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13
Q

Describe the initial set of gypsum and the properties of the material at this stage

A
  1. Dihydrate crystals come into contact - ie push apart
  2. Expansion starts
  3. Properties of weak solid and will not flow
  4. Can be carved
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14
Q

Describe the properties of gypsum material at the final setting stage

A
  1. Strong and hard enough to be worked

- strength continues to develop

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15
Q

What is used to measure initial and final setting times?

A

Gilmore needles

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16
Q

What happens to excess water during the setting reaction?

A
  1. During setting, excess water is trapped in the powder mass
  2. On completion of setting
    - excess water evaporates
    - voids are produced (porosity)
17
Q

What properties are important to consider for gypsum?

A
  1. Reproduction of surface detail
  2. Strength
  3. Surface hardness
  4. Setting time
  5. Expansion
18
Q

What width of groove can be reproduced by gypsum?

Is this suitable?

A

28-40microns

- yes, a suitable material must reproduce a 50micron wide groove

19
Q

What is the compressive strength of gypsum stone and densite after:
1 hour
24 hours

A
  • after 1 hour - 28-38 MPa

* after 24 hours - 75 MPa

20
Q

What factors reduce setting time of gypsum ?

A
  1. Increased powder
  2. Increased spatulation
  3. Increased impurities
    (These 3 also increase expansion)
  4. Potassium sulphate
21
Q

What factors increase setting time?

A
  1. Borax
22
Q

Explain how spatulation reduces setting time and increases expansion

A
  1. Increased spatulation breaks down growing crystals
  2. Fragments act as nuclei of crystallisation
  3. More growing crystals - come into contact sooner
    Therefore: decreased setting time and increased expansion
23
Q

How does increased powder to water ratio reduce setting time and increase expansion?

A
  1. More nuclei of crystallisation per unit volume
  2. Crystals come into contact sooner
  3. Faster set and greater expansion
24
Q

What are the expansion levels of gypsum plaster, stone and densite?

A
  1. Plaster: 0.2%-0.3%
  2. Stone: 0.08-0.1%
  3. Densite: 0.05-0.07%
25
Q

Why is slight expansion of gypsum somewhat beneficial?

A
  1. Allows for the model to be a little too big

- meaning crowns, bridges and dentures won’t be too tight a fit when placed in the mouth

26
Q

Why does water temperature have a variable effect on the setting time of gypsum?

A
  1. Rate of diffusion of ions increases with temperature

2. Solubility of hemihydrate decreases with increased temperature

27
Q

What temperature ranges reduce setting time of gypsum?

A

10-40 degrees Celsius

28
Q

What temperature range increases setting time of gypsum?

A

40-100 degrees Celsius

29
Q

Explain why potassium sulphate decreases setting time

A
  1. Produces syngenite
    - crystallises rapidly- encouraging growth of more crystals
    - decreases setting time
30
Q

Explain why borax increases setting time of gypsum

A
  1. Forms calcium borate - deposits on dihydrate crystals

- delays setting process (increases setting time)

31
Q

Dental stone needs to be compatible with the impression material to provide adequate surface detail, what is meant when we say it must “wet” the impression material?

A

•no resistance to flow over surface; avoid bubble formation

32
Q

What is a major weakness of gypsum?

A

It is brittle

- i.e. will readily fracture under a small amount of strain

33
Q

Brittleness isn’t assessed directly, instead flexural strength is used. What is the flexural strength of gypsum?

A

15-20 MPa

34
Q

Summarise the advantages of gypsum

A
  1. Dimensionally accurate and stable
  2. Low expansion (<0.1%) of stone/densite
  3. Good colour contrast
35
Q

Summarise disadvantages of gypsum

A
  1. Low tensile strength
  2. Poor abrasion resistance
  3. Very brittle
  4. Surface detail less than elastomer impression (20micron groove)
  5. Poor “wetting” of some impression materials