Gypsum Flashcards
Purpose of study casts (3)
- Records the position + shape of teeth
- Aids assessment of dentition
- Enables manufacture of dental prosthesis
List uses of gypsum (4)
- Cast (plaster/stone)
- Die (stone)
- Mould material
- Investment binder
List different types of gypsum (3)
- Plaster (B-hemihydrate)
- Dental stone (a-hemihydrate)
- Densite
Function of the gypsum crystalline structure
It determines properties
How is plaster (b-hemihydrate) heated and describe the particles (2)
- Heated in open vessel
2. Large porous irregular crystals
How is dental stone (a-hemihydrate) heated and describe the particles (2)
- Heated in an autoclave in the presence of Ca and Mg chloride
- Non-porous smooth crystals
How does improved stone particles look?
Compact smooth particles
Heating Calcium Sulphate Dihydrate leads to the production of what 3 things?
- Plaster
- Stone
- Improved stone
Mixing ratio for plaster
WATER: 50-60ml
POWDER: 100g
Mixing ratio for stone
WATER: 20-35ml
POWDER: 100g
Theoretical ratio
WATER: 18.6ml
POWDER: 100g
How is dihydrate formed?
Hemihydrate dissolves
Dihydrate forms
Dihydrate solubility
Solubility low - supersaturated solution
Setting process of gypsum (3)
- Dihydrate crystals precipitate on impurities as crystals
- More hemihydrate dissolved
- Continues until all hemihydrate dissolved
Describe the initial set process
- Dihydrate crystals come into contact (push apart)
- Expansion starts
- As the set is fairly weak solid at this stage, it will not flow
- Can be carved as its easy to manipulate
List gypsum advantages (3)
- Dimensionally accurate and stable
- Low expansion (<0.1%) of stone/densite
- Good colour contrast
List gypsum disadvantages (4)
- Low tensile strength + very brittle
- Poor abrasion resistance
- Surface detail less than elastomer impression
- Poor wetting of some impression materials
What is used to measure initial and final setting times
Gilmore needles
What happens to excess water during setting?
- Excess water is trapped in the powder mass
- Excess water now has the opportunity to evaporate or else bubbles are formed and will become porous (making the material v weak)
What happens on completion of setting?
- Excess water evaporates
2. Voids are produced (porosity)
Typical compressive strength of gypsum
Compressive (~20~35MPa)
hardness - low
Compare gypsum strength to composite
1/10th of composite strength
But roughly the same bonding strength
State the typical expansion value of plaster?
0.2-0.3%
State the typical expansion value of stone?
0.08-0.1%
State the typical expansion value of densite?
0.05-0.07%
Why is improved stone stronger?
Requires less water for a workable mix (less porous)
List the effects of increasing:
- Powder
- Spatulation
- Impurities
On the setting time of gypsum products
Decrease setting time
List the effects of increasing
- Powder
- Spatulation
- Impurities
On the expansion of gypsum products
Increase expansion rate
How does spatulation lead to:
Decreased setting time
Increased expansion
- Increased spatulation breaks down growing crystals
- Fragments act as nuclei of crystallisation
- More growing crystals come into contact sooner
Effect of increasing powder on the powder/water ratio (3)
- More nuclei of crystallisation per unit volume
- Crystals come into contact sooner
- Faster set and greater expansion
Why should expansion only be a small %? (2)
- Small % otherwise its problematic
- Allows for model to be a little big so it means crowns, bridges and dentures won’t be too tight a fit when placed in the mouth
How does temperature affect the rate of diffusions of ions?
Rate of diffusions of ions increases with increased temperature
What chemical additives can be added? (2)
- Potassium sulphate
2. Borax
Function of Potassium sulphate (3)
- Produces syngenite
- Crystallises rapidly encourages growth of more crystals
- Decreases setting time
Function of borax (2)
- Deposits on dihydrate crystals
- Delays setting process (increases setting time)
Name a disadvantage of gypsum
Porous - so creates a rough surface about 28 to 40um (but good enough for most applications)