Gypsum Flashcards
what is a die?
removable section of a model
ISO Standard for Dental Gypsum Products
Type 1
impression plaster
ISO Standard for Dental Gypsum Products
Type 2
dental plaster for models
ISO Standard for Dental Gypsum Products
Type 3
dental stone for die/models
ISO Standard for Dental Gypsum Products
Type 4
dental stone, die high strength, low expansion
ISO Standard for Dental Gypsum Products
Type 5
dental stone, die high strength, high expansion
gypsum products for models and dies 3
dental plaster
dental stone
densite
what colour is dental plaster?
white
colour of dental stone
yellow
colour of densite
blue/pink
chemical equation for the manufacture of gypsum product
Calcium sulphate dihydrate -> calcium sulphate hemihydrate + water
how to convert gypsum to dental plaster
Heat gypsum at 120*c
how to convert gypsum to dental stone
Apply steam pressure in an autoclave to 125*c
how to convert gypsum to densite
Boil in CaCl2
porosity decreases from which gypsum product
plaster -> stone -> densite
particle size increases from which gypsum product
density -> stone -> plaster
more water is needed to mix plaster in reality than theoretically because?
lots of air is present in the material increasing porosity
air in the plaster mixture leads to 2
loss of detail
weakness
air is expelled from plaster by 2
vibrating it
mechanically mixing under a vacuum
what are the 3 stages of the setting reaction?
water becomes saturated with hemihydrate
hemihydrate converted to dihydrate form
dihydrate crystallises out, initiated by exposure to nuclei of crystalisation
2 forms of nuclei crystallisation
impurities
stray dihydrate crystal in the mix
what is used to determine the initial and intermediate set point of a material
Gilmore needles
setting is endothermic or exothermic?
exothermic - gives off heat
how can the manufacturer decrease setting time? 2
increase concentration of nucleating agents
accelerators e.g. K2SO4 (increase solubility of hemihydrate)
how can the manufacturer increase the setting time 1
retarder e.g. borax
how can the operator decrease the setting time 1
increase mixing time - breaks up dihydrate crystals so more crystallisation nuclei
how can the operator increase the setting time 2
increase water:powder ratio - decreases concentration of crystallisation nuclei
borax retards the mix
what effect does temperature have on setting time
little affect as increasing water temperature accelerates solution process but retards crystallisation
Is dental plaster or stone the strongest and why?
stone as lower porosity
the strength of set material increases with time due to
progressive evaporation of water
advantages of gypsum products 2
inexpensive
easy to use
disadvantages of gypsum products 2
May interact with borax in alginate (Rare)
Hypochlorite may interact if not rinsed off impression before casting (Rare)