Guest Lecture Flashcards
Flotation Factors:
machine (used for process, ex. agitators), physics (of the solid-liquid interactions), circuits (pathway to separate), chemistry (of compounds)
Together make up whole system
Chemistry of flotation
hydrophobic vs hydrophilic (want hydrophobic)
- if necessary will change surface chemistry to make hydrophobic
- to change surface chemistry, will use a compound with a reactant end and a hydrophobic end
Physics of flotation
need interaction with the bubble for the solid to attach to bubble
- to increase interactions, will change size, number, and coallesion of bubbles (can do this by adding a frother)
- need small particles and larger bubbles (roughly 10-300 microns of particles)
Flotation steps
- collision (bubble and particles collide)
- attachment (particle attaches to bubble)
- detachment (particles release from bubbles)
Flotation collison
- larger particles have less deviation from path due to low affect of water movement - increases collision probability
How to improve flotation recovery?
- increase gas rate (increase number of bubble)
- decrease bubble size (with agitator)
Flotation attachment
-particle slides along bubble for certain length of time
- if sliding time > attachment time then particle attaches
- Tsliding = Length of bubble sliding over/velocity of particle)
Flotation examples
- Mining (iron flotation, rare earth flotation)
- Li-Ion battery recycling (recovery graphite instead of using leaching)