Group 7 Flashcards
Reducing ability of the Halides
Down the group reducing ability increases as outer electrons are lost more easily
Acid base- react with H2SO4 to form misty fumes
Redox- Br forms SO2 and Br2
I forms SO2, I2, S and H2S
Chlorine
Chlorine water
Cl2+ H2O <-> HCl + HClO
This is a disproportion reaction as Cl2 is both oxidised and reduced.
turns indicator red then white
In sun
2Cl2 + 2H2O -> 4HCl + O2
Can be used to sterilise water
Identification using silver nitrate the ammonia
AgNO3+NaX-> AgX +NaNO3
then ammonia
AgF AgCl are soluble in dilute ammonia
Agbr is soluble in concentrated ammonia
AgI isn’t soluble at all
Oxidising ability of the halogens
Ability to act as an oxidising agent decreases because
atomic radius increases
shielding increases
so gains electrons less easily