Group 2 Flashcards
General reaction formula between group 2 metal and oxygen
(M= metal)
2M(s) + O2(g) -> 2MO(s)
General reaction formula between Sr/Ba and oxygen to form metal PEROXIDE
(M= metal)
M(s) + O2 -> MO2(s)
General reaction formula between group 2 metal and water, as well as the exceptions for solubility (aq)
(M= metal)
M(s) + 2H2O(l) -> M(OH)2 (s) + H2(g)
Sr and Ba hydroxides are aqueous
2 different reactions for Mg + H2O
Mg(s) + 2H2O(l) -> Mg(OH)2 (s) + H2(g)
and
Mg(s) + H2O -> MgO(s) + H2(g)
General reaction formula between group 2 metal and dilute HCl
(M= metal)
M(s) + 2HCl(aq) -> MCl2(aq) + H2(g)
General reaction formula between group 2 metal and dilute H2SO4, as well as the exceptions to solubility (aq)
(M= metal)
M(s) + H2SO4(aq) -> MSO4 (s) + H2(g)
Mg sulfate is sparingly soluble (aq)
pH trend of group 2 OXIDES
Oxides are more basic down the group.
* More soluble and dissociates in water
MO(s) + H2O(l) -> M2+ + 2OH-
General reaction formula between group 2 OXIDE and water
(M= metal)
MO(s) + H2O(l) -> M(OH)2 (s)
General reaction formula between group 2 OXIDE and dilute HCl
(M= metal)
MO(s) +2HCl(aq) -> MCl2(aq) + H2O(l)
General reaction formula between group 2 OXIDE and dilute H2SO4
(M= metal)
MO(s) + H2SO4(aq) -> MSO4(s) + H2O(l)
- Mg sulfate is sparingly soluble
Solubility trend of group 2 SULFATES
Decrease in solubility down the group
Which group 2 CARBONATE is soluble?
BeCO3
General reaction formula between group 2 CARBONATE and dilute HCl
(M= metal)
MCO3(s) + 2HCl(aq) -> MCl2(aq) + H2O(l) + CO2(g)
General reaction formula between group 2 CARBONATE and dilute H2SO4
(M= metal)
MCO3(s) + H2SO4(aq) -> MSO4(s) + H2O(l) + CO2(g)
- Mg sulfate is sparingly soluble
General reaction formula of group 2 CARBONATE thermal decomposition
(M= metal)
MCO3(s) + O2(g) -> MO(s) + CO2(g)
General reaction formula of group 2 NITRATE thermal decomposition
(M= metal)
2 M(NO3)2 (s) -> 2MO(s) + 4NO2 (g) + O2 (g)
Thermal stability trend of CO3 and NO3, with reasoning.
Down the group, CO3 and NO3 thermal stability increases.
Down the group, cations get bigger and less polarising of the anion. More polarisation causes the bond to become more covalent (sharing electrons) than ionic, lowering the bond strength.
Nature of group 2 ions
Reducing agents (donates 2 outer electrons) and are oxidised (+2)
Reactivity trend of group 2 metals, with reasoning.
Reactivity increases down the group.
Nuclear charge increases, but valence electrons are added to higher principle quantum shells, increases shielding. Down the group, easier to lose electrons and more vigorous reactions.
Ionisation energy trend of group 2 metals, with reasoning.
IE decreases down the group.
Nuclear charge increases, but valence electrons are added to higher principle quantum shells, increases shielding. Down the group, easier to lose electrons so less energy needed.
Atomic radius trend of group 2 metals, with reasoning.
Atomic radius increases down the group due to increase in quantum principle shells.
Melting point trend of group 2 metals, with reasoning.
Melting point decreases down the group due to increasing atomic radius, causing further distance between nucleus and electrons, weakening attraction.
Density trend of group 2 metals.
Density increases down the group.