Group 1 and 2 Flashcards
What are group 2 metals also known as?
Alkali earth metals
What do group 2 metals act as?
reducing agents as they give 2 electrons
Do the metals in group 2 get more reactive going down the group?
Yes
What is the trend in ionisation energies down the group for group 1 and 2?
They decrease so becomes easier to remove the 2 outer electrons
What is the general equation of group 2 metals with oxygen?
2M +O2 = 2MO
What do Sr and Ba also form when reacted with oxygen?
Peroxides - MO2
What is the general equation for all group 2 metals with water?
M + 2H2O = M(OH)2 + H2
Which group 2 metal does not react with water?
Be
Which group 2 metal reacts extremely slowly with cold water?
Mg
What kind of solution is formed when Mg reacts with water and why?
It is weakly alkaline (pH 9) as magnesium hydroxide is only slightly soluble
What happens when Mg is heated with steam?
It reacts vigorously to make MgO and H2
Mg + H2O = MgO + H2
What happens when group 2 metals react with chlorine gas?
They form a metal chloride
What are all group 2 oxides?
Basic - except for BeO which is amphoteric (can act as both an acid and a base)
What is formed when group 2 oxides react with water?
Alkaline solutions
What is observed when MgO reacts with water?
MgO is only slightly soluble in water, so weakly alkaline solution (pH 10) formed
What is observed when CaO reacts with water?
Vigorous reaction which releases a lot of energy, causing some water to boil off as solid lump seems to expand and open (pH 11)
What is the general equation for group 2 oxides and water?
Oxide + water = hydroxide
What is calcium hydroxide known as when in solution?
Limewater
What is formed when a group 2 oxide react with sulphuric acid?
Group 2 sulphate
What happens when group 2 oxides react with sulphuric acid in terms of the actual reaction?
The insoluble sulphate forms at the surface of the oxide, so the solid oxide beneath it can’t react with acid
How can this (The insoluble sulphate forms at the surface of the oxide, so the solid oxide beneath it can’t react with acid) be prevented?
By using the oxide in powder form and stirring in which case neutralisation can’t take place
What is the general equation for group 2 oxides and HCl?
Oxide + dilute HCl = chloride + water
What is the general equation for group 2 oxides and H2SO4?
Oxide + dilute H2SO4 = sulfate + water
What do group 2 metal hydroxides form when reacted with a dilute acid?
Colourless solutions of metal salts
How do the solubility of the sulphates change going down the group?
They decrease (barium sulphate is an insoluble white precipitate)
What is the general equation for group 2 hydroxides and HCl?
Hydroxide + dilute HCl = chloride + water
What is the general equation for group 2 hydroxides and H2SO4?
Hydroxide + dilute H2SO4 = sulphate + water
Going down the group, how does the alkalinity of the solutions formed from oxides with water change?
It becomes more alkaline