GR Flashcards

1
Q

Acid base rcn given by grignard reagent

A

OH, NH2, SH
ACETIC ANHYDRIDE
CH3—NO2 ( METHANE PR LAGE PROTON KI ACIDIC STRENGTH PHEONLIC PROTON KE BBARABAR HOTI HAI
Such type of rxn k/as ziritnoff rxn

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2
Q

Transmetallation rxn given by grignard reagent

A

R’MgX + RCuli = R’Culi +RMgX

Exchange of ch3-

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3
Q

Ester +GR=
Amide+GR=

A

Alcohol
Ketone

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4
Q

RMgX give 1,2 or 1,4 addition in alpha beta unsaturated carbonyl compound

A

1,2

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5
Q

Carboxylic acid +RMgX

A

RH

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6
Q

Imagine the structure of Et2SO4

A

≈ Et –OTs
Electrophile is Et

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7
Q

GR follow which mechanism SN1 OR SN2

A

SN2

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8
Q

Large group syn to carbonylgroup attack from

A

Medium side

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9
Q

Large group anti to carbonyl attack from

A

Small side group

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10
Q

GR act as a base or nucleophile

A

So at same time it act as both

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11
Q

Kukinkouich rxn me kya Hota hai

A

Ester + grignard(at least 2 carbon)/ alkene = cyclopropane

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12
Q

Kylin rxn ko pahchane kaise

A

GR reagent ke sath Titanium diya hoga

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13
Q

Kylin rxn me jab substrate me dono reagents given ho to

A

Ester alkene se he react karega

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14
Q

Intermediate formed during kylin kobich rxn

A

3 ,5 membered ring formed

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