Gibbs energy and equilibrium Flashcards
the equilibrium constant and the Gibbs energy change are related in the equation:
ΔG = RTlnK
where R is the gas constant (8.31 J mol-1 K-1)
ΔG = RTlnK can be rearranged to giver K as:
K = e to the power of ( - ΔG/RT)
e is a mathematical constant equal to 2.718. The natural logarithim is ln to the base e
in K = e to the power of ( - ΔG/RT), if ΔG is negative, then the exponent (the expression in the brackets) is positive and the equilibrium constant will be greater than 1 which means the products are
favoured
in K = e to the power of ( - ΔG/RT), if ΔG is negative, then the exponent (the expression in the brackets) is positive and the equilibrium constant will be
will be greater than 1 which means the products are favoured