Getting the most from reactants Flashcards

1
Q

What does the UK chemical industry make a major contribution to?

A

the quality of life in the country

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2
Q

Give 4 examples of products which are made on a huge scale on a daily basis?

A

medicines
plastics
paints
cosmetics

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3
Q

What are industrial processes designed to do?

A

maximise profit and minimise the impact on the environment

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4
Q

Give 5 examples of factors influencing process design ?

A
availability, sustainability and cost of feedstock(s)
opportunities for recycling
energy requirements
marketability of by-products
product yield
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5
Q

Give 3 examples of environmental considerations?

A

minimising waste
avoiding the use or production of toxic substances
designing products which will biodegrade if appropriate

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6
Q

What is the research and development stage?

A

initial stage of planning

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7
Q

What is the laboratory process stage?

A

Initial trial using small quantities

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8
Q

What is the pilot study stage?

A

Trial using larger quantities in a bigger reactor to understand engineering aspects of the process.

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9
Q

What is the production stage?

A

Production is carried out in a factory/plant on a huge scale, producing tonnes of products

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10
Q

What is the process and review stage?

A

The process is reviewed and optimised to have the best conditions and best yield. A marketing team will sell the product.

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11
Q

What is a feedstock?

A

a reactant from which other chemicals can be extracted or synthesised.

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12
Q

What are feedstocks derived from?

A

raw materials

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13
Q

What are raw materials?

A

substances that can be used directly in their original form without being treated.

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14
Q

What are the 5 main raw materials used in the chemical industry?

A
fossil fuels
metallic ores and minerals
air 
water
organic materials such as oil and starch
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15
Q

What would make feedstock profit making?

A

local feedstock
feedstock that is in abundance
low cost of feedstock

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16
Q

When would feedstock cause a profit loss?

A

feedstock has to be transported for far away
feedstock may become scarce
feedstock is too expensive.

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17
Q

When would opportunities for recycling cause a profit to be made?

A

if unreacted materials can be fed back into the process this will improve efficiency and profitability.

18
Q

When would opportunities for recycling cause a profit to be loss?

A

if it is difficult to separate materials at the end of the reaction, this makes it inefficient and wasteful.

19
Q

When would energy requirements cause a profit to be made?

A

exothermic reactions can be used to sustain the heat in a reaction.
catalysts can lower the energy required for the reaction

20
Q

When would energy requirement cause a profit to be lost?

A

reactions which require a lot of heating and cooling require energy.

21
Q

When would marketability of by-products cause a profit to be made?

A

some by-product can be sold for use in other areas of the chemical industry.

22
Q

When would marketability of by-products cause a profit to be loss?

A

if by-products are toxic or corrosive they will be expensive to deal with and may harm the environment.

23
Q

When would product yield cause a profit to be made?

A

high yields are very profitable

24
Q

When would product yield cause a profit to be loss?

A

low yields cost time and money

25
Q

What is also important to consider in an industrial process?

A

thedesign of the chemical plant to ensure it has good infrastructure,i.e. good transport links (road and sea for export and import of materials) and safety precautions

26
Q

What can a flow diagram be used for?

A

by engineers and industrial chemists when designing a process. It allows them to consider important aspects of the whole chemical process.

27
Q

In most chemical reactions what happens to one reactant ?

A

Gets used up before the other

28
Q

What happens to the reaction of one reactant is used up?

A

It stops

29
Q

What is the reactant left over said to be?

A

In excess

30
Q

What is the reactant not in excess called?

A

Limiting reactant

31
Q

What does the limiting reactant determine ?

A

The quantity of product made

32
Q

What is the molar volume of a gas?

A

The volume occupied by 1 mole of a gas at a stated room temperature and pressure

33
Q

What is the approximate molar volume of gas at room temperature (20•c) and 1 atmospheres pressure?

A

22.4 litres

34
Q

What is the same for all gases?

A

22.4 litres at room temperature and 1 atmospheres pressure

35
Q

Many reactions do not go to completion. What does this mean?

A

The quantity of product obtained from the reaction (actual yield) is less than the calculated (theoretical yield)

36
Q

Why would there be a lower actual yield than theoretical yield?

A

May be due to products being lost or the reaction being reversible

37
Q

What is the equation for percentage yield?

A

Actual yield / theoretical yield x100

38
Q

What is the equation to find the actual yield?

A

Theoretical yield x %yield/ 100

39
Q

What does atom economy measure?

A

The proportion of the total mass of all starting materials converted into the desired products

40
Q

If by-products were produced what would the atom economy most likely be and why?

A

Low as there will not be a high proportion of the desired products

41
Q

What is the equation for atom economy?

A

Mass of desired product(s)/ total mass of reactant(s) x100