GEOG319 Flashcards
What drives system change in process geomorphology?
Precipitation, temperature, and climate. With enough consistency, this creates environmental factors that drive system change (eg, low temps = high snow = glacial erosion).
What are the 3 types of Equilibrium?
Static
Steady-State
Dynamic
Static Equilibrium
Remain unchanged over time due to perfectly balanced forces, typically maintained by consistent environmental conditions. Time independent (days/months)
Steady-state Equilibrium
Inputs and outputs, long-term, = 0
Offers potential to model long-term responses to changes in input parameters.
Dynamic Equilibrium
Undergo continuous change, but the rates of change are relatively constant, resulting in overall stability or balance over time. Cyclic (millions of yrs)
Recovery Time
Time to return to natural state from perturbation
Reoccurrence Interval
Determines if steady-state is maintained
True or False, landform adjustment to perturbance is magnitude dependent.
True. The size of perturbation = the magnitude of the event. Thus, is magnitude dependent.
Driving Forces
Endogenic (inside Earth)
- Internal heat from radiation, drives tectonics.
Exogenic (from atmosphere, sun)
- Climate, solar radiation, gravity
Resisting Forces
- Lithology
- Friction, viscosity
- Trees, rock pins
- Friction, viscosity
Complexities
- Thresholds
Climate, rock weakness, system returns to new condition/equilibrium state if pushed too far.- Complex response
Response in other parts of the system, which are linked (like the butterfly effect).
Process linkage, can get multiple landforms from one perturbation.
- Complex response
What Can Be Conserved?
Heat, Momentum, Mass
Conservation of Heat (Thermal Diffusion) - 3 Types
Plutons, Ground Water, Atmosphere
Conservation of Heat (Thermal Diffusion) - Plutons
Heat increase through radioactive decay, heat loss to country-rock and crystallisation.
Conservation of Heat (Thermal Diffusion) - Groundwater
Heat gain from geothermal sources, heat loss to cooler rock, water, atmosphere.
Conservation of Heat (Thermal Diffusion) - Atmosphere
Heat gain from Earth and Sun, heat loss to space.
Conservation of Momentum (5)
Wind, Rivers, Ice, Mass Wasting, Flow (rate depends on viscosity).
Conservation of Mass (Elevation)
Change in elevation = uplift - denudation: dz/dt = U - E
U = thermal, tectonic, isostatic buoyancy
E = tectonic, chemical, physical
Basic Conservation Equation Structure
dx/dt = in - out
Geomorphic Transport Functions
Describe the physics of each part of the conservation statement.
Eg: How does ice flow, heat diffuse, rock turn to soil? –> into equation
Geomorphic Transport Function Example: Rivers
E ~ KA^(m)S^(n)
Erosion ~ K x A (upstream area)m x gradientn
Steady-state and GTF
inputs and outputs are equal, because our average value doesn’t change through time. This means dz/dt = 0, and we can make uplift assumptions.
Soil Conservation Equation
dH/dt = SPR - D
Moving Mobile Regolith
Change in thickness = gains - losses.
More soil into one part of slope, soil thickens through time and dR/dt is +
Less soil into one part of slope, soil thins through time and dR/dt is -
Conservation of Water
dh/dt = (R - I) - dQx/dx
Assume steady state and integrate: Qx = (R - I)x
There are gains (Rain, R) and losses (infiltration I) and water discharge on slope (Qx)
Hydrolysis
Addition of hydrogen proton (H+, cation), where that then combines with water and the mineral. The result is the mineral begins to be stripped of big cations (like potassium which is good for plant nutrients), breaking down the rock.
Cation Exchange
Substitution between ions in the mineral and ions in solution. Depletions of base cations in exchange for hydrogen protons (H+) leads to oxides. Cation: positively charged ion
Example of Hydrolysis/Cation Exchange
Plag –> kaolinite (clay)
alteration of silicates to clays
Oxidation
Electron exchange with oxygen, where electrons are negatively charged and losing one makes a mineral more + (occurs everywhere, including below surface!)
Example of Oxidation
Olivine –> Hematite. Iron, magnesium, and sulphide minerals!
Dissolution
Dissolvement of minerals (only happens when minerals are soluble, like calcite).
Example of Dissolution
Halite –> Na and Cl ions
Primary Mineral Stability
Same order as Bowen’s reaction series, where the order of crystallisation represents which forms first. Things like Olivine and Pyroxene weather faster at Earth’s surface as the conditions are low pressure, low temp - meaning, as they don’t form in those conditions, they’re less stable.
So, if you had a parent material rich in quartz = quartz to remain and increase in concentration while other minerals weather and precipitate away.
Dissolution Rates
Fastest for high-temp forming minerals, slowest for low-temp forming minerals.
They are measured on a log scale to represent the major difference in lifetime for such a small mineral.
-13.39 is a much smaller rate than -8.00, so you would expect quartz to have high dissolution rate.
Leeching (Dissolution Rate Controls)
If you are pulling minerals out, but the surface is not being eroded, you are leeching the minerals exposed at the surface - but making it extremely hard to oxidise as all the minerals are trapped in the centre.
pH (Dissolution Rate Controls)
Higher in acidic pH, moderate in alkaline, poor in neutral pH.
Acid has H+, and oxide has OH-, both of which stick to mineral surface and accelerate weathering. Neutral pH lacks both
Fixation/Retardation (Dissolution Rate Controls)
Can oxidise iron, which gets trapped and precipitate back out as platy minerals - slowing down further reactions.
Chelation (Dissolution Rate Controls)
Related to parent material and solution. Where large, organic compounds tend to envelop metal cations - being carried out of the system.
End Products of Dissolution
Solid: new, stable mineral (clay) or old, resistant mineral (quartz).
Dissolved: cations and anions. Can be contained in pore spaces, creating rough minerals.
Mobility
Ability of ions to move, usually through water.
With increasing charge, the element becomes more tightly bound and ions will become smaller.
Comparing ionic radius to charge, increased charge with small radius = high attraction, high mobility (can’t fit in crystal structures). Decreased charge and high radius = low attraction, low mobility (can’t fit in crystal structure).
Ionic Radius/Ionic Charge Ratios
z/r = 2: low charge, big. Stay in dissolved solution.
z/r = 4, z/r 6: special zone, too big to fit into structures, too charged to stick around in dissolved water. Highly immobile, staying in crust as solids.
z/r = 16: high charge, small radius. Instantly form compounds which stick around as dissolved species (…nates). High mobility because form compounds.
Mobile vs Immobile Elements
Calcium, magnesium, sodium, potassium, Iron2+= mobile
Silicon, Iron3+, aluminum = immobile.
Cation Types
Hard Cation = remove electron, complete outer shell (sodium, potassium, calcium), stable, tend to be highly soluble (nitrates, sulphides, etc).
Anions = chuck one electron on, full outer shell.
Intermediate Cation = sometimes take or give, end up with incomplete or complete shell depending on element they interact with.
What are weathering rated dependent on?
Kinetics and Thermodynamics
Kinetics vs Thermodynamics
Kinetics: dissolution rates of the phases (minerals - quartz slow, plag fast), temperature
Thermodynamics: chemical saturation state of the solution. Stable water = easily saturated, slow. Flowing water = not saturated, fast.
Chemical Saturation
Systems further from saturation react faster. Reaches equilibrium if the system is closed. Water flow will affect saturation (stable = slow, flow = fast).
Role of Time in Weathering
Rates change as weathering progresses.
Example: glacial retreat can cause high initial weathering rates, but rates decay rapidly (eg, due to leeching, chemical saturation).
Water and Weathering
Longer residence time = more intimal dissolution, but slower rates as steady-state and saturation is reached.
Soil Water Drainage
Slower groundwater seepage velocities result in more overall weathering.
- More time to dissolve rock - May be slower dissolution rate, but total mass is dissolved longer in the end.
How Does Silicate Weathering Affect Climate?
Carbon dioxide and water and feldspar –> Carbonic Acid (soluble) –> moves to oceans –> meets up with calcium and precipitates out as limestone.
So, the carbon dioxide in atmosphere correlates to major climate changes over geological time. Silicate weathering is a CO2 sink over geologic timescales.
Climate
Broadly controls the balance between chemical and physical weathering processes.
Dry, Cold: physical.
Hot, Wet: chemical. Keeps us away from saturation.
No weathering in wet and cold environments, does not exist.
Arrhenius Exponential Curve
Weathering rates are temperature and precipitation dependent.
Curve can predict silica weathering rates for the surface of an environment depending on temperature and precipitation
Weathering and Erosion
Weathering rates generally scale with erosion rates.
More fresh minerals = more weathering (supply limitation).
Tectonics also control weathering rates. Slow uplift = slow movement of material into weathering zone. So, if you uplift, more material in = more chemical weathering.
Why Do Active Tectonic Landscapes Erode Faster?
Minerals moving through this process slowly, from rock, spend a long time in system weathering. Minerals moving fast spend a much shorter time.
Little erosion = old surface rock = low chemical erosion, but more time
Increased erosion (tectonic) = fresh rock = more minerals for weathering, but less time
At a certain point, chemical weathering can only happen so fast. Thus, any increase in the rate of minerals movement decreases chemical weathering - creating a bell-curve.
Supply Limitation Chemical Weathering
Thick soils, few primary minerals
CDF same everywhere
Mafic
Non-tectonic
Kinetic Control Chemical Weathering
Thin soils (or none), residual primary minerals
CDF should be low, spatially variable, changes with depth.
Felsic, rocky.
Tectonic
The Effects of Vegetation on Weathering
Plants enhance weathering by:
- Producing organic acids
- Disrupting weathered material (tree-throw)
- Stabilize soils, increasing residence time (roots have high tensile strength)
Plants need elements in soil, break down rock to use them = faster weathering rates.
True of False, chemical weathering occurs faster in non-tectonic regions.
True, chemical weathering occurs faster in non-tectonic regions.
Active tectonics = less residence time = faster, but less chemical weathering
Limits on Weathering: Fast vs Slow
At fast erosion rates, weathering is limited by chemical processes, residence time of water in contact with minerals surfaces (kinetic limitation).
At slow erosion rates, weathering is supply-limited (not enough fresh material supply).
Supply-Limited vs Kinetic-Limited
Supply-limited areas: if the erosion rate is increased, total weathering will also increase (as the mineral still has enough time to break down). No primary minerals.
Kinetic-limited areas: if the erosion rate increases, total weathering will decrease (as the mineral does not have enough time). Primary minerals, rich felsic.
Regolith
all altered rock.
Weathered Rock
all rock, excluding soil
Saprolite
Highly weathered rock, chemically altered but maintains structures (joints, bedding, foliation).
Mobile regolith
broken down saprolite, soil.
True or False, everything before saprolite is non-isometric
False, everything before saprolite is isovolumetric (no change in volume)
What if you see all components of a soil profile?
that system has been operating for a long time (supply-limited).
What if components of the soil are missing?
System is operating for short time/interrupted, kinetically-limited.