general definitions Flashcards
What is a reversible reaction?
A reaction where the product can re-form into the reactants
What is Le Chatelier’s Principle?
When the system is stressed, the new equilibrium shifts to be less stressed
Define chemical equilibrium
the state where the concentrations of all reactants and products remain constant with time
All reactions carried out in a closed vessel ____ reach equilibrium
will
if little product is formed, where will equilibrium shift?
sometimes
far left
if little reactant remains, where will equilibrium shift?
sometimes
far right
At dynamic equilibrium, reactions ____ to take place
forward AND reverse reactions
continue
What happens to the rate of forward + reverse reactions once they reach dynamic equilibrium?
They occur at the same rate
What factors can effect equilibrium?
temperature, pressure and concentration
How to pure liquids/solids effect hetergenous equilibria?
They don’t, they are not accounted for in the calculation or expression
Pure liquids ____ the same as solutions, which can have a change in concentration
are not
what is the symbol for equilibrium?
<–>
Using A+B <–> C+D:
What would happen to C at equilibrium if we added more A?
Adding A increases the amount of C and D at equilibrium
Using A+B <–> C+D:
What would happen to A at equilibrium if we added more C?
Adding more C increases the amount of A and B at equilibrium