General Flashcards

(356 cards)

1
Q
A
How well did you know this?
1
Not at all
2
3
4
5
Perfectly
2
Q
A
How well did you know this?
1
Not at all
2
3
4
5
Perfectly
3
Q

2V angle.

A

This is the acute angle between the two OAs within biaxial minerals.

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
4
Q

4 symmetry elements

A

Inversion: This is where an element is shown on the equal but opposite face. It is reflection through the crystal center not a plane.

Reflection: This is the planar reflection of elements.

Rotation: This is a repeating motif that is rotated about an axis.

Rotoinversion: When there is a shift and inversion in a regular pattern.

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
5
Q

4 types of twinning

A

Contact twins: Rotational symmetry/mirror plane down a central axis. Both sides of the plane are the exact same but this symmetry does not normally occur in the mineral.

Interpenetrant: two or more crystals growing near each other and impending on the others growth. It is defined by a twin axis.

Polysynthetic: twins growing parallel to one another in a repeating set. Plagioclase.

Cyclical: repeated twinning of 3 or more crystals with a non-parallel twin axis. It is like polysynthetic but instead of mirrors the crystals are rotated about a central axis.

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
6
Q

Acute Bisetrix Figure (BXA)

A

This is when the two isogyres form arcs or uneven arcs. The distance between the isogyres is proportional to the 2V between the OAs by the degree of seperation where 50o is just at the edge of view.

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
7
Q

Acute Bisetrix Figure (BXA)

A

Starting at 45 degrees off of extinction at the far left and then rotating 45 degrees.

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
8
Q

allochromatic

A

This is when transition metals occur as trace elements to color a gem. This means that the coloring agent is an impurity and it is “other colored”

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
9
Q

almadine spectra

A

The high and low ends fade out and there is a significant chunk of yellow missing.

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
10
Q

Amorphous expected results from the refractometer

A

It should be singly refractive and have a single, fixed shadow edge.

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
11
Q

Amorphous

A

These are non-crystalline solids that do not have regularity in their mineral composition.

Metamict minerals are minerals that lose their crystallization due to radiation.

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
12
Q

Anisotropic Minerals

A

Minerals that have vector dependent physical properties. Particularily concerning a change in the speed of light based on the light direction.

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
13
Q

Anomalous Double Refraction

A

This is when a gem that is otherwise isotropic experiences strain to create zones, patches, or lines of anisotropism.

Be sure to rotate the gem to ensure that it is not the result of coloring or faceting. Focus on one spot and rotate the gem several times to ensure that it is anomalous extinction.

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
14
Q

Anomalous Double Refraction

A

This is when a crystal is strained so only parts go extinct in the polariscope, NOT the full crystal.

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
15
Q

Artificial Materials

A

These are materials that have been exclusively manufactured. They are not natural

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
16
Q

Asterism examples

A

Corundum, almandine, quartz, diopside

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
17
Q

BARS

A

This stands for a bunch of very long Russian names. It is very similar to the belt but it uses cyclindric anvils and an octohedral cell to form the diamond.

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
18
Q

Biaxial Interference Figures

A
How well did you know this?
1
Not at all
2
3
4
5
Perfectly
19
Q

Biaxial/Uniaxial Positive vs. Negative

A

This is a term referring to whether the OAs are closer to the minimum refractive plane or the maximum. Positive minerals have OA closer to the maximum.

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
20
Q

Biaxial systems and materials

A

These are characterized by 3 refractive indices (two varying RI’s) and 2 OA’s. The middle “n” can then be further used to designate positive or negative which is related to the crystallographic axes.

The ‘ic’ systems:

Orthorhombic, monoclinic, triclinic

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
21
Q

Uniaxial Indicatrix

A

This is the spheroid that is derived for the uniaxial e and o ray. Because uniaxial minerals do NOT have a mid-axis there is variation between the maximum refractive index (epsilon) and the minimum (little omega).

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
22
Q

Bleaching

A

This is the use of chemicals or other agents to lighten or remove the color of a gemstone. Common stones that are bleached include pearl (kills bacteria), coral, jadeite, tiger’s eye, other quartz.

It needs to be treated with caution because it can lower the durability of a stone.

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
23
Q

Bonding types of:

Halides, Oxides, Silicates, Sulfides, and sulfosalts

A

Halides: Primarily ionic

Oxides: ~75% ionic (corondum)

Silicates: Range from ~50% to ~25% ionic based on network

Sulfides: ~65% covalent and becomes more metallic with increased electron shells

Sulfosalts: ~40% metallic (stibnite)

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
24
Q

Braveno Law

A

This is a polysynthetic twin along the {021} plane in orthoclase. This means that it is parallel to the a axis b intersects b:c at a 2:1 ratio (it is diagonal). It is common in orthoclase.

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
25
Carbonate Gems
[M+](CO3)x These are very soft and non-resilient
26
Carlsbad Law
This is a penetration twin that shows 180o rotation about the [001] axis. It is characteristic of orthoclase.
27
Diamond Testing: Cathodoluminescence
Cathodeluminescence is using a beam of electrons to create excitation within an atom. It is used in diamond to identify the growth patterns
28
Cause of Chatoyancy/Asterism
These are reflections perpendicular to long acicular needles within stones that are oriented parallel to one another. It is only obvious when cut as a cabachon. It can only be seen when the light is perpendicular to the stone.
29
Centipede inclusions
This occurs in moonstone and it looks like elongated snowflakes.
30
Ceramics imitation
These are used to produce "synthetic" turquoise, lapis lazuli, and coral using a sintering process to solidify a powdered material.
31
Character of oxide gems
Fundamentally [M+]Ox High hardness and resistance to injury/chemical attack
32
Characteristic Spectroscope Results
Emission lines: Ruby has a red emission line and green is missing Sharp lines: REE's Fe: cut off of red, missing yellow
33
Chatoyant Stones
Chrysoberyl, quartz, tourmaline, glass with optical fibers
34
Choice of Cut Factors (8)
Yield: maximized Transparency: Transparent stones are faceted, translucent and opaque stones are cut as cabochons, beds, carvings, or inlay Fire and Brilliance: Facets maximize the best dispersion Inclusions: Some cuts highlight inclusions other hide. Optical Effects: Usually with cabochons (chatoyancy) Color: Maximize attractiveness and utilize pleochroic properties (tourmaline) Physical constraints: Cleavage, anisotropic hardness, durability
35
Chromium Coloring examples and effects
Ruby: red, emerald: green, green jadeite jade: bright green, alexandrite: red/green, red spinel
36
Cleavage
This is defined as the plane of weakest atomic bonding. It is a sub-set of fracturing and is dependent of the crystal system and structure. It is very important for cutting and faceting gems.
37
Cleavage examples
none: obsidian, quartz (fracture) 2 directions: orthoclase, amphibole 3: galena (90o), calcite (105, 75) 4: Fluorite
38
Coating
This is the application of a colored layer to change or improve the colour of the gem. This commonly includes quartz, topaz, cubic zirconia, and diamonds.
39
Coating ID
They durability of various coatings is variable and on older stones they may begin to curl or flake particularly along facet edges. Looking at the back of the stone can show the film's iridescence and the spectrum is likely influenced of the coating and not of the stone. It will be abnormal.
40
Color change stones
This occurs in corundum, spinel, garnet, fluorite, and zircon. Of note is alexandrite that rarely shows color change and is very desirable. Color change is the optical phenomena where stones change color based on the light source. Most commonly this is either incandescent (tungsten bulbs) and sunlight
41
Color in gemstones is a function of...
The source of white light, modifications to said light, and the eye/brain's interpretation of the light.
42
Color Zoning
This includes structural related coloration of stones due to different trace or transition elements.
43
Common forms of Corundum?
Corundum is trigonal and will have triangles on the upper face if tabular or will be bipyramidal or barrel shaped. All forms have a tendency to have striations on the sides and hexagonal color zoning.
44
Common nomenclature changes (Spessartine, zoisite, beryl, Corundum, Cordierite)
mineral = gem Spessartine = spessartite zoisite = tanzanite beryl = emerald Corundum = Sapphire/Ruby Cordierite = Iolite
45
Common Volcanic Rock Textures
Vesicular Textures: There are "bubble formations" due to off-gassing of relatively low-gas lava Pyroclastic: These include the explosive debris of volcanic eruptions.
46
Composite gem Materials
These are materials that composed of two (doublets) or three (triplets) stones/pieces. They are generally plates of material acting as backing or on the surface providing a false front.
47
Composite Materials
These are artificially assembled from two or more natural or artificial components meant to replicate a single gem material.
48
Conoscope
This is a glass ball that is used to find interference figures, which occur along the c axis of the stone, from a material in the polariscope. Used to identify if the anisotropic/doubly refractive stone is uniaxial or biaxial.
49
Conoscope Use
When rotating the stone in polarized light look for interference colors (iridescence). When noted touch the conoscope to that part of the stone and look to see if the stone is uniaxial or biaxial.
50
Coordination Number
The total number of atoms surrounding a central cation in a molecule
51
Coral Types
Red Coral: Classic Mediterranean coral that is very pricey Black Coral: Hawaiian coral. It always has bumps/dots. Also pricey. Caribbean black coral is a psuedo-simulant that is worth about 100x less. Golden Corals: These are deepwater corals often dyed
52
Corundum Diffusion
Heating pink sapphires in the presence of beryllium shifts their color to orange. Similar processes with various other small radii elements fill vacancies and create other colors. This can leave a rind of low diffusion/high conentration.
53
Criterion for judging a faceted stone
Look at the symmetry, proportions, and polish
54
Critical angle for total internal reflection
This is ic and it represents when the refracted ray is at the interface of the two materials so r=90o it occurs at sin-1(nr/ni) where n is the refractive index
55
Crown angle
This is the angle between horizontal and the area below the girdle, it determines dispersion. If it is over 42o then you can see straight through the diamond (lack of dispersion) and if it is less than 42o then the girdle is refelcted to create a "fish eye"
56
Crystal Aggregation Habits and examples (7 kinds)
Granular: Like marble or granite Lamellar/foliated/micaceous: mica colloform/stalactitic: cave deposits geode oolitic: iron ore radiating: wavellite
57
Crystal Habit and 14 Types
This is how minerals display crystal faces dependent upon their growth environment. It is described by the general shape of the crystal. Types: Acicular: slender needles Bipyramidal Botryoidal or globular: Hemispherical masses Columnar or Fibrous: series of slender prisms Dendritic Dodecahedral Euhedral Mamillary: rounded intersecting contours Massive: lacks crystal shape Octohedral Prismatic: Collumnar, there is a substantial thickness to the collumns scalenohedron: A six-sided pyramid with unequal sides Striations: Growth lines of the crystal face. Tabular: short stubby crystals
58
Crystal Pulling
This is a method used to produce laser grade corundum, chrysoberyl, YAG (yitrium aluminum garnet), and GGG. The idea is that there is a tub of melted solution and a seed crystal is placed at the surface where it nucleates a crystal. This is very slowly pulled upwards to form a boule.
59
Crystallization from a melt
This is the concept of having molten materials that are slowly cooled to form a crystal. This includes the Verneuil flame-fusion, zone melting, crystal pulling, and skull melting processes.
60
Crystallization from a solution.
This involves having either a flux or hydrothermal solution that enables the reactents to be dissolved. This is then perturbed into instability (primarily by lowering P/T) to promote crystallization.
61
Cubic Zirconia vs. Zircon UV reaction
SWUV: zirconia is yellow to dull orange. zircon is inert LWUV: same, slightly weaker. Zircon is brown-yellow
62
Cubic/Isometric system and gem examples
a=b=c and meet at 90o Displays the highest degree of symmetry (three four fold rotational, four three fold, 4 mirror planes) Gems: Diamond, fluorite, garnet, spinel, pyrite
63
Cutters
These are workers who transform a rough stone into the mold for a gem.
64
CVD synthetic diamonds
Chemical vapour deposition growth practically forms polysynthetic diamonds by punping inert gases and diamonds gas into a chamber
65
Desirability
Customer must want the stone for some reason. Commonly this includes Want to be appreciated by others (gifts) Fashions/seasons Social customs: birthstones, royalty/celebrity Myths and Legends: Metaphysics Ethical considerations
66
Anisotropic hardness
All crystals can show directional hardness although it is less obvious among some species, kyanite is one of the most obvious. Note: Diamonds's anisotropy is why it is able to be polished.
67
Diamond Fluorescence
SWUV: generally weak LWUV: variable, oftentimes blue
68
Diamond grading
There are independent scales for color and clarity that are **subjectively** graded.
69
Diamond Manufacture
This is the process of fashioning and polishing a diamond
70
Diamond ore mineral processing
Ore is usually put into a SAG mill and can be sorted using x-ray fluorescence or because they are non-polar they stick to a grease covered belt.
71
Diamond Types
Generally diamond types are a function of impurities and vacancies that give them semi-diagnostic properties. type 1 diamonds deal with nitrogen type 2 diamonds do not have nitrogen
72
Diamond View (De Beers unit)
This uses UV fluorescence to identify diamond types
73
Diamonds: Black
These are either the result of numerous inclusions (Carbon), treatment, or extremely high concentrations of nitrogen.
74
Diamonds: Brown
This is due to the plastic deformation of diamonds that causes a unit step shift and unalignment of the atoms. It occurs in high shear enviroments.
75
Diamonds: Green
This is from radiation defects creating lattice vacancies that emit green light upon excitation.
76
Diamonds: Orange
This is the collusion of nitrogen, hydrogen, and nickel.
77
Diamonds: Pink
These are thought to be colored due to deformation and only come from the Argyle Mine in Australia. Some are thought to have manganese impurities.
78
Diamonds: Type I
This is when there are nitrogen atoms dispersed throughout the structure. It produces a "Canary Yellow" color.
79
Diamonds: Type IIb
These diamonds contain boron which allows them to conduct electricity and create a blue to blue-grey coloration.
80
Dichroscope
This is a loupe with two polarizers in opposite directions that enable a person to have the stone's pleochroic character exemplified. Stones must be colored and doubly refractive. Report resulting colors and intensity. (trichroism is only seen in biaxial materials)
81
Different kinds of lustre
Adamantine (diamond only) Sub adamantine: zircon Bright vitreous: Corundum vitreous: glass Dull vitreous: malachite Resinous: Amber Waxy: turquoise Metallic: hematite
82
Differentiating synthetic and natural opal
Synthetic opal tends to have a collumnar structure and polygons of light reflection it is also more porous and does not phosphoresces green like most natural opals after exposed to LWUV
83
Disclosure and regulation groups/guidelines
CIBJO helps to advise and provide a confederation of similarily interested individuals, organizations, and companies FTC has a jewelry guide about how to properly label gems and jewelry
84
Does glass fluoresce in LWUV?
Glass only fluoresces in SWUV
85
Double Refraction
This describes all anisotropic (biaxial) materials where an incident ray is split into more than one ray upon entering the material. This is the reason for "doubling" of images, like optical calcite.
86
Durability
This is a term that relates to a gems ability to resist change due to light, acid, oil, or heat, (stability), the hardness, and the toughness of the gem.
87
Dyeing
This can be done on any permeable material and involves soaking a material in a liquid to improve the color consistency throughout a stone. It is common to do after bleaching
88
Dyeing ID
look for sharp changes in color in cracks/veins. The absorption spectrum of the material will match to dye and not the stone itself. They may also show discrete patches of fluorescence/non-flourescence. Acetone test: DESTRUCTIVE use with caution but a swab with acetone will stain most organic dyes
89
ED-XRF
This is an energy dispersive x-ray fluorescence spectrometer. It is a non-destructive quantitative bulk chemical analysis technique with the limitation that it can only detect heavier elements meaning those with higher atomic numbers. Pearls: Detects Mn in freshwater pearls and Sr in saltwater pearls. Cannot seperate natural and cultured pearls
90
Elongated gas bubbles and swirls inclusion
These are long squirly inclusions that are indicative of glass.
91
Emission lines and fluorescence
An emission line in a spectrum will appear as a high energy peak in a plot of Intensity vs. wavelength
92
enantiomorph
A crystal which has a mirror image habits and optical characteristics occurring both in right and left handed forms.
93
Examples of carbonate gems
Calcite CaCO3 Malachite Cu2(OH)2CO3 Rhodochrosite MnCO3
94
Examples of crystal habits
Acicular: rutilated quartz Bipyrimidal: Sapphires Botryoidal/globular: chalcedony or hematite columnar/fibrous: kyanite, calcite dendritic: moss agate dodecahedral: garnet euhedral: diamond, spinel, quartz Mamillary: malachite massive: rose quartz octohedral: diamond, spinel prismatic: tourmaline, quartz, zircon scelenohedron: Sapphire Striations: tourmaline, quartz, pyrites Tabular: Ruby
95
Examples of cyclosilicate gems
Beryl (aquamarine), benitoite, cordierite, tourmaline
96
Examples of Framework Silicate Gems
Feldspar, Sodalite
97
Examples of Inosilicate Gems
Single-Chain (pyroxenes): Jade, rhodonite Double chain: Amphiboles
98
Examples of Neso Silicate Gems
Olivine, Garnets, the aluminosilicate series (sillimanite, andalusite, and kyanite), topaz, zircon, staurolite
99
Examples of sheet/phyllosilicate gems
Micas, Chlorite
100
Examples of Sorosilicate Gems
Zoisite (Epidote), Vesuvianite (Idocrase)
101
Expected results from a hexagonal crystal in the refractometer
There would be two shadow edges but only one moves. This shows it is double refractive and uniaxial.
102
Facet terms (table, cutlet, girdle, crown)
The table is the top of the facet. The girdle is the vertical band around the stone's midsection that is used to keep the stone in its setting The cutlet is a little flat part at the bottom tip of the stone that helps prevent brittle fractures and reduces cut imperfections. The crown is the part of the stone above the girdle.
103
Feathers
This is a type of inclusion that represents a "healed" fracture. It looks like a fracture but it is not a plane that has cohesion it is generally less sharp.
104
Ferrous vs ferric coloring
Ferrous (Fe2+) causes the green of peridot and red of almandine Ferric iron (Fe3+) causes the green color in sapphire Iron is also responsible for the blue colors of aquamarine and blue spinel
105
Fluorescence
This is the emission of visible light due to excitation of atoms due to higher energy light interference. It is caused by short wavelength light (E=k(1/lambda))
106
Flux-Melt Technique
This is used for emerald, ruby, sapphire, spinel, and alexandrite It has a series of strung seed crystals in a platinum container with different reactants above and below the seed crystals and a flux in the center. This is heated so the reactants go into solution and precipitate onto the seed crystals. This is identified by the presence of "wispy veils" not "fingerprints" in emeralds and corondum
107
Color Terms (4 types)
Hue: secondary vs. primary (eg Purplish-blue) Tone: Light or dark (eg light blue) Saturation: Color intensity; deep, bright, vivid, pale Consistency of Color: Even, patchy, zoned, bi-colored, parti-colored
108
Four types of cleavage
Basal: Parallel to the pinacoid. 1 direction of cleavage. Octohedral: Parallel to octohedral faces (flourite, grows cubic) Prismatic: Parallel to prism faces. This has four directions of cleavage. Rhombohedral: Parallel to the rhomb faces (calcite). This is three directions of cleavage.
109
Fracture
This is an inclusion that represents a random, non-directional break within a stone.
110
Fracture and 4 types
This is a broad category that primarily describes how something breaks that is not on a cleavage plane. It is conchoidal, hackly, splintery, or smooth (diamonds)
111
Fracture examples:
conchoidial: quartz, obsidian hackly: gold, silver, platinum splintery: kyanite, serpentine uneven: ammolite, chrysocolla Granular: jade, jadeite, lapis lazuli smooth/even: Basal topaz
112
Fracture Filling
This is the filling process that involves filling fractures with polymers or oils to remove the optical effects and improve durability.
113
Fracture Filling Diamond
This is done through using a high RI glass. Look for a characteristic color flash (pink to green) and occasionally frisbee like bubbles form in the cracks.
114
Fracture Filling ID
Look for discrete planes of blue-yellow iridescence and bubbles/clouds (epoxy)
115
FTIR
Fourier transform infrared spectrometer This is useful to identify diamond types, synthetic quartz, turquoise stabilization, and emerald determinations.
116
Fundamental Particles (Atom, proton, electron, neutron)
Atom: This is the smallest unit of ordinary matter that forms a chemical element. It is composed of particles. Proton: Positive particles within an atom Electron: Negative particles within an atom Neutron: ~same mass as a proton but without an electric charge
117
Gel Growth
This is the process involved with producing "synthetic" opal (truly a simulent). It involves suspending a gel of silica spherules that slowly settle and produce the simulent.
118
Gem mining
This is broken into coloured stone mining: ASM (Myanmar, Brazil, Sri Lanka, and Madagascgar) and Diamonds: LSM (Canada and Russia) divided by kimberlites and lamprolites
119
Gem Science/Gemology
The study of gems from origin to jewelry, including the study and identification of gemstones and their treatments.
120
Gem Simulant
This refers to when a gem substitute does not have the same structure as the original gem.
121
Gem Value
Cost Vs. Demand Durability, rarity, beauty at time=t properly identified and treatments considered. 4 C's: Cut, Carat weight, Color, Clarity 5th C: Cost
122
Gems
Any material that is used for adornment or decoration especially when cut nad polished. This includes rough or cut minerals chosen for their beauty and durability that have been cut and polished specifically for adornment. It also includes ornamental rock, biogenic/organic material, or artificial/synthetic.
123
Gemstone dealers
This is the group that sells the cut and polished stones to jewelersand retailers
124
Gemstone Pipeline
Generally the gemstones start at the production (mining or synthetic). 2. ) they are traded between rough dealers, cutters, and treaters 3. ) they are traded between cut dealers and manufacturers 4. ) retail 5. ) customer 6. ) secondary market/auctions
125
Gemstone Treatment
This refers to a suite of potential alterations that is defined as the process of artificially altering and improving the appearance or properties of gem materials. It ought to be disclosed by sellers.
126
General Cutting Procedure for a faceted diamond
Generally, you cut off the upper point. Then it is **Butted** which is rounding the stone. Then it is **Faceted** which gives the stone a few rough faces. This is finished by **Brillianteering** which includes adding all of the small faces and polishing.
127
Geologic Laws
Law of original horizontality: Rocks have a tendency to be created in horizontal layers Law of Superposition: Older rocks have a tendency to be at the base of the formation under review. Law of inclusions: This says that xenoliths/clasts are older than the layer they are found within. Cross-Cutting: To be cross-cut the layer has to be older than the intrusion.
128
Hardness and Luster Relation
Harder gems are less likely to lose lust after being polished and will polish better.
129
Hardness
The ability of a material to resist scratching and abrasion, measured on the Moh's scale of hardness. Look at how sharp the facets are and how deep scratches are to indicate relative hardness of a stone. Hardness testing is **destructive** so always work from soft to hard testing in places that are not readily visible. Do not use a diamond point for testing.
130
heat treatment: amber
Heat treated amber removes the impurities and clouds in the stone but can leave a burnt crust on the edges and stress spangles.
131
Heat treatment: Corundum Other
At a variety of temperatures it can enhance color, remove inclusions, create inclusions, remove color, and create/remove chatoyancy.
132
Heat Treatments
This is a suite of treatments most commonly used to remove or even out color through changing the valency of transition metals, diffusing materials, or dehydration. It is also used to exsolve or dissolve inclusions (rutile in qtz). It can also be used to create fractures to mimic natural stones or increase the effects of dye.
133
Heating and Diffusion
This is used to improve the color of the stone and involves the reaction of various inclusions and elements within a stone changing valency or bonding.
134
Heating and Diffusion: Corundum
In the dark blue sapphires heating shifts Fe2+ to Fe3+ + e- This lightens the stone. In Light blue sapphire there is low ferrous iron and potentially Ti4+ which creates a reducing enviroment to produce more ferrous iron and enhancing the blue color.
135
Heating and Irridation
This is the idea that heating causes valency shifts that can be reversed through irradiation. This includes beryl, quartz, and topaz
136
Heating and Irridation: Beryl
Aquamarine can be heated to become more blue by reducing beryllium and irridated to oxidize beryllium to form yellow helidor.
137
Heating and Irridation: Diamond
Various irridation at different temperatures can create carbon vacancies, transform carbon to nitrogen, and create nitrogen isotopes that produce distinctive spectra trackable with raman.
138
hexagonal crystal system, symmetry, and gem examples
This system has 6 equal faces parallel to the z-axis making it have 6 fold symmetry. a=b/=c α= 120o β= γ= 90o This is also said as having 4 axis (three in the x-y plane at 120 degrees and a z axis) Gem Examples: Beryl (heliodor, aquamarines, morganite, emerald), apatite, taaffeite
139
Hexagonal and trigonal twinning
Contact twins (calcite) Brazil and dauphine twins (qtz interpenetration twins) Japan (qtz contact twin)
140
High Pressure High Temperature (HPHT\_
This was developed in the 1950's for diamonds and principally using a triaxial compression machine to compress a heated vessel of carbon to produce diamonds. They two main machines are called the belt and BARS
141
horsetail/ponytail inclusions
These are radiating fibers that nucleate from one spot within demantoid garnets.
142
How is fossil ivory regulated?
Many states have legislation that limits the transport of ivory and fossil ivory across state bounds making it illegal to purchase unless a state resident.
143
How to find interference figures.
Rotate the stone until iridescence is seen Orient the conoscope over this iridescence to see the interference figure.
144
HPHT diamond coulours/types
This produces yellow to brownish yellow, type Ib yellow diamonds Blue diamonds Type IIb + Type Ib Greeb Type IIb + Ib Colorless Type IIa
145
HPHT treatment
This is used on diamonds to alter the color centres
146
Hydrothermal Synthesis
This places seed crystals (plates) in an autoclave with reactants and water. This creates a supersaturated solution that is cooled to produce synthetic corundum, emerald, beryl, and quartz
147
Hydrothermal Systems
The heating of meteoric, sea, or magamatic fluids to transfer and deposit elements through subsurface "plumbing"
148
Identifying a boule
They will have radiating circles from the spinning and progressive stepwise changes in reactant addition.
149
Identifying composites
They will often have bubbles at the junction, feathers or other inclusions with abrupt ends at the interface. Generally look at the side to ID layers, different wear along the facets, sharp changes in luster or color, and bubbles in adhesives.
150
Identifying diamonds vs. simulents
Most commonly this includes moissanite and cubic zirconia. Both are doubly refractive so look at the setting and see if it doubles. Alternatively, you can place the stone over a black line and if it is not a straight line it is CZ or moissanite. Look for a sloppy cut Look for unpolished corners. Only diamonds will have tiny parts that are left natural to maximize the carat weight.
151
Identifying HPHT synthetic diamonds
Occasional "breadcrumbs" of metal flux hour glass colour zoning stronger reaction to SWUV than to LWUV Attracted to a strong REE magnet
152
Identifying hydrothermal synthesis
They oftentimes have small chevron or zig-zag patterns in their lattice although they are difficult to distinguish.
153
Identifying Moissanite
It was originally only a material found in meteorites but is doubly refreactive and if set in jewelry you can look through the base to see if it doubles the image. Diamond is isometric so this will not occur.
154
idiochromatic gems
These are gems that have transition metals integrated into their lattice to be 'self colored'
155
Imitation and Simulent Materials
These are natural or artificial materials that are used to imitate the effect, colour and appearence of other natural gem materials without having equivalent chemical and physical properties
156
Importance of Gem Sedimentary Deposits
Primarily alluvial deposits of garnet, diamond, olivine, and other resilient gems.
157
Impregnation and Filling
This is treating a stone with wax, oil, and other substances to either improve appearance, lustre, transperency, or durability. It is common in stones that may otherwise be porous or have many fractures like turquoise, jadeite, and lapis lazuli. This substance may also be colored making it a dyeing and consolidating process.
158
Incipient Fracture
This is a directional fracture within a stone.
159
Inicpiatte fracture
This refers to internal cracks/fractures that can or cannot reach the surface.
160
Interference Colors
This is the result of anisotropic minerals e and o rays constructively interfering when exiting the crystal. The two add like vectors and this changes the speed and %transmission of the resultant light. This is proportional to specific mineral properties, thickness, and the light source.
161
Internal features (4)
Inclusions, color zoning, feathers, and cleavage lines
162
Internal reflections examples
Platelets of hematite cause sunstone's shimmer. Copper within glass creates "goldstone" Green mica spangles cause aventurine quartz.
163
Iridescence Cause
This is caused by thin layers of heterogeneous solid or liquids within a material. This commonly includes exsolved feldspar (labradorite), layers of agate (fire agate), aragonite in pearl. The different layers reflect light differently and creates the shimmering effects we see due to wave constructive/destructive interference. This is what creates the iridescence.
164
Irridation types (3)
1. ) high-energy neutron rays from a nuclear reactor 2. ) streams of electrons produced by an accelerator 3. ) gamma rays produced by a radioisotope, typically Co60
165
Isometric Twins
Spinel (octohedral contact twins) Iron cross (2 pyritohedrons rotated 45o apart) Inerprenetration along {111} fluorite. This adds three fold symmetry.
166
Isostructural
This is when there is a synonymous structure/lattice of a material but there are different elements interchanged within minerals. For example, the cation site in garnet. This is also called isomorphism.
167
Isotope
One of two or more species of atoms of a chemical element with the same atomic number but differing masses and properties
168
Isotropism
Mineral properties that are non-directional. Isotropic minerals are extinct in XPL and light travels at the same speed through every direction through the material. It is a property that arises due to symmetry. Glass, gases, amorphous solids, isometric minerals, and most liquids are isotropic materials.
169
Ivory
This is a type of giant tooth. It can be simulated with sperm whale teeth, walrus tusk/teeth, narwhal, bear, elk, crocodile, hippopotamus, warthog teeth.
170
Jet
This is a type of petrified wood or petrified coal.
171
jewelry manufacture
This is the process of sending a cut stone to a factory to be faceted and polished
172
KM laser treatment
This uses a laser to not drill into a stone but to heat it to cause a surface reaching fracture that is used to remove a dark inclusion with acid.
173
LA-ICP-MS
Laser ablated-Inductively Coupled Plasma-Mass Spectroscopy This is a very expensive tool that vaporizes a tiny portion of material to be quantitively analyzed by the proportions of oxides present. It is ideal for low atomic number elements and for trace elements.
174
Lapidary
This is the art of cutting and polishing gem materials that are not diamond
175
Laser Treatment
This is used on diamonds to reduce or remove dark inclusions. It involves using a laser to drill into a diamond until the inclusion is met. This is then dissolved to remove the unpleasant inclusion
176
Lattice Defects (6)
Intrinsic Defects: Vacancies (missing an atom), edge/loop dislocations (when there is a terminated chain of atoms) Extrinsic Defects: Interstitial impurity atoms (random heterogeneous atoms), precipitate of impurity atoms (a chunk of impurity), Substitutional impurity atom (substitution unlike the structure)
177
Nodes
Nodes are collections of atoms within the lattice. They represent elements.
178
LIBS
Laser induced breakdown spectroscopy unit This is a type of ICP-MS unit that vaporizes a tiny portion of a stone to identify treated corundum.
179
Lilly Pads
These are partially healed tension cracks around a small cavity or pore in peridot
180
Luminescence
This is the emission of "cold" non-incandescent visible light. It is all emission of light from a substance. fluorescence is a type of luminescence.
181
Lustre
This is a term that describes the _surface_ reflectiveness/gemminess. This is influenced by hardness, reflective index (the best test for lustre), polish quality, and surface quality. It is a property that is proportional to durability.
182
Mammoth vs elephant growth lines
Mammoth lines are at ~90o elephants are greater than 90o towards the outer edge of the tusk.
183
Manebach Law
This is a form of polysynthetic twinning on the {001} of orthoclase
184
Mineral Groups
These are groups of mineral series and end-members
185
Mineral/Gem hierarchy
Supergroups: Include 3 or more groups of minerals Groups: Includes several minerals Species/End-Members: Individual mineral compositions Variety: End-members that may have specific trace elements that alter their appearence.
186
Mineraloids
These are naturally occurring mineral-like substances that lack crystalline structures. These include obsidian and opal.
187
Minerals
A naturally occurring inorganic crystalline solid of fixed limits of chemical composition and physical properties composed of 2+ elements. 3+ minerals make rocks
188
Modern, Round, Brilliant cut diamonds
This is the most common diamond cut that is seen very often.
189
Monoclinic system, symmetry elements, and gem examples
a/=b/=c α= γ= 90o β\>90o This system is characterized by being an elongated parallelogram and has 2-fold rotational axis and/or 1 mirror plane. Gem examples: Feldspar (K-spar only; moonstone), malachite, azurite, clinopyroxenes (diopside and jadeite), staurolite, sphene/titanite, and spodumene (kunzite).
190
Monoclinic Twinning
Manebach law, carlsbad law, braveno law, swallow tail twins.
191
Nacre
This is the hexagonal aragonite layers in a pearl. They are interlayered with an organic layer of conchiolin and create the iridescence
192
Natural Materials
These are materials that have been formed by nature without human interference or modification outside of fashioning
193
OA Figure
This will only show at a maximum three isogyres. When oriented in this direction they will be extinct in 360 rotations in XPL.
194
Object reference mohs
masonry bit: 8.5 Steel nail: 6.5 Knife/glass plate: 5.5 Copper penny: 3.5 Fingernail: 2.5
195
Observation and Magnification Procedure/Results
1. ) Start with general inspection. Identify color, transparency, heft, crystal forms, and other noteworthy characteristics. 2. ) Use the loupe to ID inclusions, lustre sharpness of facets, cleavage, fracture, and other noteworthy characteristics. Rest the loupe on your cheek bone and hold the stone at an equidistance from your loupe as the loupe is from your eye. 3. ) Further inspection? Microscope.
196
Types of cuts
Faceted: sharp defined edges Cabochon cuts, rounded domes Carvings: these are not defined by having a "base" Cameo: These are a carving extruding from a base intaglio: this is a carving intruding into a stone
197
Optic axis
This is the axis within a crystal where double refraction does not occur. Uniaxial crystals have one direction that double refraction does not occur. Biaxial materials have two.
198
Optic Axis Figure (OA)
One of the optic axes is perpendicular to the stage and there is a partial isogyre.
199
Optic normal figure
This is a flash figure and it represents when one of the privileged directions is parallel to the incident rays. This has the maximum level of interference.
200
Optical Phenomena
This is a group of phenomena that articulate how light interacts with stones Asterism: This is chatoyancy with more than one line that creates a star or some other shape. Chatoyancy is cat's eye. Play of color: This is the multi-colored stones that are common with opals Iridescence: This is the multi-colored reflection of light due to thin films of material being present. Internal Reflections/Inclusions: These are for internal objects and different substances within a material. Scattering: This is light scatter due to irregular particles. It creates a sky-blue color with clouds. Color Change: This is idea that some stones change color under different light sources.
201
Optically Anisotropic
These are doubly refractive materials that shift between extinct and not extinct 4 times through a 360o rotation
202
Organic/biogenic Gems
Carbon-based mineraloids, jet, pearl, amber, ivory, coral. Pearls are the only gem explicitly unaltered.
203
Orthorhombic System, symmetry, and gem examples
a/=b/=c α= β= γ=90o Gems: Olivine (peridot), topaz, chrysoberyl, cordierite (iolite), tanzanite Symmetry Elements: three 2-fold rotational axis and/or 3 mirror planes
204
Orthorhombic expected refractometer results
Two shadow lines move. This shows the material is doubly refractive, biaxial.
205
Orthorhombic twins
Cyclical twins (aragonite) Interpenetration twins (staurolite)
206
Other diamond types
Red diamonds have phosphorous or deformations Purple diamonds have H+ Green diamonds have been irridated Black diamonds have carbon or are deep mantle diamonds (metals) pink diamonds (Argyle mine) have dislocations brown diamonds have dislocations that can be treated via HPHT
207
Oxide Gems Examples
Chrysoberyl: BeAl2O4 Corundum: Al2O3 Quartz: SiO2 Spinel: MgO\*Al2O3
208
parallel growth
This is a term that refers to minerals growing with parallel edges/faces. This is a mineral cluster not a twin.
209
Parallel Growth
This is not a twinning phenomena but describes with all faces of a crystal are formed in contact with the adjacent crystal cluster.
210
Parting
This is "psuedo-cleavage" that occurs at discrete intervals but are not on the weakest planes.
211
Pearl
This is the result of a mollusk covering something with nacre and organic layers of conchiolin
212
Pearl X-ray Fluorescence and CT scans
ONLY Freshwater pearls fluoresce Saltwater pearls with a thin nacre film around a freshwater nucleas may fluoresce. Conch pearls are purple in x-ray radiation. Pearls are oftentimes scanned/x-rayed to look at each individual nacre layer and identify if there is a bead at the center of the pearl.
213
Pearl testing: easiest
Look in the drill hole for a nucleas and/or banding from a shell. Use LWUV, cultured have a green tint, Cortez Sea pearls are bright red, natural have a green tint, and general size/shape.
214
Pegmatite Gems (6 gems)
Feldspars, quartz, beryl, tourmaline, topaz, and zircon
215
Peizoelectricity
This is when pressure distorts the lattice of a crystal slightly to create a dipole that is used as an electric charge. It occurs in trigonal minerals.
216
Peridot lilly-pads
This is a form of incipiatte fracture around inclusions.
217
Phosphate gems
[M+](PO4)x Character: Soft and effervescent Apatite: Ca5(F,Cl)(PO4)3 Turquoise: CuAl6(PO4)4(OH)8\*4H20 -note: Phosphates can easily replace one another. Turquoise after apatite within fossils and mineral deposits.
218
Phosphorescence
This is a type of luminescence when materials radiates after being irridated by a high energy source. Phospherescence occurs after the high energy light is removed. In comparison fluorescence requires the stone is continually irridated to release the light.
219
Physical characteristics to note in a gem
Habit, luster, color (colorless), heft, prisms, terminations, fracture, cleavage, crystal system, transparency.
220
Physical Properties
This is any distinguishing property with a physical specimen that can used to ID the object.
221
pinacoid
A pinacoid is a pair of planes that are either "side pinacoids" (parallel to c-axis) or basal (in the a-b plane)
222
Plane polarized light
This is light that is polarized in two directions.
223
Plane vs Space Lattice
Plane lattices are in 2d. Space lattices are 3d.
224
Plastic simulants for organics sign
Plastic will have chips or is flaky in certain areas.
225
Play of Color Cause
This is because of different radii of stacked spheres/globules of SiO2 that are creating opal. The gaps between spheres cause diffraction and the resultant colors. This is similar to what occurs in a rainbow. The larger the gaps the larger the range of colors.
226
Pleochroism
This is a term for when a mineral that shows multiple colors dependent on the orientation/transmission of light. It is best seen down the OA where the fast and slow directions create different colors dependent on which polarity of light is able to travel through. There will no color change if the OA is perpendicular to the stage. Isotropic minerals will not be pleochroic. Report pleochroism through terms of intensity and using the dichroscope (weak, moderate, strong).
227
Point system of weight
100 points=1 carat 50 points=.5 carat
228
Polariscope
This is a light transmitting device that can be used to test the optics of rough, faceted, or carved materials. It has two polarizers; the material goes between these two polarizers to be observed. The two polarizers are at 90o from one another creating XPL view or the two rays are said to be plane polarized. It is not diagnostic but helps to classify and narrow down the search.
229
Polariscope Reactions
Dark through a full rotation = optically isotropic, singly refractive, amorphous or isotropic. Light and dark 4x in a full rotation = optically anisotropic and Doubly Refractive Light through a full rotation = polycrystalline Patchy light and dark through a full rotation = singly refractive with strain. This is anomalous double refraction.
230
Polariscope use
Place the stone on the rotating stage and rotate the stage in 360 degree rotations. re-orient the stone and repeat. Report results Singly refractive = extinct always=isotropic doubly refractive= 4x extinct = anisotropic fully illuminated always = polycrystalline anomalous extinction = strain = polycrystalline or amorphous with strain
231
Polarization of light
Unpolarized light has components in all directions. Polarized light is constrained to a plane. Reflected rays are polar parallel to the reflecting surface and refracted rays are partially polarized parallel normal to the refracted ray.
232
Polycrystalline materials, examples, and polariscope reaction
Aggregates of randomly oriented small crystals or crystal fibers which need magnification to identify. Examples: Jadeite, nephrite, chalcedony, turquoise They are fully illuminated in the polariscope
233
Polycrystalline growth
This is the aggregate of randomly oriented small/micro crystals/fibers. Examples include jadeite, nephrite, chalcedony, or turquoise.
234
Polycrystalline materials optically
These materials will never go extinct through a 360o rotation.
235
Polymorphism
Chemically synonymous compositions with differing structures
236
Pricing of Pearls: Origin
Saltwater=~10\*freshwater natural=~100\*cultured
237
Pyro Electricity
This is when crystals that are heated show electrical properties. This is why tourmaline in show cabinets attract dust. It is fundamentally caused by the heat causing charge diapoles in the crystals forming partial positive and partial negative zones.
238
Quartz inclusions (5)
Rutile (brown=Brazil, Red=NC), dumortierite (blue acicular needles from Brazil), hematite, brookite (silky grey lines), petroleum, asbestos replaced by quartz (tigers eye), mica (aventurine), moss agate (epidote)
239
Raman Effect
This is the effect of shooting a laser at a substance and some of the photons scatter. Some photons interact with the electrons within the bonds of the material to excite electrons. Upon returning to a ground state this will create "scattering" characteristic to the material. This is used to identify the material.
240
Raman peak intensity with bonding
Generally a more rigid structure (like diamond) produces very sharp peaks. Amorphous materials produce broad peaks.
241
Raman spectra light source
LAsers are used because they uniquely have enough energy to excite electrons. The return wavelength from the electrons is the same regardless of the source. The intensity of peaks does change with source wavelength though.
242
Rarity (4 kinds)
Geographic Rarity: This is determined by how widespread the variety is among localles. Tanzanite is geographically rare Historic rarity: Historic mines produce rare gems. Burma rubys, Kashmir sapphires Quality related rareness: Abundant gems that are low quality vs rare gems at high quality (diamond) Specific color or saturation: Gem-specific rarities like amethyst with a red/blue flash
243
Reconstructed materials
This is the process of taking pieces of a material and re-bonding them together. Amber can be reconstructed by heating many pieces to 200 C Look for sharp boundaries and interesting feathers or bubbles.
244
Reconstructed Materials
These are artificial materials made by bonding or fusing materials into a singular gem.
245
Reflectance Meters
These are very unreliable reflectance measures.
246
Refraction when a ray enters a stone at 90 degrees
No refraction occurs
247
Refractive Index
This is defined as n=C/Cm this is the ratio of the speed of light in a vaccum to the speed of light in the material of interest. n\>1
248
Refractometer
A "table" of very high RI material is used to place the flat, polished, side of a gem. Light is passed up at an angle through the table onto the stone. Because the gems's RI is less than that of the table some of the material is reflected back and the boundary between the totally reflected light and the shadowy, partially reflected light is the shadow edge. It principally reflects light and then splits the emergent o and e rays to identify the birefringence of a stone, uniaxial/biaxial character, and if it is positive/negative. It is a semi-diagnostic test.
249
Refractometer Use
1. ) remove the polarizing filter (if present) 2. ) Prepare with the refractometer oil by placing a small drop on the glass table. 3. ) slide a suitable facet gently over the drop. Generally, place the largest face/facet downwards. 4. ) Keep the stone centered and look into the eyepiece at the shadow edge. 5. ) Rotate the stone. IF no shadow edge moves the stone is ISOTROPIC (singly refractive). IF two shadow edges (seen as a partially illuminated area of the scale) move the stone is BIAXIAL. If one moves it is UNIAXIAL. 6. ) Use the max-min to find the birefringence and report the highest values for RI.
250
Relative Density
This is the ratio of the weight of a material to the weight of another material of equivalent volume. In comparison to SG this does not have to be compared to water, although that is commonly the case.
251
Reporting spectroscopy results
Materials can "cut-off" at one end of the spectrum. There can be bright emission lines Thick, thin, fine lines. There are "three zones" of color. Blue, yellow, and red.
252
Retail
This is the interface of the jewelry industry and the public. It is increasingly moving towards online sales.
253
Rock Cycle
sed rocks to meta or weathering. meta to magma, erosion. ig to melt, meta, weathering.
254
Rocks
These are things composed of 3 or more minerals.
255
Rough dealers
These are dealers selling stones most proximal to the mines. This is also the locale where the greatest amount of synthetics are integrated into the supply chain.
256
Ruby Asterism Natural vs. Synthetic
Natural: Rounded back (increases weight), off-center star, slightly fuzzy arms Synthetic: flat back, centered star, the reflection seems to be "sitting" on the stone surface.
257
Ruby fracture filling
This is done using a leaded glass that show blue to golden flashes an bubbles. The glass may be a significant proportion of the stone's volume.
258
Scattering Cause
This is caused by misalignments in the crystal structure due to inclusions (in moonstone it is albite and causes adulescence) The scattered transmitted light is reddish/pink. The top/sides that are reflected are sky blue.
259
Secondary Market
This is the resell market and includes pawn shops, auctions, and consignment (increasingly popular)
260
Selective Absorption
This is the property of certain elements (primarily transition metals) to absorb most wavelengths of light and the reflected wavelengths are those we observe.
261
Shadow edge
This is the boundary between to the totally reflected light and the partially reflected light used to indicate RI. The other line (@ 1.79 or 1.81) is the refractometer fluid used to create a contact between the gem and the table.
262
Silicate Types
Island/Nesosilicates: Characterized by individual tetrahedra of silicate Paired/Sorosilicate: Tetrahedra are linked in pairs Inosilicates: BOTH single-chain (pyroxenes) and double-chain (amphiboles) silicates Ring/Cyclosilicates: Complex ring "sheets" Sheet/phyllosilicates: Complete sheets of connected tetrahedra often forming hexagons connected to three other hexagons Framework/network silicates: Connectivity of 4
263
Silicates
Silicic acid with metal [M+](SiOy)x Very hard and durable
264
silk inclusions
Usually a very fine rutile inclusion that may cause a hazy appearance in the stone, most often seen in corundum.
265
Singly Refractive materials
These are optically isotropic materials. They are singly refractive.
266
Skull Melting
This is used to principally produce cubic zirconia. It involves having a porous shell aka "skull" filled with seed crystals at the base and the reactents above. This is then heated with a coil that is slowly raised allowing the base to slowly cool and form CZ.
267
Snell's law
This says that ni \*sin(i)= nr sin(r) where i is the angle from the incident ray to the normal and r is the angle from the refracted ray to the normal. Note: the reflected ray is at i too.
268
Snowflake inclusions
These are the white radiating patterns in obsidian
269
Soudes
This is a triplet where the top is spinel, then there is a layer of emerald and the base is glass
270
Space lattice angles
α= angle between B and C axis β= angle between the A and C axis γ= angle between the A and B axis
271
Specific Gravity, and measuring SG
Specific gravity is defined by the ratio of the mass of material in air to the mass of displaced fluid (H2O @STP) of equal volume. In practice it is wts(air)/(wts(air)-wts(water)). This is _hydrostatic weighing_
272
Spectroscope
This requires white light that can be split into the whole visible spectrum. This light is sent through a crystal and the viewer is able to see only the transmitted wavelengths. The dark areas show areas where the gemstone has absorbed the light. The emission spectra is characteristic of particular minerals/materials although the test is not diagnostic it can help narrow coloring elements.
273
Spectroscope Use
Option 1: fix the stone to a source of white light using putty. Look through the spectroscope to see the spectrum. Make sure that the putty fully covers the light source and the room is dark. Option 2: place the stone on a black or dark background. "Bounce" the light through the stone into the spectroscope. Report emission lines, cut offs, thin, and thick lines within their given color range.
274
Spectroscopy
This is the science of analyzing the interaction of light with a material, either visually, or mathematic analysis. For our interests spectroscopy is related to the emission spectrum of minerals.
275
Spinel diagnosis
Spinel is cubic and red. It commonly forms macles and has triangular pits on the pyramid faces.
276
Stability
This is the ability of a stone to resist alteration due to light, heat, or chemicals.
277
Stabilization
This is common with extremely porous materials that are impregnated with polymer resins to increase durability.
278
Steps of artificial crystallization
There are two principle steps, nucleation and crystal growth. Nucleation refers to the physical process of achieving the correct orientation of materials that equates to the crystal structure. Crystal growth refers to the chemical process of the material growing based on the nucleated crystal. The rate and extent is related to the amount of reactants available and the environmental conditions which growth is initiated. It is generally crystallization from a melt or solution.
279
Stone Beauty
This is a subjective measure of a stone that changes with place and time but is generally dependent on style of cut and shape, color, transperency, luster, optical effects. It is ultimately determined by how the stone interacts with light.
280
Sublimation Process
This is a process for producing synthetic moissanite (gem grade silicon carbide) It involves sublimating graphite and Si C powder at 2300oC and sucking it into an Argon atmosphere where at the base of the vessel it is 2200oC and a seed crystal grows into a boule.
281
Swallow tail twins
This is polysynthetic twinning common in gypsum along the {100} plane. It is parallel to the a-axis.
282
SWUV safety
SWUV can cause burns. Do not stare into any UV light and do not expose yourself to SWUV to avoid sunburns.
283
Synthetic lapis id
Iron pyrite
284
Synthetic Materials
These are a sub-section of artificial materials that aim to mimic or replicate their natural counterparts. They have physical and chemical unity with their natural counterparts but if considered path dependent do not follow a natural path.
285
Synthetic Spinel fluorescence reaction
SWUV: it is chalky blue/green LWUV: it is inert
286
Synthetic vs natural opal
Synthetic opals will have the colors "stacked" in a cross section of the stone. This is because the stone is made by allowing sphereoles of silicon dioxide fall.
287
Synthetics production
This primarily occurs in large factories in either China or Russia
288
Tagua Vegetable Ivory
This is an ivory simulant made from the tagua nut, a type of palm nut.
289
Terms of a centered uniaxial optic axis figure.
Note: the isogyres show the principal planes that the o and e rays travel through.
290
Terms to describe cleavage
Quality: Perfect, distinct, good, fair, poor Difficulty: easy, hard, difficult. Describes how hard something must be hit to cleave.
291
Tetragonal Crystal System w/ gem examples and symmetry
a=b/=c α=β=γ=90o This is a rectangular prism and the system has a single 4-fold rotational axis. Gems: Zircon, idocrase, rutile, wulfenite, scapolite
292
Tetragonal Twins
Cyclical Contact Twins like cassiterite and rutile. Oftentimes on the {011} plane.
293
The belt
This is a HPHT method for diamond synthesis where diamond powder is set within a metallic flux (iron or nickel) and the capsule is subjected to extreme heat and pressure. They use a seed diamond at the base and the new crystal forms dependent on the seed crystallographic orientation, P, and T
294
The colors produced by the transition elements
Ti: blue V: green+pink (emerald) Cr: red+green (ruby, emerald, alexandrite) Mn: pink (rhodochrosite) Fe: green, blue, red, yellow Co: blue (spinel) Ni: green (turquoise) Cu: blue, green
295
The mohs hardness scale reference minerals
10: daimond 9: corondum 8: topaz 7: quartz 6: orthoclase 5: apatite 4: fluorite 3: calcite 2: gypsum 1: talc
296
Thermal and electrical conductance
This is important for diamond distinction. Generally, most stones are very poor conductors but diamond is a very high thermal conductor and moissanite is too. The two are differentiated because moissanite is electrically conductive and diamond is not.
297
Three kinds of metamorphic protoliths
Metapelites: These are metamorphosed clay rocks Metacarbonates: Metamorphosed carbonates Metabasalts: Metamorphosed basalts
298
Three types of hydrothermal
Hypothermal: These are the highest P and T hydrothermal deposits. 300-500 celsius Mesothermal: Intermediate depths and pressures 200-300C Epithermal: Shallowest depths and low T 50-200C
299
tiger stripe inclusions
stripes along partially healed twinning planes in quartz
300
Topaz: heating and irridation
Clear topaz can be irridated brown then heated blue. This can be further heated to be clear again or irridated to become brown again.
301
Tortoise shell fake vs real
Real shell will be less sharp at the boundaries of the coloration whereas plastic will have sharp edges of coloration, non-diffusive.
302
Total Internal Reflection
This is the angle (ic) of a ray where the refracted ray has r=90 so it travels along the interface of the substances and the ray of light is totally reflected back into the material. The gemological refractometer uses TIR to measure birefringence and RI.
303
Toughness
This is the ability for a stone to resist fracture or cleavage. It is more related to acute stresses and not long term wear.
304
Transition elements selective absorption (8)
Ti: blue V: green, pink Cr: red, green Mn: Pink Fe: green, blue, red, and yellow Co: Blue Ni: Green Cu: Green, Blue
305
Transparency terms (3)
Transparent means that you can read through it. Translucent means that you can see through it. Opaque means that you cannot see through it.
306
Trapiche Emerald
This is a hexagonal inclusion in emeralds due to carbon materials that causes sectored growth.
307
Treatment and Detection
This alludes to the processes of both treating the rough/cut material and the latter processes of trying to identify the treatments.
308
Triboelectric stones and meaning
This is when a stone is particular prone to static charge like amber.
309
Triboelectricity
310
triclinic system, symmetry elements, and gem examples
a/=b/=c α/= β/= γ/= 90o symmetry includes a one fold rotational axis Gem examples: Feldspar (plag; sunstone and labradorite), kyanite, rhodonite, turquoise
311
Triclinic twinning
Albite and Pericline twinning. This is polysynthetic twinning perpendicular to the b axis.
312
Trigonal crystal system, symmetry and gem examples
This is a subdivision of hexagonal w/ less symmetry where: a=b/=c α= 120o β= γ= 90o This is also said as having 4 axis (three in the x-y plane at 120 degrees and a z axis) and shows only three fold symmetry. Gems: tourmaline, quartz, corundum
313
Trigons
These are triangular pits that appear in the octohedron faces of diamonds that are from etching during exhumation. They are in the opposite direction of the point.
314
Tringular steps
These are in the direction of the octahedron and show a preferred habit. Ex: Spinel
315
Turquoise simulants and identification
"synthetic" turquoise: it does not have a groundmass and if placed into a groundmass as a conglomerate it is visible in a loupe Reconstructured turquoise: Composites of dust and can be ided using IR spectroscopy to detect adhesive Dyed howlite or magnesite: look for greyish marks.
316
Twinning
This is when 2+ crystals grow together in a crystallographic relation that produces a symmetric shape. It has an abrupt change in the lattice continuity without changing the structural continuity. It is caused by stress or a change in P/T during growth. Twins NEVER form on a previously existing symmetry plane but do increase the symmetry.
317
type 1 diamonds
1a: nitrogen is aggregated into clusters. These started as 1b but aged and diffused. They are colorless or yellow 1b: These are younger, yellow/orange diamonds, with disseminated nitrogen throughout the lattice 1aA: These are yellow diamonds with Nitrogen pairs throughout the structure. 1aB: This is when there are 4 nitrogens around a square vacancy where the corner atoms are carbon.
318
Type 2 diamonds:
These diamonds do not have nitrogen 2a: These have no nitrogen or boron, colorless 2b: These have dissemeninated boron atoms (B5+) they are blue
319
Types of Fracture
Conchoidal: shell-like fracture with clam shell striations. Slightly concave. Ex: network silicates Hackly: Breaking along jagged irregular surfaces. Common in aggregate masses. Splintery: Long fibrous splinters Smooth/even: There are no signs of roughness. Like in diamonds
320
Types of Gem Materials (w/ examples)
Synthetic gems (lab-grown diamonds) Biogenic (pearls) Minerals (Emeralds, Rubies...) Adornment Material (Rocks like Lapis Lazuli)
321
Types of inclusions
Single monophase inclusion: a single liquid or gas or solid within a mineral two-phase inclusions: more than one state of material Three phase inclusion: all three phases present.
322
Types of optical effects
Asterism: "cats eyes" Chatoyancy iridescence: labradorite dispersion/"fire": diamond Play of color: opal
323
Uniaxial Interference Figures
If aligned down the c-axis then the figure will be a distinguishable cross. If the c-axis is not parallel to the light then you will see an arm of the figure. If the c-axis is perpendicular to the OA then there will be a flash figure and there will mainly be a big melatope.
324
Uniaxial pos vs neg in refractometer
The c-axis is parallel to the top facet in a uniaxial crystal and thus if the higher shadow edge moves up and down it is positive. If the lower RI shadow edge moves it is negative.
325
Uniaxial systems and materials
Uniaxial materials are characterized by two extreme refractive indices (n) for each wavelength. They have one optic axis and have only a max and min RI. The systems that end in 'al': trigonal, hexagonal, tetragonal
326
Unit Cell
The unit cell is the smallest repeatable unit of nodes needed to create a lattice
327
Using UV light fixtures
Clean the material to remove dust, fingerprints, and other surface contaminants that can fluoresce. Place the material on a black, non-reflective surface. Do not hold it in tweezers. Minimize outside light, this is why UV cabinets are useful. Be careful to not confuse blue reflectance and blue fluorescence.
328
UV-VIS-NIR
Ultraviolet-visible-near-infrared spectrometer This is a specialty tool primarily used for origin reports of sapphires, Paraiba tourmalines, emeralds, garnets, and to detect died materials.
329
Verneuil Flame Fusion
This is a cheap, rapid, and old method for making simple oxide gems like corundum, spinel, rutile, and strontium titanate. It is basically a long tube with a dust feed at the top followed by a furnace in the middle and an air source at the base. This enables a hot kiln in the center where the dust is fed to create a boule.
330
What 4 classifications are determined through the polariscope?
Singly refractive Doubly refractive polycrystalline strained
331
What color is in the upper right of optically positive minerals?
Blue is in the upper right. Yellow is in the upper right of optically negative minerals.
332
What direction does light turn when entering a denser medium?
Light turns toward the normal, closer to vertical.
333
What does inclusion interference look like?
This can appear like patches or changes in extinction dependent on the material.
334
What extinction is exhibited in twinning?
This is often shown through one part of the crystal becoming extinct at different times than the other parts.
335
What gem has the highest reflectivity?
Diamond. It reflects all of the light back out to the viewer. Metallic surfaces are better at reflection but they are not gems.
336
What hexagonal mineral will have hexagonal pits on the top and rectangular prisms on the edges?
Beryl
337
What is a bullseye?
This is a uniaxial figure with a "hole" in the center that is diagnostic of quartz.
338
What is a carat/?
It is 1/5th of a gram or the weight of one carob seed.
339
What is the general relationship between weight and price?
Price=wtk where k\>1. This is idealized where in reality it is piece-wise where big notable quanta of weights change the price (eg .9 vs 1 ct)
340
What is white light?
It is the combination of all the colors of the visible specturm.
341
When/where do interference figures appear and what is their use?
Interference figues are only seen down the C-axis in doubly refractive materials. It will help reveal whether the stone is uniaxial or biaxial (+-)
342
Why is specific gravity or density important?
Stones are sold by weight. Therefore a stone with similar volume but different density will have a very different price.
343
X-ray radioagraphy
This literally x-rays the rock for internal structure. It is used to identify pearls because they have concentric aragonite layers. It is very fast too, ~15-20 minutes
344
Yield
This is the comparison of the weight of stone retained after cutting vs. the rough weight. Generally, stones are fashioned to increase yield. It can either be said as a percent or as an absolute weight.
345
Zircon common forms
Zircon is tetragonal but often the c axis is not too long making it seem bipyramidal.
346
Zone Melting
This used a conglomerate or sintered rod that is then heated by passing a heating coil along the rod and feeding reactent as it moves to enlarge the rod.
347
Girdle
This is the fine band around the widest part of the modern round brilliant cut that is used to secure the stone in jewelry
348
Pavillion
This is the term referring to the part of the facet that is below the girdle in includes the lower girdle facet, pavilion main facet, and the cutlet.
349
Crown
This is the area above the girdle. It includes the table, upper girdle facet, and crown main facet.
350
Other facet styles
Step cuts: Emerald (tapered rectangle) and Baguette cut (trapezoid) Rose cut: This is the oldest facet and it is a disco ball on the top and a flat bottom Mixed Cuts: These include more than one type of faceting style Fantasy cuts: These are particularly popular right now and create unique internal inclusions
351
Baroque
These are irregular polished and tumbled stones. It also applies to irregular pearls.
352
Cabachon styles
There is medium, flat, double (rounded top and bottom), and hollow (used with garnet to increase transperency) cabochons
353
Cabochon cut reasons
Cabochon cuts may be preferred if the stone is translucent or opaque, reveal optical effects, or to maximize the durability of softer stones.
354
Beads
These are polished or faceted materials with a hole in the middle
355
Inlays
This is popular in native american jewelry and includes flat pieces of stone arranged to create unique patterns.
356